Temporal variations in magma composition at Merapi Volcano (Central Java, Indonesia): magmatic cycles during the past 2000 years of explosive activity

Merapi Volcano (Central Java, Indonesia) has been frequently active during Middle to Late Holocene time producing basalts and basaltic andesites of medium-K composition in earlier stages of activity and high-K magmas from 1900 ¹⁴C yr BP to the present. Radiocarbon dating of pyroclastic deposits indicates an almost continuous activity with periods of high eruption rates alternating with shorter time spans of distinctly reduced eruptive frequency since the first appearance of high-K volcanic rocks. Geochemical data of 28 well-dated, prehistoric pyroclastic flows of the Merapi high-K series indicate systematic cyclic variations. These medium-term compositional variations result from a complex interplay of several magmatic processes, which ultimately control the periodicity and frequency of eruptions at Merapi. Low eruption rates and the absence of new influxes of primitive magma from depth allow the generation of basaltic andesite magma (56–57 wt% SiO₂) in a small-volume magma reservoir through fractional crystallisation from parental mafic magma (52–53 wt% SiO₂) in periods of low eruptive frequency. Magmas of intermediate composition erupted during these stages provide evidence for periodic withdrawal of magma from a steadily fractionating magma chamber. Subsequent periods are characterised by high eruption rates that coincide with shifts of whole-rock compositions from basaltic andesite to basalt. This compositional variation is interpreted to originate from influxes of primitive magma into a continuously active magma chamber, triggering the eruption of evolved magma after periods of low eruptive frequency. Batches of primitive magma eventually mix with residual magma in the magmatic reservoir to decrease whole-rock SiO₂ contents. Supply of primitive magma at Merapi appears to be sufficiently frequent that andesites or more differentiated rock types were not generated during the past 2000 years of activity. Cyclic variations also occurred during the recent eruptive period since AD 1883. The most recent eruptive episode of Merapi is characterised by essentially uniform magma compositions that may imply the existence of a continuously active magma reservoir, maintained in a quasi-steady state by magma recharge. The whole-rock compositions at the upper limit of the total SiO₂ range of the Merapi suite could also indicate the beginning of another period of high eruption rates and shifts towards more mafic compositions.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

湖南中生代陆内构造变形的深部过程：煌斑岩地球化学示踪

湖南煌斑岩以富集大离子亲石元素和轻稀土元素，而亏损高强场元素(Nb-Ta-Ti)为特征，同位素以高^87Sr/^86Sr、低^143Nd／^144Nd为特征。源区可能为早期俯冲交代的古老岩石圈富集地幔。煌斑岩的侵入是软流圈上涌的结果，表明湖南地区于晚三叠世已从岩石圈的挤压阶段开始向岩石圈伸展-减薄阶段转换。     

重磁遗传算法三维反演中高速计算及有效存储方法技术

将地下场源区域规则划分成很多小长方体单元，并且通过反演确定这些单元的物性变 化，勾画出场源的分布图像，这种方式逐步成为重磁反演，特别是三维反演的重要方向；遗 传算法等非线性技术进行该类反演将逐步成为发展趋势. 本文指出，在应用遗传算法进行该 类反演过程中，隐含着数据量较大时超常规的计算量，它已成为制约该类反演充分发挥作用 的瓶颈问题；同时，本文提出了针对性的分离并存储几何格架的计算策略、以及独特的几何 格架等效压缩存储技术，可以从根本上提高非线性反演计算速度，为该类反演的有效应用奠 定了坚实的基础.     

中国夏季降水异常空间模与副热带高压的关系

本文用1959～1994年6、7、8月全国范围47个5°×5°经纬度网格降水资料分析了夏季降水异常空间模的月际差异，并在此基础上用西太平洋副高指数及青藏高原指数#FKB#FS分析降水异常空间模与环流的关系，为检验环流指数与降水相关场的整体信度，还对8月份降水资料进行了Monte-Carlo检验。结果表明，夏季总降水异常的空间模在每一月份中并非表现得同样清楚，江淮流域与河套及华南的反相关在8月份表现得最清楚。而青藏高原中东部南北两侧的负相关在6月及8月很清楚，7月份次之。8月份西太平洋副高北界异常对江淮流域与河套及华南地区降水异常反相关的产生有很大作用。副高稳定偏北时，河套、华南易涝，江淮易旱。反之亦然。青藏高原指数#FKB#FS与逐月降水的相关分析表明，青藏高原上高压及低涡活动对高原中东部南北两侧负相关的产生有一定作用。当高压活动偏多时，北侧易旱、南侧易涝。并且6月及8月的作用较大，7月较小。另外，8月份副高活动对这一降水异常空间模的产生也有一定影响。     

中国重力异常的小波变换与多尺度分析

阐述了小波变换及多尺度分析方法的原理，利用二维小波多尺度分析方法对中国布格重力异常进行了分解，并从其中划分出有意义的剩余异常．模型结果证明方法有效．由于本文方法可以将重力异常分解成各种几何尺度意义下的不同成分，这为重力解释和研究地壳的结构提供更多更新的依据．     

地下气体运移变化的物理化学机制研究

在河北省怀来县后郝窑地区，对地下气体运移变化的影响因素进行了野外模拟实验研究。选择３个试验点，对地下气体的扩散作用，物理化学影响因素及水压效应等进行了模拟实验，主要研究Ｈ２，ＣＯ２气体运移变化机制。实验研究表明，Ｈ２，ＣＯ２气体运移变化机制不尽相同，水压效应对Ｈ２，ＣＯ２等地下气体运移影响相当明显     

地球化学样品中硒的循序提取技术

研究开发了一种硒的循序偏提取步骤，将地球化学样品中的硒选择性地循序提取到六个“操作上”定义的相态中：水溶性硒（水提取）；吸附在氧化矿物和粘土矿物上配位可交换的亚硒酸根离子（０．１ｍｏｌ／ＬＫＨ２ＰＯ４提取）；与有机质结合的硒（０．１ｍｏｌ／ＬＮａ４Ｐ２Ｏ７提取）；与铁锰铝氧化物和碳酸盐结合的硒（４．０ｍｏｌ／ＬＨＣｌ提取）；硫化物中的硒（ＫＣｌＯ３＋浓ＨＣｌ提取）；硅酸盐残渣中以副矿物和被硅质包裹的硒微粒存在的硒（ＨＦ＋ＨＮＯ３＋ＨＣｌＯ４强混合酸溶解）。对提取步骤的可行性和实用性作了详细的讨论。     

The onset of Pleistocene glaciation in the Barents Sea: implications for glacial isostatic adjustment

In this paper the effect of a delayed onset of glaciation in the Barents Sea on glacial isostatic adjustment is investigated. The model calculations solve the sea-level equation governing the total mass redistributions associated with the last glaciation cycle on a spherically symmetric, linear, Maxwell viscoelastic earth for two different scenarios for the growth phase of the Barents Sea ice sheet. In the first ice model a linear growing history is used for the Barents Sea ice sheet, which closely relates its development to the build-up of other major Late Pleistocene ice sheets. In the second ice model the accumulation of the Barents Sea ice sheet is restricted to the last 6 ka prior to the last glacial maximum.
The calculations predict relative sea levels, present-day radial velocities, and gravity anomalies for the area formerly covered by the Weichselian ice sheet. The results show that observed relative sea levels in the Barents Sea are appropriate for distinguishing between the different glaciation histories. In particular, present-day observables such as the free-air gravity anomaly over the Barents Sea, and the present-day radial velocities are sensitive to changes in the glaciation history on this scale.
A palaeobathymetry derived from relative sea-level predictions before the last glacial maximum based on the second ice model essentially agrees with a palaeobathymetry derived by Lambeck (1995). The additional emerged areas provide centres for the build-up of an ice sheet and thus support the theory of Hald, Danielsen & Lorentzen (1990) and Mangerud et al. (1992) that the Barents Sea was an essentially marine environment shortly before the last glacial maximum.     

Periodicity of magnetic intensities in magnetic anomaly profiles: the Cenozoic of the South Atlantic

Spectral analyses of several published magnetic anomaly profiles from Candé & Kent (1992a) were undertaken prior to analysing, in the same way, raw magnetic anomaly data from similar parts of the South Atlantic. It was found that similar and distinct medium and short wavelengths were present in both the published and raw data. When these are converted into the time domain using the average rate of spreading for each profile, these periodicities appear similar, possibly identical, to those expected from the long-term eccentricity orbital parameters (Fischer, DeBoer & Premoli Silva 1990). While such correlations are not necessarily causative, they suggest that magnetohydro-dynamical processes near the core-mantle boundary may be affected by gravitational changes due to planetary orbital perturbations.