Delayed geochemical hazard: Concept, digital model and case study

Delayed Geochemical Hazard (DGH briefly) presents the whole process of a kind of serious ecological and environmental hazard caused by sudden reactivation and sharp release of long-term accumulated pollutant from stable species to active ones in soil or sediment system due to the change of physical-chemical conditions (such as temperature, pH, Eh, moisture, the concentrations of organic matters, etc.) or the decrease of environment capacity. The characteristics of DGH are discussed. The process of a typical DGH can be expressed as a nonlinear polynomial. The points where the derivative functions of the first and second orders of the polynomial reach zero, minimum and maximum are keys for risk assessment and harzard pridication.The process and mechanism of the hazard is due to the transform of pollutant among different species principally. The concepts of "total releasable content of pollutant", TRCP, and "total concentration of active specie", TCAS, are necessarily defined to describe the mechanism of DGH. The possibility of the temporal and spatial propagation is discussed. Case study shows that there exists a transform mechanism of "gradual release" and "chain reaction" among the species of the exchangeable and the bounds to carbonate, iron and manganese oxides and organic matter, thus causing the delayed geochemical hazard.     

东秦岭上宫金矿流体成矿作用:矿物学研究

通过对上宫金矿矿物学资料的研究，确定其成矿过程具有3阶段演化特征。早阶段以粗粒乳白色石英脉为标志，矿物破碎、变形明显，金和杂质成分含量低，形成于挤压构造背景下静岩压力的变质流体。中阶段发育细粒多金属硫化物-碲化物-自然元素组合，呈微细网脉浸染于共轭节理或裂隙，没有遭受变形，金和杂质成分含量高，自然金与其他矿物属共沉淀关系，由变质流体沸腾导致，而流体沸腾则由造山过程的地壳快速隆升剥蚀引起。晚阶段发育具梳状构造的石英-碳酸盐网脉，含金性较低，由静水压力的大气降水热液在伸展构造背景下贯入张性裂隙形成。矿床地质地球化学特征与造山型金矿一致，成矿过程同步于陆陆碰撞造山作用，属于典型的断控脉状造山型金矿，成因适合于CMF模式。     

Formation of Fe-oxyhydroxides from the East Pacific Rise near latitude 13°N:Evidence from mineralogical and geochemical data

The mineralogical and geochemical characteristics of Fe-oxyhydroxide samples from one dredge station (long. 103°54.48'W, lat. 12°42.30'N, water depth 2655 m) on the East Pacific Rise near lat 13°N were analyzed by XRD, ICP-AES, and ICP-MS. Most Fe-oxyhydroxides are amorphous, with a few sphalerite microlites. In comparison with Fe-oxyhydroxides from other fields, the variable ranges in the chemical composition of Fe-oxyhydroxide samples are very narrow; their Fe, Si, and Mn contents were 39.90%, 8.92%, and 1.59%, respectively; they have high Cu (0.88%―1.85%) and Co (65×10?6―704×10?6) contents, and contain Co Cu Zn Ni> 1.01%. The trace-element (As, Co, Ni, Cu, Zn, Ba, Sr) and major-element (Fe, Ca, Al, Mg) contents of these samples are in the range of hydrothermal sulfide from the East Pacific Rise near 13°N, reflecting that this type of Fe-oxyhydroxide constitutes a secondary oxidation product of hydrothermal sulfide. The Fe-oxyhydroxide samples from one dredge station on the East Pacific Rise near 13°N are lower in ΣREE (5.44×10?6―17.01×10?6), with a distinct negative Ce anomaly (0.12 ― 0.28). The Fe-oxyhydroxide samples have similar chondrite-normalized rare-earth-element (REE) patterns to that of seawater, and they are very different from the REE composition characteristics of hydrothermal plume particles and hydrothermal fluids, showing that the REEs of Fe-oxyhydroxide are a major constituent of seawater and that the Fe-oxyhydroxides can become a sink of REE from seawater. The quick settling of hydrothermal plume particles resulted in the lower REE content and higher Mn content of these Fe-oxyhydroxides, which are captured in part of the V and P from seawater by adsorption. The Fe-oxyhydroxides from one dredge station on the East Pacific Rise near 13°N were formed by secondary oxidation in a low temperature, oxygenated environment. In comparison with the elemental (Zn, Cd, Pb, Fe, Co, Cu) average content of hydrothermal sulfide samples from the East Pacific Rise near 13°N, the Zn, Cd, and Pb contents of the Fe-oxyhydroxides are lower, and their Fe, Co, and Cu contents are higher.     

阿尔泰高山区金矿带的确定和意义

根据地质、地球化学和资源总量预测等方法的综合研究表明,在阿尔泰高山区红山咀断裂以北宽20～30km,东西长约150km地带为一重要金成矿带。金矿赋存于晚古生代陆相酸—中酸性火山岩地层中,空间上受冰长石-黄铁绢英岩化蚀变带严格控制,是以毒砂、辉锑矿等金属硫化物为主要载体的层控浅成低温热液溶滤型金矿,也是一种新的重要的金矿工业类型。     

湘西南采金“信”的地质解释

在湘西南民间开采脉金的活动中,人们积累了很多识别金富集的标志,简称“信”。本文收集列举了25种“信”,并相应地作了地质解释,评估了含金情况。从金的地球化学特性,论述了“信”与金富集的内在联系。     

Risk Management for Petroleum Reservoir Production: A Simulation-Based Study of Prediction

We consider numerical solutions of the Darcy and Buckley–Leverett equations for flow in porous media. These solutions depend on a realization of a random field that describes the reservoir permeability. The main content of this paper is to formulate and analyze a probability model for the numerical coarse grid solution error. We explore the extent to which the coarse grid oil production rate is sufficient to predict future oil production rates. We find that very early oil production data is sufficient to reduce the prediction error in oil production by about 30%, relative to the prior probability prediction.     

Multidimensional statistical technique for detection of low contrast geochemical anomalies

In this article we propose an advanced technique for detecting low contrast geochemical anomalies using a set of features. There are three principal elements in this technique: (1) a statistical measure of the contrast of the anomaly, denoted as τ; (2) selection of a background population; and (3) reduction of the dimensionality of the feature space. In the frame of the model, which describes the statistical distribution of geochemical background as a multidimensional normal distribution of logarithms of concentrations, the index, τ, is a powerful test statistic for the hypothesis of abnormality of an observation. Maps of τ anomalies can be rigorously interpreted on the basis of statistical inferences. Under all equal conditions this technique allows the detection of geochemical anomalies with at least the same contrast (if the chemical elements in a background population are correlated, then even the better) as using selective extractions of metals from soil or other techniques for data processing. The advantages of the proposed technique are demonstrated both theoretically and on examples of rare-metal and copper–nickel mineral deposits.     

松潘地区岩金统计成矿予测中泛克立格法的应用

川西北地区是国内重要的岩金普查靶区。本文对松潘地区的地质特征,泛克立格法原理,及在本区的应用情况作了介绍,对主要计算步骤,给出基本结果,对计算获得的有意义异常区,进行地质解释,并将此方法与趋势面分析进行对比。     

地球磁场对太阳风的加载响应与地震

地磁预报地震的方法越来越多,本文应用加卸载响应比方法,分析山西地区2009—2016年观测的加卸载响应比与山西地区4.0级地震之间的对应关系,初步给出适用于山西地区震例特征的磁异常判别指标。     

基于遗传算法的分类体系在地震预报中的应用探索

采用模似自然界生物进化过程的遗传算法的分类体系,并以首都圈地区为例,利用地震活动性资料的8种时空参数在地震预报中进行了应用探索．通过对1967—1992年间信息的学习演化,获得了20条拥有不同适应度的具有层次结构的地震预报规则集．对首都圈地区中等地震活动的预报规则进行了初步的分析讨论,发现了人们以往难于考虑周全的可能具有重要预报意义的异常组配.应用探索表明：在地震预报研究中应用具有自适应和潜在学习能力的基于遗传算法的分类体系,将可能推动人们对地震前兆及其物理机制的研究和探讨．