1993年7—9月的全球地震动态

１９９３年第三季度，全球地震活动水平为中等偏高，明显高于上半年平均水平。日本北海道西南近海发生７．６级浅源地震，但不属于日本海沟地震。埃及西奈半岛发生５．７级地震，为今年亚欧带西段之最大地震。马里亚纳群岛发生８．１级中深震，使西北太平洋地区地震水平达到全球第一。兴都库什地区接连发生三次较大中深震，可能对我国西部地区地震活动有影响。墨西哥恰帕斯州近海发生７．３级地震，美洲带新的地震活动轮回正式开始。印度南部发生６．３级中强震，属于板内地震。     

Field measurements of NO and NO2 emissions from fertilized and unfertilized soils

Field measurements of NO and NO₂ emissions from soils have been performed in Finthen near Mainz (F.R.G.) and in Utrera near Seville (Spain). The applied method employed a flow box coupled with a chemiluminescent NO _x detector allowing the determination of minimum flux rates of 2 g N m^-2 h^-1 for NO and 3 g m^-2 h^-1 for NO₂.The NO and NO₂ flux rates were found to be strongly dependent on soil surface temperatures and showed strong daily variations with maximum values during the early afternoon and minimum values during the early morning. Between the daily variation patterns of NO and NO₂, there was a time lag of about 2 h which seem to be due to the different physico-chemical properties of NO and NO₂. The apparent activation energy of NO emission calculated from the Arrhenius equation ranged between 44 and 103 kJ per mole. The NO and NO₂ emission rates were positively correlated with soil moisture in the upper soil layer.The measurements carried out in August in Finthen clearly indicate the establishment of NO and NO₂ equilibrium mixing ratios which appeared to be on the order of 20 ppbv for NO and 10 ppbv for NO₂. The soil acted as a net sink for ambient air NO and NO₂ mixing ratios higher than the equilibrium values and a net source for NO and NO₂ mixing ratios lower than the equilibrium values. This behaviour as well as the observation of equilibrium mixing ratios clearly indicate that NO and NO₂ are formed and destroyed concurrently in the soil.Average flux rates measured on bare unfertilized soils were about 10 g N m^-2 h^-1 for NO₂ and 8 g N m^-2 h^-1 for NO. The NO and NO₂ flux rates were significantly reduced on plant covered soil plots. In some cases, the flux rates of both gases became negative indicating that the vegetation may act as a sink for atmospheric NO and NO₂.Application of mineral fertilizers increased the NO and NO₂ emission rates. Highest emission rates were observed for urea followed by NH₄Cl, NH₄NO₃ and NaNO₃. The fertilizer loss rates ranged from 0.1% for NaNO₃ to 5.4% for urea. Vegetation cover substantially reduced the fertilizer loss rate.The total NO _x emission from soil is estimated to be 11 Tg N yr^-1. This figure is an upper limit and includes the emission of 7 Tg N yr^-1 from natural unfertilized soils, 2 Tg N yr^-1 from fertilized soils as well as 2 Tg N yr^-1 from animal excreta. Despite its speculative character, this estimation indicates that NO _x emission by soil is important for tropospheric chemistry especially in remote areas where the NO _x production by other sources is comparatively small.     

The global distribution of methane in the troposphere

Methane has been measured in air samples collected at approximately weekly intervals at 23 globally distributed sites in the NOAA/GMCC cooperative flask sampling network. Sites range in latitude from 90° S to 76° N, and at most of these we report 2 years of data beginning in early 1983. All measurements have been made by gas chromatography with a flame ionization detector at the NOAA/GMCC laboratory in Boulder, Colorado. All air samples have been referenced to a single secondary standard of methane-in-air, ensuring a high degree of internal consistency in the data. The precision of measurements is estimated from replicate determinations on each sample as 0.2%. The latitudinal distribution of methane and the seasonal variation of this distribution in the marine boundary layer has been defined in great detail, including a remarkable uniformity in background levels of methane in the Southern Hemisphere. We report for the first time the observation of a complete seasonal cycle of methane at the South Pole. A significant vertical gradient is observed between a sea level and a high altitude site in Hawaii. Globally averaged background concentrations in the marine boundary layer have been calculated for the 2 year-period May 1983–April 1985 inclusive, from which we find an average increase of 12.8 ppb per year, or 0.78% per year when referenced to the globally averaged concentration (1625 ppb) at the mid-point of this period. We present evidence that there has been a slowing down in the methane growth rate.Presented at the Conference on the Scientific Application of Baseline Observations of Atmospheric Composition (SABOAC), Aspendale, Australia, 7–9 November 1984.     

Termites and global methane—another assessment

New CH₄ emission data from a number of Northern and Southern Hemispheric, tropical and temperate termites, are reported, which indicate that the annual global CH₄ source due to termites is probably less than 15 Tg. The major uncertainties in this estimate are identified and found to be substantial. Nevertheless, our results suggest that termites probably account for less than 5% of global CH₄ emissions.     

The Chemical Composition of Global Subducting Sediments and Its Geological Significance

Subducted sediments play an important role in crust-mantle interaction and deep mantle processes, especially for subduction zone magmatism and mantle geochemistry. The current rate of Global Subducting Sediments (GLOSS) is 0.5~0.7 km³/a. The GLOSS are composed of terrigenous material(76 wt.%), calcium carbonate(7 wt.%), opal(10 wt.%) and mineral-bound H₂O⁺(7 wt.%). The chemical compositions of GLOSS are similar to those of upper continental crust which is mainly controlled by the terrigenous materials, and yet the materials formed by marine processes will dilute the terrigenous materials. The components of subducted sediments are different among trenches. In the accretionary margin, the components of subducted sediments are similar to those of the upper crust, while in the non-accretionary margin the components are terrigenous materials plus those produced by marine processes. During subduction, subducted sediments will released fluids, melt or supercritical fluid to affect island arc/back-arc basin magmatism by means of aqueous fluid or sediment melt. In addition, a part of subducted sediments, together with underlying altered oceanic crust/lithosphere, recycle into the mantle and contribute to the mantle heterogeneity. Geochemical tracers indicate that subducted sediments play variable contributions to the magmatic processes in different tectonic setting. Thus, subducted sediments play an important role in two relatively independent dynamics systems (plate tectonics and mantle plume), as well as related mantle evolution models. As a result, by accurately calculating the compositions of subduction sediments and using various geochemical indicators, we can further limit the input and output fluxes of various elements or isotopes, and then obtain more accurately residual subducted components, which can provide us some important clues for geodynamic process.     

关于大陆构造的思考

大陆动力学与全球动力学是当代地学的重在前沿领域。本文在研究青藏高原与周缘盆地的同步演化规律和综合前人最新研究成果的基础上，分析了大陆构造的１０个基本问题，并进一步阐述了层流构造模式，其内容包括：（１）深部层流导致浅部隆陷；（２）层流隆陷构造系统的物质循环过程；（３）大陆层块结构与地温场，应力场的关系；（４）层流构造的阶段发展与复合叠加；（５）层流构造的深部过程及动力学源，特别强调指出应当区大分陆隆     

全球旋回地层学

全球旋回地层学是指在对全球沉积岩进行综合系统研究之基础上，通过估算沉积盆地中源于物源区的沉积物类型和沉积环境条件变化，来预测地层学特征的一种过程一结果模型。其研究内容包括对全球地质演化时期全球海平面变化、全球气候条件、全球构造运动、全球古地理背景、全球沉积环境特征、全球古生物事件及全球矿产形成过程进行动态模拟，强调古气候在地质记录中的意义，注重沉积记录的全球同时性研究；强调各种事件在沉积作用中的意     

古新统─始新统界线与事件沉积

深海钻探揭示的古新统—始新统界线上许多全球性变化引起了地质学家的普遍关注。这些变化包括：岩性上从海绿石石英砂岩变化到粘土岩、粘土矿物组合从伊利石／蒙脱石为主变化为高岭石为主、大陆植物群的绝灭和迁移、钙质超微化石物种更新速度加快、底栖有孔虫绝灭和分异度降低、碳氧同位素强烈负异常、大陆哺乳动物演化发生变化、大气环流强度减弱、海洋环流模式改变、海平面上升、海底热液活动呈１～２个数量级加强。通过对古新世—始新世的地层沉积学、古生物学、古气候学和古海洋学研究，确认古新统—始新统地层界线是全球构造事件的结果，表现为全球板块边界重组、扩张中心和转换断层模式改变、海底热液活动呈１～２个数量级加强。     

Emission of aliphatic amines from animal husbandry and their reactions: Potential source of N2O and HCN

We measured the emissions of volatile aliphatic amines and ammonia produced by the manure of beef cattle, dairy cows, swine, laying hens and horses in livestock buildings. The amine emissions consisted almost exclusively of the three methylamines and correlated with those of ammonia. The molar emission ratios of the methylamines to ammonia, and data on NH₃ emissions from animal husbandry in Europe, together with global statistics on domestic animals, were used to estimate the global emissions of amines. Annual global methylamine-N input to the atmosphere from animal husbandry in 1988 was 0.15±0.06 TgN (Tg=10¹² g). Almost 3/4 of these emissions consisted of trimethylamine-N. This represents about half of all methylamine emissions to the atmosphere. Other sources are marine coastal waters and biomass burning.Possible reaction pathways for atmospheric methylamines are shown. Among various speculative but possible products N₂O and HCN are of interest because the emission of methylamines could contribute to the global budgets of these compounds. Maximum atmospheric N₂O production from methylamines are below 0.4 Tg N/year, which is less than 10% of the annual N₂O growth rate. Although we do not expect the methylamine emissions to contribute in a major way to the atmospheric N₂O budget, more studies are needed to establish this conclusion beyond doubt. Similar conclusions hold for HCN.     

1994年全球地震活动综述

１９９４年全球地震活动属于高水平，有４次大深震和４次浅源大地震。全球全年共发生６级以上地震１３４次，超过１９９３年。全球地震活动中心仍在太平洋西北边缘地震带。１０月４日的千岛群岛地震是最大的浅源地震；６月９日的玻利维亚地震是最大的深源地震。１９９４年全球地震活动开始转折，揭开强烈活动期的序幕。各大地震带的Ａ（ｂ）值几乎按同一比例上升，显示全球地震整体性增强。全球地震Ａ（ｂ）值在６月和１０月有两次高