南海北部含油气构造上方化探异常研究

在南海北部利用地球化学方法作为油气勘探的一种辅助手段。在6个航次中采集了沉积物、底层海水及海面大气样品，测定了近50种化探指标，并采用稳健统计方法进行了数据处理和异常圈定。化探结果在油气藏上方发现了清晰的、具不同指标组合的综合化探异常，与邻近空构造形成鲜明的对照。圈闭顶部的块状异常和圈闭周绿的环状、半环状异常是下伏油气藏的良好指示，而剖面上呈锯齿状、平面上呈线状的异常则与断裂带有关。实践表明，建立已知油气藏上方的化探异常模式及解剖已知空构造上方的地球化学特征对于指导本区或邻区的化探异常评价是十分必要的。     

粘土矿物去除赤潮生物的动力学研究

于１９９２年４－９月进行粘土矿的絮凝赤潮生物（微型原甲藻）的动力学研究；考察粘土种类、浓度、第二组分（ＰＡＣＳ）和ＰＨ等因素对絮凝速率的影响，建立粘土矿物絮凝赤潮生物的动力学模型，从理论上分析和讨论各种因素的影响，并提出提高絮凝速率的方法和途径。结果表明，高岭土体系絮凝速率大于蒙脱土体系，其速率方程可用双分子反应来描述。其中，速率常数随絮凝过程发生变化；粒子间的相互作用能和作用半径是控制和影响絮凝     

低硼氢氧化镁的制备及热分解动力学参数

本文以水合氯化镁、工业氨水为原料制备出了低硼含量的纯度 >99%的氢氧化镁和氧化镁。利用差热 -热重 (DTA- TG)、X-射线衍射 (XRD)、透射电子显微镜 (TEM)等手段 ,对氢氧化镁的热稳定性、相结构、表观状态以及脱水动力学参数进行了分析。结果为 :氢氧化镁以束状纤维和片状粉末共存 ,在 6 2 3K基本完成脱水反应生成氧化镁 ,其脱水反应的表观活化能 E为135 .4 k J· mol-1,指前因子 A为 5 .15× 10 10 ,反应级数 n为 1.10     

Elemental geochemical records of seafloor hydrothermal activities in the sediments from the Okinawa Trough

The major and minor element contents in the sediment core H9 from the hydrothermal fields of the Okinawa Trough show a sharp change at the depth of 80 cm. The elements enriched in the upper 80 cm core are those enriched in the hydrothermal deposits and in the surface sediments recovered from the hydrothermal fields in the trough, which indicates the input of hydrothermal materials. Comparing with other hydrothermal sediments from Mid-ocean Ridges or the Lau Basin, the degree of the enrichment of elements iron, copper,cobalt, and nickel is relatively low. However, the enrichment of elements manganese, lead, arsenic, antimony and mercury is remarkable. The average contents of these elements in the upper 80 cm core sediments are three to six times those in the lower section, and 3~12 times those in the surface sediments which are not influenced by hydrothermal activities. Hydrothermal activities have contributed significant manganese, lead, arsenic, antimony and mercury to the sediments, and these elements are distinct indicators for the hydrothermal activity in the Okinawa Trough. The significant enrichment of these elements in Core H9 upward from the depth 80 cm indicates the start or the significant enhancing of the hydrothermal activity in this area at about 5 740 aB.P. The average accumulation rate of manganese during this period is about 40 461 μg/(cm2·ka), which is similar to the hydrothermal sediments in the Lau Basin or the East Pacific Rise.     

南黄海表层沉积物中氮的区域地球化学特征

通过分级浸取分离的方法获得了南黄海表层沉积物不同形态的氮，首次探讨其分布的区域性特征：南黄海表层沉积物中各形态氮在不同测线上均呈现出波状分布。B测线的基本上呈现出中部海域高，两边海域低，而西部海域又略高于东部海域的趋势，D和E测线的基本上呈现出西高、东低的趋势，C测线的则呈现出西低、东高的趋势，F测线的变化趋势比较平缓，从整体上看，SOEF—N和TN的分布呈现出西部海区比东部海区低的趋势。受各测线上沉积物种类差异的影响，自北向南各形态氮的变化幅度逐渐减小，其中SOEF-N在各测线上的变化幅度最大，且自北向南降幅最大。受水动力及沉积物粒度的影响，不同形态氮在黄海槽内各站位沉积物中的含量较高。沉积物中各形态氮在不同测线上的分布还表明，陆源输入对南黄海沉积物中氮测线分布有较小的影响，海洋自生氮对南黄海表层沉积物中氮的形态、含量与分布具有重要影响。     

基于GIS数据仓库的激光单分子海洋油气化探数据可视化处理

采用基于地理信息系统(GIS)的数据仓库技术,以激光单分子海洋油气化探数据处理与评价作为数据仓库主题,实现了激光单分子海洋油气化探数据的可视化处理。将可视化处理分为4个步骤:数据预处理、异常背景分析、异常分析、异常综合评价;使用MAPX、DELPHI等软件研制开发了相应的可视化软件模块。通过对渤海湾盆地某测区实测的甲苯化探数据的处理,验证了所开发技术的实用性。     

Summer distribution and geochemical composition of suspended-particulate matter in the east china sea

The distribution and geochemical composition of suspended-particulate matter (SPM) in the East China Sea (ECS) were investigated during the summer period of high continental runoff to elucidate SPM sources, distribution and cross-shelf transport. The spatial variability of SPM distribution (0.3–6.5 mg l⁻¹) and geochemical composition (POC, Al, Si, Fe, Mn, Ca, Mg and K) in the ECS was pronounced during summer when the continental fluxes of freshwater and terrestrial materials were highest during the year. Under the influences of Changjiang runoff, Kuroshio intrusion, surface production and bottom resuspension, the distribution generally showed strong gradients decreasing seaward for both biogenic and lithogenic materials. Particulate organic carbon was enriched in surface water (mean ∼18%) due to the influence of biological productivity, and was diluted by resuspended and/or laterally-transported materials in bottom water (mean 9.4%). The abundance of lithogenic elements (Al, Si, Fe, Mn) increased toward the bottom, and the distribution correlations were highly significant. Particulate CaCO₃ distribution provided evidence that the SPM of the bottom water in the northern part of the study area was likely mixed with sediments originally derived from Huanghe. A distinct benthic nepheloid layer (BNL) was present in all seaward transects of the ECS shelf. Sediment resuspension may be caused by tidal fluctuation and other forcing and be regarded as the principal agent in the formation of BNL. This BNL was likely responsible for the transport of biogenic and lithogenic particles across or along the ECS shelf. Total inventories of SPM, POC and PN are 46, 2.8 and 0.4 Tg, respectively, measured over the total area of 0.45 × 10⁶ km² of the ECS shelf. Their mean residence times are about 27, 13 and 11 days, respectively. The inventory of SPM in the water column was higher in the northernmost and southernmost transects and lower in the middle transects, reflecting the influences of terrestrial inputs from Changjiang and/or resuspended materials from Huanghe deposits in the north and perhaps from Minjiang and/or Taiwan’s rivers in the south. The distribution and transport patterns of SPM and geochemical elements strongly indicate that continental sources and cross-shelf transport modulate ECS particulate matter in summer.     

海底天然气水合物地球化学探测技术

海底天然气水合物是未来的新型能源，地球化学探测与分析技术在天然气水合物勘探、研究和开发中发挥巨大作用。简要介绍了天然气水合物地球化学探测方法及相关的分析测试技术，包括海底沉积物、海水、海面低层大气中烃类气体(主要为甲烷)、孔隙水中阴阳离子和同位素地球化学异常等。并对发展天然气水舍物地球化学探测与分析新技术提出建议。     

火山热液型铅锌矿床岩石地球化学特征及预测指标

火山热液型铅锌矿床赋矿围岩、后期脉岩和蚀变岩石中成矿元素铅锌银含量高,矿体元素组合复杂,原生异常发育,并存在着原生分带现象。矿体前缘元素为I、Hg、As、Sb、B、Ba;近矿指示元素是Pb、Zn、Ag、Au、Cd、Mn、Cu;尾部或矿下指示元素为Cu、Mo、W、Sn。根据矿床指示元素的分布规律和原生晕的分带性,研制了判别矿床剥蚀程度和评价异常的地球化学指标,建立了该类矿床的地球化学找矿预测标志。