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101.
102.
Hang Li Dahua Li Tangfu Xiao Libin He Zengping Ning Jialong Sun Changsheng Zhu Yan Shuang 《中国地球化学学报》2008,27(1):21-27
The Jinding Pb-Zn deposit in Yunnan Province is the representative of a Cd-enriched area and mining activities lead to the release of Cd into the hypergenic ecosystem, resulting in Cd pollution. The concentrations of Cd vary greatly from one type to another type of rocks in the mining district. In the host rock, Cd concentrations range from 50×10^-6 to 650×10^-6 with an average of 310×10^-6. In primary ores, Cd concentrations range from 14×10^-6 to 2800×10^-6 with an average of 767×10^-6. However, in oxidized ores, Cd concentrations are highest, varying within the range of 110×10^-6 to 8200×10^-6 , averaging 1661×10^-6. It is shown that the oxidized ores are the main carder and environmental source of Cd. Leaching test showed that Pb/Zn ores are easy to oxidize and thereafter release Cd and other harmful elements. These leached elements in the leachate may be precipitated rapidly in the order of Zn〉Pb〉Cd. As for the concentration distribution of Cd in the Bijiang River, it is estimated to be 15.7 μg/L Cd in water, 49.3 mg/L in suspended substances, and 203.7 mg/L in sediments. The average value of Cd in soil from the polluted area is 83.0 mg/kg. Natural weathering of Cd-rich rocks and minerals imposes a potential environmental risk on the aquatic ecosystem of the Bijiang catchment. 相似文献
103.
Extensive organic-matter (OM) rich facies (black shales) occur in the Ordo-Silurian boundary successions in the Yangtze area, South China. To investigate the redox changes of the Yangtze Sea during the Ordo-Silurian transition, two OM sections (Wangjiawan in Yichang, Hubei Province, and Sanjiaguan in Zhangjiajie, Hunan Province) straddling the Ordo-Silurian boundary are studied. The measurements finished in this study include contents of the total organic carbon (TOC), pyrite sulphur, and different species of Fe, including dithionite-extractable Fe (FED), pyrite Fe (FeP), HCl-extractable Fe (FeH), and total Fe (FeT), in black shales, as well as other redox proxies, such as the SIC ratio, the ratio between highly reactive Fe (FeHR = FeD + FeP) and FeT, and the FeP/(FeP + FeH) ratio, known as the degree of pyritization (DOP). In the Wangjiawan section, the Middle Ashgill sediments have high FeHR/FeT ratios (0.20-0.77; avg. 0.45), high DOP values (0.21-0.72; avg. 0.54), and a relatively constant sulfur content independent of the organic carbon content. By the contrast, the mid-early Hirnantian deposits generally have low FeHR/FeT ratios (0.10-0.35; avg. 0.21), low DOP values (0.11- 0.40; avg. 0.28), and SIC values are clustering on the normal marine value (SIC = 0.36). The late Hirnantian and early Rhuddanian deposits, similar to those of the Middle Ashgill deposits, are characterized by high FeHR/FeT ratios (0.32-0.49; avg. 0.41), high DOP values (0.46-0.68; avg. 0.53) and fairly constant sulfur contents. These data suggest the occurrences of marine anoxia on the Yangtze Sea shelf during intervals of the Mid Ashgill, Late Hirnantian and Early Rhuddanian, and ventilated and oxygenated marine conditions during the mid-early Hirnantian time. The mid-early Hirnantian ventilated event was concomitant with the global glacial period, likely resulted from the glacio-eustatic sea-level fall and subsequent circulation of cold, dense oxygenated waters 相似文献
104.
水仙花为福建省特色农业之一,简要介绍了漳州水仙花生长特性,初步探讨了水仙花生长区的地貌、地层岩性、水文地质和地球化学背景,建议选择与原水仙花田农业地质背景相似的西洋坪一带作为发展基地。 相似文献
105.
大金山铅锌矿位于泰宁一政和北东东向铜多金属成矿带上,是该成矿带主要的矿种之一,也是闽北地区一个较有价值的矿床。矿床产于早元古代南山组上段,受燕山期北东东向构造控制,属中低温热液充填交代型矿床。 相似文献
106.
河南桐柏围山城层控金银成矿带同位素地球化学 总被引:8,自引:2,他引:6
河南省桐柏山区的围山城金银成矿带包括破山特大型银矿、银洞坡大型金矿、银洞岭大型银多金属矿床及一些矿点,赋矿地层是新元古界歪头山组,矿体产状与地层产状一致,形态呈似层状、鞍状或透镜状,层控特征显著。氢-氧-碳同位素地球化学研究指示早、中阶段的成矿流体主要为变质水,晚阶段有大量大气降水加入成矿流体系统。碳-硫-铅同位素指示成矿物质来自于歪头山组地层;钾-氩同位素表明成矿作用(100~140Ma)发生在秦岭陆陆碰撞造山的高峰期之后碰撞挤压向伸展转变的背景下。综合考虑矿带的成矿流体来源、成矿物质来源以及矿床地质特征,认为围山城成矿带属典型的层控造山型金银成矿系统,形成于中生代扬子与华北板块的陆陆碰撞造山体制。 相似文献
107.
Elisa Sacchi Gian Maria Zuppi Luca Pizzino Fedora Quattrocchi Salvatore Lombardi 《Aquatic Geochemistry》2008,14(4):301-319
The EC funded Geochemical Seismic Zonation program (EEC GSZ Project 1996–1998) chose Sardinia as a low-seismicity site, in which the relationships between fluid geochemistry and seismo-tectonics
had to be investigated and results compared with outcomes from other selected high-seismicity sites. A first article, examining
the role of fault segmentation and seismic quiescence on the geochemical composition of groundwaters and gases, has already
been presented (Angelone et al. 2005). This article deals with environmental isotopes which, together with selected hydrochemical data, give hints on tectonically-related
fluid circulations. Four water-dominated hydrothermal systems were considered, all located along regional fault systems and
discharging groundwaters belonging to the Na–HCO3 and Na–Cl facies. In the considered systems, groundwater circulation takes place, principally, in the Palaeozoic Crystalline
Basement (PCB), with the exception of the Logudoro system, where hydrological circuits develop in the Mesozoic Carbonate Platform
(MCP). The high CO2 contents, the non-attainment of fluid-rock equilibrium and the large lithological variability prevent the construction of
a unique hydrogeological–geochemical conceptual model. In this case, stable isotopes provide a useful tool to describe the
origin of fluids and their subterranean movements. Stable isotopes of water, integrated with hydrochemical data, indicate
that fluids are derived from three main end members. The dominant component is a relatively recent local meteoric water; the
second one is marine water; and the third one is a fossil freshwater, depleted in heavy isotopes with respect to modern rains.
The latter end member entered the aquifer system in the past, when climatic conditions were greatly different from today.
At least two circulation systems can be recognised, namely a shallow cold system and a deep hydrothermal system, as well as
two distinct hydrological processes: (1) gravity-controlled descent of cold water towards greater depths and (2) convection
linked to a thermal gradient, causing deep fluids to rise up from the hydrothermal reservoir towards the surface. The highly
variable δ13CTDIC values suggest the presence of two distinct CO2 sources, namely, a biogenic one and a thermogenic one. The relation between the isotopic compositions of CO2 and He indicates an increased mantle signature in uprising CO2-rich fluids. 相似文献
108.
Taeko Shinonaga Helmuth Aigner Dilani Klose Peter Spinder Heinz Fröschl David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101
The recommended concentrations of 239Pu, 240Pu and 239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of 239Pu and 240Pu (239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of 242Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg?1, (28 ± 3) Bq kg?1 and (66 ± 4) Bq kg?1 are proposed as recommended values for 239Pu, 240Pu and 239+240Pu, respectively, and (9.5 ± 0.4) Bq kg?1 for 238Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg?1, (3.3 ± 0.4) ng kg?1 and (0.015 ± 0.003) ng kg?1 for 239Pu, 240Pu and 238Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study. 相似文献
109.
作为GPS/重力边值问题理论及方法的应用,在对GPS/重力方法确定(似)大地水准面的原理进行简要介绍与分析的基础上,利用收集到的N区的600个GPS/重力数据和48个高精度GPS水准数据,计算出该区域的(似)大地水准面。通过拟合法和系统差直接改正法进行的精度分析表明,应用GPS/重力数据结合水准方法确定的该地区(似)大地水准面的精度达到厘米级精度。 相似文献
110.
R. A. Oktyabrsky A. A. Vrzhosek A. M. Lennikov T. A. Yasnygina S. V. Rasskazov E. Yu. Moskalenko T. A. Velivetskaya 《Russian Journal of Pacific Geology》2008,2(4):325-335
New geochemical data are presented on the magmatic rocks of the Late Jurassic Koksharovka alkaline-ultrabasic massif, which is associated with deposits of vermiculite, apatite, V-bearing titanomagnetite, and placer isoferroplatinum. The REE geochemistry and strontium, oxygen, and carbon isotopic composition of carbonatites and related ijolites and pyroxenites, together with geological observations, point to the magmatic origin of the Koksharovka carbonatites. The origin of associated magmatic rocks is discussed. Trace element modeling of partial melting of mantle sources was conducted to decipher the genesis of the melts of the Koksharovka carbonatites and host titanite-kaersutite pyroxenites. 相似文献