中国金矿床(Ⅰ):成矿理论研究新进展

针对中国近年来金矿床学领域研究工作,综合讨论了金矿床成矿学理论研究方面的主要进展。它们集中体现在①大型一超大型金矿床;②区域成矿学与成矿系统;③造山带成矿与造山型金矿：从俯冲（增生）造山到碰撞造山成矿的显著发展;④成矿系列、成矿谱系到成矿体系研究;⑤热点、地幔柱及其多级演化：从边缘成矿到板内成矿;⑥成矿时代：从模糊到精确;⑦现代金矿成矿的实时模型;⑧从板块构造演化、超越板块构造到成矿地球动力学等8个方面。     

辽宁小塔子沟金矿地质特征及成矿控制因素

小塔子沟金矿床位于凌源一北票金矿成矿带的中部,为受区域断裂构造、燕山期石英二长岩和太古界小塔子沟组变质杂岩所控制的含金石英脉型和蚀变岩型金矿,通过对矿床地质特征的分析,进一步总结该区成矿控制因素,认为区域上找矿前景广阔。     

河南石板沟金矿矿床地质特征及成因探讨

在总结石板沟金矿床矿化地质特征的基础上,通过对矿石氢氧同位素测试和矿石微量元素相关分析,认为成矿热液主要来源于变质水,矿床成矿环境应属低温环境,矿床成因类型属受构造剪切带控制的低温变质热液蚀变型金矿床。     

云南东川因民铜矿金矿化特征及成因初探

因民铜矿发育两种金矿化类型:一是铜矿的伴生金;二是热液构造蚀变岩型。化探样品分析结果显示,金矿化主要赋存于金箔箐断层上、下盘的角砾状蚀变岩内,空间上受岩性和断裂构造的双重控制。邻区拖布卡金矿的成矿地质背景与本区相似,在成矿地质年代上作以类比推测,认为喜马拉雅期是主成矿期。另外通过对光片镜下和化探原生晕样聚类分析研究,发现构造蚀变岩型金矿化具明显的多期多阶段性及热液特征。     

大别地块东南缘逆冲滑脱构造体系及其对金矿的控制作用

大别地块自晚元古代以来主要经受了自北而南的推挤,并且发生了两次较强烈的南移运动,造成了地块前线逆冲滑脱构造体系。特别是中生代的推挤和滑移,不仅构造变形强烈,而且还伴有热事件,大别地块东南缘郯－庐断裂南延部分和广济－宿松平移－推覆型韧性剪切带均是＂热线构造＂,它们提供了深层次岩浆活动的通道。本区岩石以绿片岩－角闪岩相变质岩为主,含金背景值高,逆冲滑脱构造和韧性剪切带的活动与金元素的活化、迁移和富集创造了良好的条件。     

四川木里耳泽岩溶型金矿床形成条件和成矿机制

四川本里耳泽金-菱铁矿建造矿床,赋存于上二叠统海相碳酸盐岩层中,矿化受古岩溶的严格控制,组成矿石的基本矿物为菱铁矿,金不均匀地分布于菱铁矿矿体内。成矿溶液来自加热的循环地下水。成矿过程分为早阶段和中-晚阶段。成矿温度为156-210℃,成矿深度小于1km.成矿物质主要来自地层。成矿热液呈碱性和弱还原性,贫硫,含中等盐度。矿床形成时的地质构造环境较稳定。这是我国仅见的一种特殊金矿类型。     

贵州中三叠统烂泥沟金矿有机质的初步研究

烂泥沟金矿是以浊积岩为容矿岩石的微细浸染型金矿。有机岩石学分析表明,矿石与围岩中干酪根类型无明显差别,同属腐泥-腐植型。与围岩相比,矿石中干酪根成熟度(R₀=2.74%-3.06%)和含金性(6.15-24.8μg/g)均较高;干酪根总含金量在全岩中所占的比例是围岩高于矿石。氯仿沥青“A”的检测说明,矿石样品中可溶性有机质形成于强还原和高盐度环境,沥青质和含硫有机化合物发育。研究认为,干酪根含金性与碳的活化有关;不饱和的有机基因对金的动一定转换可能具有重要意义。     

An electrochemical study of pyrite oxidation in the presence of carbon coatings in cyanide medium

The anodic and cathodic behaviour of pyrite with clay and different carbon coatings of activated carbon, graphite and carbonaceous matter in cyanide medium was investigated using the potentiodynamic method. The presence of clay coating did not change the polarisation curve appearance for either the anodic oxidation of pyrite or the cathodic reduction of oxygen or the potential of the current plateau, but only decreased the plateau current especially at a higher coating thickness. The presence of the carbon coatings marginally shifted the rest potential for pyrite to a more anodic position and slightly changed the polarisation curve appearance for pyrite oxidation. The current density for pyrite oxidation largely increased in the presence of the carbon coatings, the potential at the plateau shifted to more cathodic positions, and the plateau width became smaller. These effects became more noticeable at a higher coating thickness. The activated carbon, graphite and carbonaceous matter coatings performed similarly in affecting pyrite oxidation at a similar thickness. The carbon coatings significantly increased the limiting current densities for oxygen reduction on pyrite, and the limiting current plateau became steeper at a higher coating thickness. The carbon coatings increased the limiting current density for oxygen reduction to a similar extent at a low coating thickness, but increased to varied extents at a higher coating thickness. The carbon coatings also greatly increased the cathodic current density for gold reduction on pyrite. The enhancement of pyrite oxidation and oxygen or gold reduction on pyrite by the carbon coatings was likely attributed to the electrochemical interaction between pyrite and the carbon materials with electron-rich surfaces and high conductivity. The presence of the carbon coatings significantly increased the oxidation of pyrite in aerated cyanide solutions and the preg-robbing of pyrite especially at a higher coating thickness.     

The Ore-forming Fluid of the Gold Deposits of Muru Gold Belt in Eastern Shandong, China - a Case Study of Denggezhuang Gold Deposit

Abstract. Denggezhuang gold deposit is an epithermal gold‐quartz vein deposit in northern Muru gold belt, eastern Shandong, China. The deposit occurs in the NNE‐striking faults within the Mesozoic granite. The deposit consists of four major veins with a general NNE‐strike. Based on crosscutting relationships and mineral parageneses, the veins appear to have been formed during the same mineralization epochs, and are further divided into three stages: (1) massive barren quartz veins; (2) quartz‐sulfides veins; (3) late, pure quartz or calcite veinlets. Most gold mineralization is associated with the second stage. The early stage is characterized by quartz, and small amounts of ore minerals (pyrite), the second stage is characterized by large amounts of ore minerals. Fluid inclusions in vein quartz contain C‐H‐O fluids of variable compositions. Three main types of fluid inclusions are recognized at room temperature: type I, two‐phase, aqueous vapor and an aqueous liquid phase (L+V); type II, aqueous‐carbonic inclusions, a CC₂‐liquid with/without vapor and aqueous liquid (LCO₂+VCC₂+Laq.); type III, mono‐phase aqueous liquid (Laq.). Data from fluid inclusion distribution, microthermometry, and gas analysis indicate that fluids associated with Au mineralized quartz veins (stage 2) have moderate salinity ranging from 1.91 to 16.43 wt% NaCl equivalent (modeled salinity around 8–10 wt% NaCl equiv.). These veins formatted at temperatures from 80d? to 280d?C. Fluids associated with barren quartz veins (stage 3) have a low salinity of about 1.91 to 2.57 wt% NaCl equivalent and lower temperature. There is evidence of fluid immiscibility and boiling in ore‐forming stages. Stable isotope analyses of quartz indicate that the veins were deposited by waters with δ^O and δD values ranging from those of magmatic water to typical meteoric water. The gold metallogenesis of Muru gold belt has no relationship with the granite, and formed during the late stage of the crust thinning of North China.