陕西黑河流域地下水水化学特征

2017年在秦岭黑河流域7个采样点进行地下水样品采集。通过综合分析、Gibbs图、Piper三角图、主要离子比值法、主成分分析法得出黑河地下水化学成分的特点、水化学类型及其成因。结果表明:阳离子的主要组成成分是Ca^2+,HCO3^-是阴离子的主要组成成分,黑河流域地下水化学类型为HCO3^--Ca^2+和SO4^2--HCO3^--Ca^2+型。Gibbs图分析得出该地下水化学离子组成受岩石风化作用控制;Piper三角图、主要离子比值法、主成分分析及相关分析表明,地下水化学组分主要受方解石、白云岩等碳酸盐岩矿物的风化溶解,同时伴有硫酸溶解碳酸盐岩,受硅酸盐岩的溶解控制作用较小。     

可可西里苟仁错湖泊沉积物元素地球化学特征及其环境意义

湖泊沉积物元素地球化学特征及其比值，有效地揭示了湖泊沉积物物源区的化学风化程度．已成为反映古气候波动的有效指标。根据可可西里苟仁错湖泊沉积物的元素地球化学特征，通过CIA，ICV等元素比值的结果，揭示该地区1400AD以来化学风化作用十分微弱，因此湖泊沉积物元素组成，对气候变化非常敏感。研究表明1400AD以来该地区气候经历多次冷暖波动，且呈干旱化的趋势，1420AD左右进入小冰期，其中1480～1520AD最为寒冷，1900AD后干旱化加剧。     

Engineering characteristics and uses of duricrusts in Australia

The uses and shortcomings of duricrusts (ferricrete, calcrete and silcrete) in engineering construction (as used for road‐base, aggregate, foundation materials and aquifers) are reviewed. Australian production of these materials represents about one‐third of all unprocessed road‐base and they are especially important as pavement courses for lightly trafficked, low‐cost rural and outback roads. However, duricrusts are regarded as marginal materials at best because of their typically poor grading, particle unsoundness, high fines plasticity, and absorption of water and bitumen. These materials are used because they are available locally in areas that are otherwise lacking in hard rock materials, such as deeply weathered and sedimentary rock terrains. The weathering profiles of which they form part are characterized by high permeability (despite being clay‐rich), variable cementation, low compressibility and a tendency to become weaker with depth. Although the more indurated layers are unrippable, they are also difficult to blast. Pedogenic (nodular) duricrusts were formerly sought for natural road‐base, because they occur widely and require only rudimentary processing. However, well‐cemented groundwater (vadose) duricrusts are now the preferred deposits, even though they require crushing and screening. Ferricrete is the most widely exploited of the duricrusts for engineering purposes, especially in northern and southwestern Australia, although calcrete is important in South Australia and in the Murray Basin. Silcrete is only a minor source of aggregate and road‐base, mainly in western Queensland.     

The freeze-thaw weathering regime at a section of the Niagara escarpment on the Bruce Peninsula,Southern Ontario,Canada

The bedrock freeze-thaw and moisture regimes at an actively eroding site on the Niagara Escarpment, Bruce Peninsula, southern Ontario, were monitored between December 1983 and April 1984, and the results compared with amounts of debris collected in an adjacent rock trap. Frost wedging in pre-existing rock fissures is the primary mechanism responsible for the observed rockfall events; hydration effects are negligible. Debris production was more closely related to the duration of the freezing leg of the freeze-thaw cycle than to intensity or to cycle frequency. Release also coincided with periods of high pore saturation (> 60 per cent) and the seepage of water from cracks and fissures. Fewer freeze-thaw cycles were recorded in the air than at 1 and 3.5 cm in the bedrock. The number of cycles that could be declared geomorphologically effective according to established temperature criteria was normally less than half the total number of freeze-thaw cycles recorded in both air and bedrock. Under the current temperature regime at the field site, few effective cycles are capable of penetrating more than 5 cm into the free face.     

大连新港的红粘土及其工程特性的形成

在大连新港油罐区的建设中,发现了一种具有高孔隙性、高含水量、高塑性、中低压缩性的特殊土。作者对这种土及其母岩的矿物学、岩石学、地球化学、物理化学和工程特性进行了系统研究,揭示了该区红粘土及其工程特性的形成机理,该区红粘土乃是蒙脱石化的粗玄岩,在中温带气候区红土花作用的产物。     

论宁夏金场子渗流热卤水-表生改造型金矿床的矿源

稳定同位素、岩石微量元素(金)和地质特征研究的结果,表明金场子金矿床的成矿物质来源系上地壳源,并且金、银、铅、铜等金属和硫、硒、砷、氯、氟、碳等来源于石炭纪和泥盆纪沉积岩。成矿流体是大气水和沉积地层水的混合溶液。金矿化与地热流体渗流热卤水成矿作用和表生风化成矿作用有关。     

Tafoni on coastal slopes,South Devon,U.K.

Cavernous weathering (tafoni development) occurs on coastal slopes in greenschist bedrock at elevations up to 40 m above sea level. The freshly weathered surfaces of the cavern interiors are irregular in morphology, discordant to major rock structure, formed by substantially weakened rock and associated with granular weathering debris. The weathering debris contains soluble elements in proportions similar to those present in seawater, and the penetration of elements associated with sea salts into the weathering surface to estimated depths of at least 0·1–0·2 m is indicated by the presence of chlorine. Scanning electron microscopy and microprobe analyses suggest that rock breakdown occurs principally through limited chemical weathering at grain boundaries. The mechanism for the emplacement of marine salts within sheltered rock surfaces in the tafoni is postulated to be a combination of dry deposition under turbulent atmospheric conditions and wetting by coastal fog.     

风化壳淋积型稀土矿床成矿机理的实验研究

风化壳淋积型稀土矿床是很重要的一种矿床类型。作用采用水析法提取了梧州市区风化壳淋积型稀土矿床中的粘土矿物，并进行了钕和镱的吸附实验研究。实验结果表明，在不同的实验体系中，吸附反应达到平衡的时间是不同的，２％ＨＣ１至少１２ｈ，１％ＨＣ１至少０．１ｈ。影响粘土吸附稀土的物理化学因素有：溶液浓度，溶液酸碱度（ｐＨ值），离子强度，固液比和温度等。在ｐＨ值较低的相同实验条件下，轻稀土的吸附效率要明显高于重稀     

Remeasurement of weathering rates,St. Paul's Cathedral,London

Remeasurements of weathering rates at six sites on the base of the balustrade of St. Paul's Cathedral gave substantially lower mean results (0.06 mm a^?1, 1980–1985) than for earlier results (0.14 mm a^?1, 1980–1981). Statistical analysis of the data showed that for five of the sites there were no significant differences between the measurement periods. The only significant spatial difference was for the southwest (exposed) site which was greater than the other sites for 1980–1981, but not at later times. This site also showed the only significant decrease over time. If this site is included in the statistical analysis, the whole set shows a significant decrease over time; omitting this site from the data removes any significant differences over time. The results for this one site for 1980–1981 thus have significant bias on the data body as a whole. Methodological problems, such as rock erosion by the probe and temperature effects, are thought to have minimal effect on the interpretation of the data. Calibrations showed that measurements were accurate to ±0.006 mm and that only results of a change ≥ 0.02 mm were reliably interpretable as different. Remeasurements of the Lead Plug Index (LPI) for the top of the balustrade in 1987 gave a mean rate for 1718–1985 of 0.081 mm a^?1. This is not significantly different from the 1718–1980 mean rate of 0.078 mm a^?1 but the data are not directly comparable, the 1987 sample being smaller than the 1980 set. For the 1987 data, the only statistically significant differences are for the southeast rate ≧ northeast and for a rise in rate in the northeast quadrant. The LPI data are comparable to most of the 1980–1985 MEM data. The conclusion is that most erosion rates have neither increased nor decreased significantly in the measurement time, except for a significant decrease at one (southwest) site from 1980–1981 to 1981–1982. Such a sustained level of erosion gives cause for concern in the context of stone conservation. Causative factors of air quality are discussed and while SO₂ levels have decreased, NO₂ and smoke levels show increases. An overall decrease in stone decay in association with the decrease in SO₂ levels is thus not in evidence.