断陷盆地陡坡带砂砾岩扇体地震反射特征--以东营凹陷为例

针对陆相断陷盆地陡坡带发育的砂砾岩扇体油气藏具有成因类型多、形态各异、岩性变化大、地震识别和描述困难的特点,主要从陡坡带砂砾岩扇体的类型和沉积特征研究入手,分析了大量的实际地震资料,总结出了陡坡带冲积扇、近岸水下扇、扇三角洲和近源浊积扇4种类型砂砾岩扇体的地震相特征及地震波传播速度、振幅、频率、相干性等地震属性特征;根据其地震特征建立的地震识别模式在东营凹陷陡坡带砂砾岩扇体的油气藏勘探中取得了良好的应用效果.     

Modelling ion composition in seepage water from a column experiment with an open cut coal mine sediment

Secondary reactions occurring in pyrite-containing sediments from open cut coal mines are complex and not fully understood. In this study, the changes in seepage water composition in a column experiment with a sediment containing pyrite (5.6 g kg⁻¹) were evaluated using a chemical equilibrium model. A column experiment with artificial irrigation (730 mm water yr⁻¹) was carried out for 2 yr with a sediment from the open pit mine Garzweiler, Germany, at the Institute of Applied Geology. Tracer (LiCl) was added to the sediment. Seepage water composition at 52 cm depth was sampled weekly. Redox potential and the water potential were also recorded weekly. Sulphate and Fe(II) were the dominant ions in the seepage water with concentration maxima of 500 and 350 mmol l⁻¹ after 50 days (0.7 pore volumes (PV)). Minimum pH values were around 0.8 after 100 days (1.4 PV), but increased subsequently and reached 2.4 after 700 days (9.5 PV). Ion activity product calculations indicated the intermediate formation of gypsum (19th–480th day of the experiment). Solutions were undersaturated with respect to alunite, jarosite, jurbanite, schwertmannite, melanterite, gibbsite and goethite during the whole experiment. The model of coupled equilibria which included inorganic complexation, precipitation/dissolution of gypsum and multiple cation exchange was tested. Pyrite oxidation and pH-dependent silicate weathering were considered using simple input functions. Transport was modelled using a field capacity cascade submodel. Model results showed satisfactory agreement with measured values for pH and concentrations of SO₄, Fe, Mg, Ca and Al. Correlation coefficients lay between 0.7 and 0.9 and linear regression coefficients (modelled against measured) were 1.5 (Ca), 1.0 (Fe, SO₄), 0.8 (Mg), 0.7 (pH) and 0.6 (Al). The results showed that the protons produced during pyrite oxidation (94 mmol_c H⁺ kg⁻¹) were mainly released into seepage water (as HSO₄⁻ and H⁺). Cation exchange reactions buffered 20 mmol_c of H⁺ kg⁻¹ sediment, and Al released by silicate weathering accounted for 3.6 mmol_c H⁺ kg⁻¹. Modelling was useful to further understand the significance of different pH buffer reactions.     

Spatial variations in chemical compositions along Langtang–Narayani river system in central Nepal

Surface water samples were collected from Langtang Lirung glacier outlet point to the Narayani river system in central Nepal in order to investigate the role of elevation in the variation of chemistry along the drainage networks. The chemistry of Langtang–Narayani river system was dominated by sulfide oxidation coupled with carbonate dissolution and weathering of silicate minerals. Calcium and magnesium concentrations were relatively higher than other cations and the sum of both species strongly correlated with alkalinity, supporting the dissolution of carbonate and dolomite as the dominant source for these ions. Aluminosilicate minerals primarily as albite and anorthite appeared as dominant silicate minerals within the drainage basin. Bisiallitization was the dominant type of weathering within the entire drainage system. Hydrogen ion concentration was lower in the low elevation sites than in high elevation sites reflecting the more consumption of carbon dioxide in the low elevation sites due to enhanced chemical weathering rates. Furthermore, major solutes like sum of base cations, silicon as well as alkalinity increased in concentration in the lower elevation sites. All regulating factors appeared to be directly related to elevation and hence elevation appeared to be the prime factor for the variation in chemical species along the Langtang–Narayani river system. Toshiyuki Masuzawa: deceased.     

Formation of Colloidal Silica and Alumina During Experimental Granodiorite Weathering

The role of aluminum and silica in the formation of colloids during granodiorite weathering was studied on the basis of long-term experiments in batch reactors. Rock samples were dissolved in un-buffered solutions of initial pH 3.2, 5.4, and 9.9 at ambient conditions for 500 days. During weathering, extremely high supersaturation with respect to various secondary solids was attained in the solutions. Consequently, new solids, part of which was conserved in solutions as colloids, condensed. The mean concentrations of colloidal Si reached values of 70, 50, and 48 mol 1^–1 in the alkaline, neutral, and acid solutions, respectively. The mean concentrations of colloidal Al, reached values of 34, 22, and 12 mol 1^–1 in the alkaline, neutral, and acid solutions, respectively. The concentration of colloids gradually decreased after 200-400 days of experiment. This phenomenon was interpreted as being due to the competition between homogeneous nucleation and crystal growth. At the initial stages of the experiments, the colloidal species (predominantly colloidal Al) comprised a large proportion of the total amounts of aqueous species. Their share, however, decreased with time. The molar Al/Si-ratios of colloids were as high as 2–2.5 at the early stages of the experiment. After 250–300 days of experiments, on the other hand, these ratios decreased to values of about 0.5 in both the neutral and alkaline solutions and to a value of 0.15 in the acid solution. The evolution of colloids was consistent with the evolution of secondary solids in the sequence Al-hydroxides – clay minerals (illite, chlorite), in both the neutral and alkaline solutions. In acid solutions, the evolution of Al/Si-colloids was influenced by the presence of sulfate ion and Al-sulfate precipitation. Besides Al and Si, other elements, in particular Ca or Mg as a major component and Na, K, P, S, and Cl as minor components, readily participated in the formation of colloids.     

郑家王庄地区下第三系沙河街组砂砾岩扇体特征研究

利用现代沉积学理论结合测井和地震等资料，对郑家王庄地区砂砾岩扇体特征研究后认为：郑家王庄地区在下第三系以形成沙一、沙三、四段的较高水动力能砂砾岩扇体（冲积扇、扇三角洲、近岸水下扇）沉积体为主，其中沙三上亚段扇三角洲砂砾岩体是本区最主要的砂砾岩扇体类型，并具有较好的储集性能，是区内最主要的油气储集体；郑家王庄地区砂砾岩扇体沉积，强烈地受制于边界构造条件；其砂砾岩扇体沉积及其形态均受沉积相的控制，并具有复杂多变的特征，从而直接导致了本区油气藏的聚集和分布具有复杂多变的特点。     

Origin of PhosphoriteNodules of Lebedinsky Iron Deposit in Kursk Magnetic Anomaly （KMA） of the Russian Platform

INTRODUCTION TheKurskmagneticanomaly(KMA)coversnear ly120000km2andhasalengthof600kminSE NW direction,withawidthrangingfrom150kmto250 km.TheKMAbasinislimitedbytheDoneskPaleozoic massifinthesouthandthePrecambrianAzovsk podol skupliftinthesouth westanditsnorthernborderis markedbythecrystallinemassifupliftofVaronesh.0 c s TheLebedinskycomplexdepositislocatedinthecentral partoftheRussianplatformbetweenlatitude50°00′and50° 20′north,andlongitude34°00′and39°00′east,inthefron ti…     

Links between bulk sediment particle size and magnetic grain‐size: general observations and implications for Chinese loess studies

Using a combination of particle size analysis, magnetic measurements, scanning electron microscopy and transmission electron microscopy imaging, this study shows that in a wide range of depositional environments, there is a strong link between particle size classes and magnetic response, especially below the upper limit of stable single domain magnetic behaviour. Ferrimagnetic grain assemblages dominated by stable single domain magnetosomes regularly have peak susceptibility and remanence values in coarser grades than do those containing finer‐grained, viscous and superparamagnetic secondary magnetic minerals formed during pedogenesis. This effect is despite the fact that there is a one to two orders of magnitude size difference between the particle size boundaries (at 1 or 2 μm) and key domain state transitions (mostly below 0·05 μm). The implications of these results are explored using samples spanning 22 Myr of loess accumulation on the Chinese Loess Plateau. The results from the loess sections, complemented by data from low‐temperature magnetic experiments, show that there are subtle distinctions in mean ferrimagnetic grain‐size between the Pleistocene and Miocene parts of the record, thus allowing more refined rock magnetic interpretations of the fine‐grained ferrimagnetic mineral assemblages arising from the effects of weathering, pedogenesis and possibly diagenesis in the sections studied.     

Use of sample color to estimate oxidized Fe content in mine waste rock

 Color, a readily perceived feature of natural earth materials, including mine waste, often represents compositional variation as a result of oxidative processes involving Fe. Near surface samples from excavated trenches in a mine-waste rock pile were collected to investigate the relationship between color and contents of Fe, Cu, and S. The silt+clay fraction (<0.05 mm) was isolated from recognizable colored material of the bulk sample for determination of pH, total and extractable Fe and Cu, and bulk mineralogy. Rock fragments within the pile exhibited coatings of crystalline gypsum and amorphous Fe. These coatings result from weathering (secondary products) and play important roles in surface reactions of waste rock piles, such as adsorption of anions (SO₄ ^2–) or coprecipitation of Fe with Cu. The correlation between color (Hurst method) and extractable Fe was high. Although color is influenced by site conditions such as original mineral composition, materials handling, weathering conditions etc., the results suggest that color measurements may provide an inexpensive and rapid estimation for secondary iron compounds and associated sorbed elements. Received: 5 April 1998 · Accepted: 30 June 1998     

Mineralogical changes during intense chemical weathering of sedimentary rocks in Bangladesh

Bangladesh is situated in a subtropical to tropical climatic zone. A recently weathered crust has developed on sedimentary bedrock (sandstone, siltstone, shale and claystones) of Tertiary–Quaternary age. Weathered samples were collected from 16 sections totaling 68 samples and were analyzed mineralogically. The main primary minerals identified in the weathered crust of sedimentary rocks are quartz, plagioclase, K-feldspar, biotite, muscovite, sparse carbonate and epidote. The secondary minerals are kaolinite, illite, chlorite, gibbsite and goethite. Weathering initiated along the grain boundaries and cleavage planes of the minerals, forming small cloudy materials which were very difficult to identify. In the advanced stage of weathering, these cloudy materials have turned into secondary minerals. In region 1, high rain fall (7100 mm/yr) and monsoonic climate resulted in a kaolinite–gibbsite–goethite suite through the weathering of feldspars and biotite. The occurrence of gibbsite in the relatively elevated lands of Sylhet and Fe-kaolinite throughout the study areas is indicative of a humid–tropical climate during formation of the weathered crust.     

Cavernous Weathering in Aeolian Sandstones: An Example from the Yongningshan Hill of the Loess Plateau, Northwest China

Cavernous weathering is commonly found on sandstone slopes in different environments. Either a single dominant process or polygenetic agents require to be invoked in order to interpret the development. The Yongningshan hill of the central Loess Plateau is representative of cliff dwellings in Northwest China, which is characterized by well-developed cavernous weathering features and provides a good opportunity for the better understanding of sandstone weathering in the Loess Plateau. Multiple methods, including field survey, in-situ rock strength measurement, along with experiments on samples for microscopic observation, element composition and salt chemistry, were employed to investigate the controlling factors of cavernous weathering. The results show that cavern development is different on the four slopes with the western slope hosting massive honeycombs, tafoni and hardened surfaces. The porous and permeable aeolian sandstones are fundamental, because they provide space and pathways for the transportation of water and salt, honeycombs dominantly aligning within the lamination of cross-beds. The environmental factors such as the seasonal wetting and drying cycle, aeolian salt, moisture and water vapor are key factors for the development of cavernous weathering forms. The northern and northwestern wind-blown dust storms have brought abundant salts, the lengthier dry periods of the wetting and drying cycle being beneficial for salt accumulation within caverns, favoring salt weathering.