天文(重力)水准的新手段及其计算方法

介绍当今确定天文大地垂偏差的新仪器－CCD自动天体测量仪和确定两点间高程异常差的新方法，该方法用单极坐标代替繁琐的双极坐标进行计算，讨论了天文重力水准的误差及垂线偏差非线性影响等问题，估计在不久的将来，用这一手段施测山区似大地水准面的精度可望达到厘米级。     

基于移动式监测的道路PM2.5浓度精细化时空模拟

作为主要的大气污染指标,PM_2.5浓度常来源于固定环境监测站点的监测与遥感影像数据,但时空精度普遍不足,难以揭示微尺度下城市内部PM_2.5时空分布情况。本文利用移动式监测方法,选择典型工作日(2017年11月27日),对广州市主城区道路以1 s和1 m为时空粒度进行PM_2.5浓度数据采集,并以早、晚出行高峰时段为对象,通过机器学习方法模拟道路PM_2.5精细化时空分布格局。结果表明,主城区早高峰道路PM_2.5浓度值相近的平均范围为24 m,晚高峰为15 m,PM_2.5浓度存在微尺度的时空异质性。利用多层感知器(MLP)构建的早、晚高峰PM_2.5浓度模型,拟合度分别达到0.70和0.68,明显优于传统的普通最小二乘法(OLS)线性回归模型。模型揭示出早高峰主城区全路网PM_2.5平均浓度为30.19μg/m3,晚高峰达到44.55μg/m3,部分高达94.82μg/m3,且“西高东低”的分布特征显著。本文提出的PM     

Characterisation of tobelite (NH4)Al2[AlSi3O10](OH)2 and ND4-tobelite (ND4)Al2[AlSi3O10](OD)2 using IR spectroscopy and Rietveld refinement of XRD spectra

Tobelite (NH₄) Al₂ [AlSi₃O₁₀] (OH)₂, the ammonium analogue of muscovite, and its deuterated form ND₄-tobelite (ND₄) Al₂ [AlSi₃O₁₀] (OD)₂ have been synthesised at 600?°C and 200 and 500 Mpa using a well homogenised, stoichiometric SiO₂-Al₂O₃ oxide mix with Al₂O₃ in excess of 5 mol% and a 25% NH₃ solution whose relative abundance was such that the amount of NH₄ ⁺ stoichiometrically available was in excess of 50%. Characterisation of both tobelite and ND₄-tobelite using IR-spectroscopy, Rietveld refinement of X-ray powder diffraction data, and electron microprobe analysis indicate that, similar to K⁺ in muscovite, the NH₄ ⁺ or ND₄ ⁺ molecule occupies the interlayer site. IR absorption bands caused by NH₄ ⁺ and ND₄ ⁺ can be explained, to a very good approximation, on the basis of T_d symmetry. Nevertheless, substantial line broadening and the occurrence of shoulders indicate a deviation from ideal T_d symmetry. However, even at 77?K, no discrete splitting of the degenerate states could be confirmed. The OH stretching frequencies observed for synthetic tobelite are quite similar to those for muscovite, indicating that the replacement of K⁺ by NH₄ ⁺ has no effect. The low FWHH of the OH bands indicate that the hydroxyl groups are well ordered within the structure. Rietveld refinement of tobelite and ND₄-tobelite indicates that all samples synthesised consist of the 3 different mica polytypes which are typical of muscovite – namely 1M (C2/m), 2M ₁ (C2/c) and 2M ₂ (C2/c). Tobelite and ND₄-tobelite synthesised at 500 Mpa principally contain the 1M polytype, whereas the principle polytype for ND₄-tobelite synthesised at 200 Mpa, is 2M ₂. Rietveld refinement of X-ray diffraction spectra for tobelite synthesised at 200 Mpa was problematic due to the very broad FWHH of the X-ray peaks indicating poor crystallinity. In comparision to synthetic muscovite, the cell dimensions observed for tobelite and its deuterated analogue are quite similar except for the lattice constant c. Due to the larger radius of NH₄ ⁺ or ND₄ ⁺ compared to K⁺ cation, the c-direction is expanded form 10.275 Å in muscovite to approximately 10.540 Å in tobelite and ND₄-tobelite.     

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The reduction of aliasing in gravity anomalies and geoid heights using digital terrain data

Observations of gravity can be aliased by virtue of the logistics involved in collecting these data in the field. For instance, gravity measurements are often made in more accessible lowland areas where there are roads and tracks, thus omitting areas of higher relief in between. The gravimetric determination of the geoid requires mean terrain-corrected free-air anomalies; however, anomalies based only on the observations in lowland regions are not necessarily representative of the true mean value over the topography. A five-stage approach is taken that uses a digital elevation model, which provides a more accurate representation of the topography than the gravity observation elevations, to reduce the unrepresentative sampling in the gravity observations. When using this approach with the Australian digital elevation model, the terrain-corrected free-air anomalies generated from the Australian gravity data base change by between 77.075 and −84.335 mgal (−0.193 mgal mean and 2.687 mgal standard deviation). Subsequent gravimetric geoid computations are used to illustrate the effect of aliasing in the Australian gravity data upon the geoid. The difference between 'aliased' and 'non-aliased' gravimetric geoid solutions varies by between 0.732 and −1.816 m (−0.058 m mean and 0.122 m standard deviation). Based on these conceptual arguments and numerical results, it is recommended that supplementary digital elevation information be included during the estimation of mean gravity anomalies prior to the computation of a gravimetric geoid model.     

新疆全区域似大地水准面的建立

简述了大地水准面精化的方法、原理及新疆似大地水准面确定的过程。     

局部大地水准面精化系统软件的设计与实现

给出了局部大地水准面精化系统的总体结构以及各分系统的详细设计与实现方法,开发了旨在对相关重力测量数据实现自动化处理的局部大地水准面精化系统工具软件,并应用于某区域实际大地水准面的精确计算。实践证明,该系统能有效提高相关数据的处理效率,有助于局部大地水准面精化过程的规范化。     

EGM96/2008重力场模型在似大地水准面构建中的应用

似大地水准面的构建可以将GPS测量的高程迅速转化为正常高,极大降低高程测量的成本,提高相关工作效率。将EGM96/2008重力场模型与“移去-恢复”法相结合,在矿区内建立似大地水准面,并使用不同的插值方法,验证最优方案。结果表明,使用二次线性插值的EGM2008重力场模型拟合效果更好,模型外符合精度达到3.6 mm,更适合应用于该区域似大地水准面构建。     

水平面代替水准面对两井贯通的影响

理论结合实际,用详实的数据说明了在两井贯通时,把水准面当作水平面处理的界限,避免了盲目应用而产生严重后果.