Comparative Study of Acid and Alkaline Stimulants with Granite in an Enhanced Geothermal System

The Enhanced Geothermal System (EGS) is an artificial geothermal system that aims to economically extract heat from hot dry rock (HDR) through the creation of an artificial geothermal reservoir. Chemical stimulation is thought to be an effective method to create fracture networks and open existing fractures in hot dry rocks by injecting chemical agents into the reservoir to dissolve the minerals. Granite is a common type of hot dry rock. In this paper, a series of chemical stimulation experiments were implemented using acid and alkaline agents under high temperature and pressure conditions that mimic the environment of formation. Granite rock samples used in the experiments are collected from the potential EGS reservoir in the Matouying area, Hebei, China. Laboratory experimental results show that the corrosion ratio per unit area of rock is 3.2% in static acid chemical experiments and 0.51% in static alkaline chemical experiments. The permeability of the core is increased by 1.62 times in dynamic acid chemical experiments and 2.45 times in dynamic alkaline chemical experiments. A scanning electron microscope analysis of the core illustrates that secondary minerals, such as chlorite, spherical silica, and montmorillonite, were formed, due to acid-rock interaction with plagioclase being precipitated by alkaline-rock interactions. Masking agents in alkaline chemical agents can slightly reduce the degree of plagioclase formation. A chemical simulation model was built using TOUGHREACT, the mineral dissolution and associated ion concentration variation being reproduced by this reactive transport model.     

中亚造山带南缘中—新元古代地壳的揭示——来自北山—阿拉善北部钻遇碱性花岗岩的年代学和Hf同位素示踪研究

前寒武纪微陆块是北山—阿拉善北部增生造山带的重要组分,旱山、雅干和珠斯楞—杭乌拉地区的前寒武纪基底是否存在学界尚存争议.居延海介于北山造山带北部和阿拉善地块北缘的构造衔接部位,受限于巴丹吉林沙漠覆盖,岩石露头极少,我们通过钻井工程,钻遇一套晚石炭世碱性花岗岩,锆石U-Pb年龄和Hf同位素特征揭示,该花岗质岩浆锆石结晶年龄为(312±1)Ma(MSDW=0.46,n=18)和(315±2)Ma(MSWD=0.93,n=15),具有正的εHf(t)值,介于+0.8～+4.4之间,平均值为+2.2,对应二阶段模式年龄TDM2为1048～1267 Ma,平均值为1183 Ma,具有古老地壳的源区属性.通过与旱山构造带、雀儿山构造带、雅干构造带和珠斯楞—杭乌拉构造带的晚石炭世花岗质岩浆对比分析,结合旱山构造带、雅干构造带和珠斯楞—杭乌拉构造带0.9 Ga花岗质岩石的出露以及区域上的重磁资料解译,我们认为旱山、雅干和珠斯楞—杭乌拉构造带存在中—新元古代地壳,且可开展进一步的衔接关系研究.     

Single Zircon LA-ICP-MS U-Pb Dating of the Guandimiao and Wawutang Granitic Plutons in Hunan, South China and Its Petrogenetic Significance

1 Introduction The South China Block (SCB), located between the Qinling-Dabie and Songma Indosinian sutures, experienced successively two important tectonic movements during the Mesozoic, i.e. the Indosinian movement (early Mesozoic) and the Yanshanian movement (late Mesozoic). Therefore, the generally accepted viewpoint is that the key geological problems during the Mesozoic are essentially the dynamics and material expression of these two tectonic movements in South China (Chen et al.…     

柴北缘元古宙鹰峰环斑花岗岩及其共生岩石的地球化学特征、成因及地质意义

中元古代鹰峰岩体的主体是环斑花岗岩,与其共生的岩石有石英闪长岩-奥长花岗岩和辉绿岩。环斑花岗岩高碱（Na2O＋K2O=8.49%～9.39%）、富钾（K2O/Na2O=1.12～1.43）,铝近饱和,高铁镁比值[（ΣFeO）/MgO=4.91～7.19];富Rb、Ba、Ga、Th、Zr、Nb、Ta,贫Cr、Ni、V;高ΣREE（392.24×10-6～594.76×10-6）,稀土元素强分异[（La/Lu）N=12.67～17.09],弱铕负异常（δEu=0.58～0.78）,显示碱性花岗岩的特征,与密云环斑花岗岩相似。石英闪长岩-奥长花岗岩具钙碱性系列岩石的特征;与环斑花岗岩相比,其Rb、Ba、Ga、Nb、Ta、Th、Hf、Zr低,而Ni、Cr、V高;ΣREE较低（ΣREE=77.04×10^-6～129.85×10^-6）,轻重稀土分异明显,但（La/Lu）N的比值较小（11.62～14.06）,铕异常更弱（δEu=0.69～0.93）。辉绿岩具低碱、高ΣFeO的特征,属拉斑玄武质,与洋中脊拉斑玄武岩相比,K2O等不相容元素高,具大陆拉斑玄武质的特征。辉绿岩的ISr（1776Ma）为0.7066,εNd（1776Ma）为＋3.6,环斑花岗岩的ISr（1776Ma）为0.7181,εNd（1776Ma）为-5.5,显示辉绿岩起源于年轻的地幔,花岗质岩浆主要源自古老的地壳。综合分析显示,这些侵入岩形成于伸展背景,是北半球中元古代非造山环斑花岗岩的成员之一,在加里东期卷入到柴北缘造山带的古老地壳中。这在世界上提供了一个古老克拉通及环斑花岗岩卷入古生代造山带的一个实例。     

Regional variations in cleavage and fold development in North Wales

The arcuate pattern of the main Caledonian cleavage and associated fold axial plane traces in North Wales is due partly to NW-SE compression with tectonic transport to the southeast against the concealed crop of the Tan y grisiau Microgranite. Low-angle cleavage close to the microgranite is shown to be a local variant of the regional cleavage formed during the main deformation and not an earlier phase as previously supposed. Transcurrent movements along several major fault systems are also related to compression around the microgranite and the Harlech Dome block.     

Geochemistry and Petrogenesis of Late Ediacaran Rare-metalAlbite Granites of the Arabian-Nubian Shield

The Abu Dabbab albite granite(ADAG), in the central Eastern Desert of Egypt, hosts the most significant rare metal ore deposit in the northern part of the Neoproterozoic Arabian-Nubian Shield. Here, we report detailed field,petrographic, mineralogical and geochemical investigation of the ADAG, an isolated stock-like granitic body with sharp intrusive contacts against metamorphic country rocks, probably emplaced at about 600 Ma. The fine-grained porphyritic upper unit is a preserved remnant of the shallowly-emplaced apex of the magma chamber, whereas the medium-grained lower unit crystallized at deeper levels under subvolcanic conditions. The peraluminous leucocratic ADAG shares common geochemical characteristics with post-collisional intraplate A-type magmas. In addition to the conspicuous enrichment in Na2 O, the ADAG is remarkable for its anomalous concentrations of Ta, Nb, Li, Hf, Ga, Sn, Zn and heavy rare-earth elements. Nb-Ta minerals in the ADAG are mixed with Fe-Mn oxides, forming black patches that increase in abundance toward of the base of the intrusion. Columbite-tantalite, cassiterite and wolframite are the most important ore minerals.Pronounced negative Eu anomalies(Eu/Eu* = 0.10–0.24) reflect extreme magmatic fractionation and perhaps the effects of late fluid-rock interaction. The ADAG was most likely generated by partial melting of the juvenile middle crust of the ANS as the geotherm was elevated by erosional uplift following lithospheric delamination and it was emplaced at the intersection of lineations of structural weakness. Although formation of the ADAG and its primary enrichment in rare metals are essentially due to magmatic processes, late-stage metasomatism caused limited redistribution of rare metals. Fluid-driven subsolidus modification was limited to the apex of the magma chamber and drove development of greisen, amazonite, and quartz veins along fracture systems.     

兴安地块南段晚泥盆世包格德岩体时代的厘定及地质意义

中亚造山带东端兴安地块南段的包格德岩体由石英二长岩、二长花岗岩和花岗斑岩3种岩性组成,岩体锆石LA-ICP-MS U-Pb定年结果分别为368±+1 Ma、364±1 Ma、355±1 Ma,为晚泥盆-早石炭世岩浆活动的产物;岩体的(Na2O+K2O)含量为7.62％～8.82％,K2O/Na2O值为0.93～4.21...     

西藏甲玛矿床南坑高分异Ⅰ型花岗斑岩及黑云母矿物学特征

高硅花岗岩对于理解浅部岩浆房的行为具有重要意义.本文对西藏甲玛矿区南坑矿段的花岗斑岩开展了岩相学、岩石地球化学及黑云母矿物学研究.结果显示,该花岗斑岩具有高SiO2(73.39％～77.99％)、高K2O(4.34％～6.45％)和低P2O5(0.03％～0.06％)特征,铝饱和指数为0.97～0.98,富集Rb、Th...     

Archean (about 2500 Ma) anatexis in eastern North China Block

Two Neoarchean alkaline feldspar-rich granites sourced from partially melted granulite-facies granodioritic orthogneiss have been here recognised in the eastern part of the North China Block (NCB). These poorly foliated granites have previously been assumed to be Mesozoic in age and never dated, and so their significance has not been recognised until now. The first granite (AG1) is a porphyritic syenogranite with megacrystic K-feldspar, and the second (AG2) is a quartz syenite with perthitic megacryst. Zircons from the granites yield LA-ICP-MS U-Pb ages of 2499 ± 10 Ma (AG1), and 2492 ± 28 Ma (AG2), which are slightly younger than the granodioritic orthogneiss that they intrude with a crystallisation U-Pb age of 2537 ± 34 Ma. The younger granites have higher assays for SiO₂ (71.91% for AG1 and 73.22% for AG2) and K₂O (7.52% for AG1 and 8.37% for AG2), and much lower assays for their other major element than the granodioritic orthogneiss. All of the granodioritic orthogneiss and granite samples have similar trace element patterns, with depletion in Th, U, Nb, and Ti and enrichment in Rb, Ba, K, La, Ce, and P. This indicates that the granites are derived from the orthogneiss as partial melts. Although they exhibit a similar REE pattern, the granites have much lower total REE contents (30.97×10⁻⁶ for AG1, and 25.93×10⁻⁶ for AG2), but pronounced positive Eu anomalies (Eu/Eu* = 8.57 for AG1 and 27.04 for AG2). The granodioritic orthogneiss has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70144, εNd(t) value of 3.5, and εHf(t) values ranging from −3.2 to +2.9. The orthogneiss is a product of fractional crystallisation from a dioritic magma, which was derived from a mantle source contaminated by melts derived from a felsic slab. By contrast, the AG1 sample has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.6926 that is considered too low in value, εNd(t) value of 0.3, and εHf(t) values between +0.57 and +3.82; whereas the AG2 sample has an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70152, εNd(t) value of 1.3, and εHf(t) values between +0.5 and +14.08. These assays indicate that a Sr-Nd-Hf isotopic disequilibrium exists between the granite and granodioritic orthogneiss. The elevated εHf(t) values of the granites can be explained by the involvement of Hf-bearing minerals, such as orthopyroxene, amphibole, and biotite, in anatectic reactions in the granodioritic orthogneiss. Based on the transitional relationship between the granites and granodioritic orthogneiss and the geochemical characteristics mentioned above, it is concluded that the granites are the product of rapid partial-melting of the granodioritic orthogneiss after granulite-facies metamorphism, and their crystallisation age of about 2500 Ma provides the minimum age of the metamorphism. This about 2500 Ma tectonic-metamorphic event in NCB is similar to the other cratons in India, Antarctica, northern and southern Australia, indicating a possible connection between these cratons during the Neoarchean.     

藏南拉康温泉地质特征及雄曲河谷两岸地热分布不均成因分析

西藏山南地区洛扎县雄曲河拉康段在600 m距离内出露温泉4处,仅1处位于河谷右岸;平硐勘查显示两岸岩性、产状、构造一致,地热异常却仅在左岸平硐内部显著,右岸平硐地热异常不明显.本次研究以此异常为出发点,通过片麻状花岗岩不同切面导热实验、片麻状花岗岩与板岩相同切面导热实验,温泉水δ2H,δ18O同位素测试分析等方法,探究...