同位素地质年代学及在地质学中的应用(英文)

一些元素（Ｋ,Ｒｂ,Ｒｅ,Ｓｍ,Ｌｕ,Ｕ和Ｔｈ）的自然长寿命放射性同位素,衰变为另种元素稳定同位素的作用,广泛应用于岩石和矿物的年龄测定。这种测年提供了关于地球地质历史的信息,并已用于标定地质年代表。同位素测年的物理原理并不难理解,但所需要的测定技术,则要求同位素地球化学家利用地质人员采集的样品进行熟练精细的操作。对测年结果的解释也应由双方合作进行,并且在很大程度上依靠区域和地区的地质信息。笔者只介绍最广泛应用于测定岩浆岩和变质岩年龄的同位素方法,其余的一些方法只一提而过,详见同位素地质年代学专著     

Meso–Neoarchaean crustal evolution of the Bundelkhand Craton,Indian Shield: new data from greenstone belts

ABSTRACT

The Mauranipur and Babina greenstone belts of the Bundelkhand Craton are formed of the Central Bundelkhand greenstone complex (CBGC). This complex represents tectonic collage which has not been previously studied in depth. The purpose of this study is to contribute to the understanding of the main features of the Archaean crustal evolution of the Bundelkhand Craton. The CBGC consists of two assemblages: (1) the early assemblage, which is composed of basic-ultramafic, rhyolitic–dacitic, and banded iron formation units, and (2) the late assemblage, which is a felsic volcanic unit. The units and assemblages are tectonically unified with epidote–quartz–plagioclase metasomatic rocks formed locally in these tectonic zones.

The early assemblage of the Mauranipur greenstone belt is estimated at 2810 ± 13 Ma, from the U–Pb dating (SHRIMP, zircon) of the felsic volcanics. Also, there are inherited 3242 ± 65 Ma zircons in this rock. It is deduced that this assemblage is related to early felsic subduction volcanism during the Mesoarchaean that occurred in the Bundelkhand Craton.

Zircons extracted from metasomatic rocks in the early assemblage’s high-Mg basalts show a concordant age of 2687 ± 11 Ma. This age is interpreted as a time of metamorphism that occurred simultaneously with an early accretion stage in the evolution of the Mauranipur greenstone belt.

The felsic volcanism, appearing as subvolcanic bodies in the late assemblage of the Mauranipur greenstone belt, is estimated to be 2557 ± 33 Ma from the U–Pb dating (SHRIMP, zircon) of the felsic volcanic rocks. This rock also contains inherited 2864 ± 46 Ma zircons. The late assemblage of the Mauranipur greenstone belt corresponds with a geodynamic setting of active subduction along the continental margin during Neoarchaean.

The late assemblage Neoarchaean felsic volcanic rocks from the Mauranipur and Babina greenstone belts are comparable in age and geochemical characteristics. The Neoarchaean rocks are more enriched in Sr and Ba and are more depleted in Cr and Ni than the Mesoarchaean felsic volcanic rocks of the early assemblage.

Through isotopic dating and the geochemical analysis of the volcanic and metasomatic rocks of the CBGC, this study has revealed two subduction–accretion events, the Meso–Neoarchaean (2.81–2.7 Ga) and Neoarchaean (2.56–2.53 Ga), during the crustal evolution of the Bundelkhand Craton (Indian Shield).     

U–Pb geochronology,Sr–Nd isotopic compositions,geochemistry and petrogenesis of Shah Soltan Ali granitoids,Birjand, Eastern Iran

The Shah Soltan Ali area (SSA) is located in the eastern part of the Lut Block metallogenic province. In this area different types of sub-volcanic intrusions including diorite porphyry, monzonite porphyry and monzodiorite porphyry have intruded into basaltic and andesitic rocks. Zircon U–Pb dating and field observations indicate that intermediate to mafic volcanic rocks (38.9 Ma) are older than subvolcanic units (38.3 Ma). The subvolcanic intrusions show high-K calc-alkaline to shoshonitic affinity and are metaluminous. Based on mineralogy, high values of magnetic susceptibility [(634 to 3208) × 10^?5 SI], and low initial ⁸⁷Sr/⁸⁶Sr ratios, they are classified as belonging to the magnetite-series of oxidant I-type granitoids and are characterized by an enrichment in LREEs relative to HREEs, with negative Nb, Ti, Zr and Eu anomalies. These granitoids are related to volcanic arc (VAG) and were generated in an active continental margin. Low initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043 to 0.7052) and positive εNd values (+1.48 to +3.82) indicate that the parental magma was derived from mantle wedge. Parental magma was probably formed by low degree of partial melting and metasomatized by slab derived fluids. Then assimilation and fractional crystallization processes (AFC) produced the SSA rocks. This magma during the ascent was contaminated with the crustal material.All data suggest that Middle-Late Eocene epoch magmatism in the SSA area, occurred during subduction of Neo-Tethys Ocean in east of Iran (between Afghan and Lut Blocks).     

Strontium,SO42−/Cl− and Mg2+/Ca2+ ratios as tracers for the evolution of seawater into coastal aquifers: the example of Castell de Ferro aquifer (SE Spain)

The strontium content and the SO₄^2?/Cl^? and Mg²⁺/Ca²⁺ ratios were used as natural tracers of the residence time of seawater intrusion into the Castell de Ferro aquifer. Analysis of these parameters indicated the existence of two principal flowpaths in the aquifer. The first flows through the eastern part of the aquifer, through the karstified Castell de Ferro massif; it accommodates a larger and more rapid flow, so that the residence time is shorter, leading to lower SO₄²⁺/Cl^? ratios, lower Sr²⁺ content and higher Mg²⁺/Ca²⁺ ratios. The second flowpath is in the western sector, and flows exclusively through alluvial deposits; the flow here is slower, particularly that flowing towards the sea. Thus the residence time of the water here will be longer and there is scant flushing of the intruded seawater; this is manifested in the high Sr²⁺ content, high SO₄²⁺/Cl^? and low Mg²⁺/Ca²⁺ ratios. To cite this article: P. Pulido-Leboeuf et al., C. R. Geoscience 335 (2003).     

Early Mesozoic metamorphism and tectonic significance of the eastern segment of the Lhasa terrane,south Tibet

The metamorphic belt in the Basongco area, the eastern segment of Lhasa terrane, south Tibet, occurs as the tectonic blocks in Paleozoic sedimentary rocks. The Basongco metamorphic rocks are mainly composed of paragneiss and schist, with minor marble and orthogneiss, and considered previously to be the Precambrian basement of the Lhasa terrane. This study shows that the Basongco metamorphic belt experienced medium-pressure amphibolite-facies metamorphism under the conditions of T = 640–705 °C and P = 6.0–8.0 kbar. The inherited detrital zircon of the metasedimentary rocks yielded widely variable ²⁰⁶Pb/²³⁸U ages ranging from 3105 Ma to 500 Ma, with two main age populations at 1150 Ma and 580 Ma. The magmatic cores of zircons from the orthogneiss constrain the protolith age as ca. 203 Ma. The metamorphic zircons from all rocks yielded the consistent metamorphic ages of 192–204 Ma. The magmatic cores of zircons in the orthogneiss yielded old Hf model ages (T_DM2 = 1.5–2.1 Ga). The magmatic zircons from the mylonitized granite yielded a crystallization age of ca. 198 Ma. These results indicate that the high-grade metamorphic rocks from the Basongco area were formed at early Jurassic and associated with coeval magmatism derived from the thickening crust. The Basongco metamorphic belt, together with the western and coeval Sumdo and Nyainqentanglha metamorphic belts, formed a 400-km-long tectonic unit, indicating that the central segment of the Lhasa terrane experienced the late Paleozoic to early Mesozoic collisional orogeny.     

Sidebands to the lower kilohertz quasi-periodic oscillation in 4U 1636–53

In this paper we report on further observations of the third and fourth kilohertz quasi-periodic oscillations (QPOs) in the power spectrum of the low-mass X-ray binary (LMXB) 4U 1636−53. These kilohertz QPOs are sidebands to the lower kilohertz QPO. The upper sideband has a frequency  55.5 ± 1.7 Hz  larger than that of the contemporaneously measured lower kilohertz QPO. Such a sideband has now been measured at a significance  >6σ  in the power spectra of three neutron-star LMXBs (4U 1636−53, 1728−34 and 1608−52). We also confirm the presence of a sideband at a frequency ∼55 Hz less than the frequency of the lower kilohertz QPO. The lower sideband is detected at a 3.5σ level only when the lower kilohertz QPO frequency is between 800 and 850 Hz. In that frequency interval, the sidebands are consistent with being symmetric around the lower kilohertz QPO frequency. The upper limit to the rms amplitude of the lower sideband is significantly lower than that of the upper sideband for lower kilohertz QPO frequencies >850 Hz. Symmetric sidebands are unique to 4U 1636−53. This might be explained by the fact that lower kilohertz QPO frequencies as high as 800–850 Hz are rare for 4U 1728−34 and 1608−52. Finally, we also measured a low-frequency QPO at a frequency of ∼43 Hz when the lower kilohertz QPO frequency is between 700 and 850 Hz. A similar low-frequency QPO is present in the power spectra of the other two systems for which a sideband has been observed. We briefly discuss the possibility that the sideband is caused by Lense–Thirring precession.     

Age and tectonic significance of the Louth Volcanics: implications for the evolution of the Tasmanides of eastern Australia

Abstract

Re-evaluation of geochemical and geophysical datasets, and analysis of magmatic and detrital zircons from drill-core samples extracted from the Louth region of the southern Thomson Orogen (STO), augmented by limited field samples, has shown that two temporally and compositionally distinct igneous groups exist. The older Lower Devonian, calc-alkaline group corresponds to complexly folded, high-intensity curvilinear magnetic anomalies in the Louth region (Louth Volcanics) and are probable equivalents to Lower Devonian volcanics in the northern Lachlan Orogen. A younger Permo-Triassic alkaline assemblage forms part of an E–W corridor of diatremes that appears to relate to focussed lithospheric extension associated with the later stages of the Hunter–Bowen Orogeny in the New England Orogen. The alkaline group includes gabbros previously considered as Neoproterozoic, but all magmatic rocks, including alkaline basalts, contain an unusual number of xenocrystic zircons. The age spectra of the xenocrystic zircons mimic detrital zircons from Cobar Basin sedimentary rocks and/or underlying Ordovician turbidites, suggesting incorporation of upper crustal zircons into the alkaline basaltic magmas. A distinct difference of detrital zircon age spectra from central Thomson Orogen metasediments indicates the STO metasediments have greater affinities to the Lachlan Orogen, but both orogens probably began in the Early Ordovician during widespread backarc extension and deposition of turbidites in the Tasmanides. A surprising result is that Ordovician, Devonian and Permo-Triassic basaltic rocks from the STO and elsewhere in the Tasmanides, all yield the same Nd-model ages of ca 960–830 Ma, suggesting that Neoproterozoic subcontinental lithospheric mantle persisted throughout the evolution of the Tasmanide orogenic system.     

The Grenvillian orogeny in the Altun–Qilian–North Qaidam mountain belts of northern Tibet Plateau: Constraints from geochemical and zircon U–Pb age and Hf isotopic study of magmatic rocks

Numerous Neoproterozoic magmatic and metamorphic events in the Altun–Qilian–North Qaidam (AQNQ) region record Grenvillian orogenesis and amalgamation of the supercontinent Rodinia. However, the tectonothermal regimes responsible for these Neoproterozoic events and the assumed position of the AQNQ in Rodinia remain controversial. Zircon U–Pb age data show that the orthogneiss and paragneiss/schist of the AQNQ experienced concurrent magmatism and metamorphism at 895–925 Ma. Zircon Lu–Hf isotopic data indicate that the gneisses in the AQNQ have ε_Hf (0.9 Ga) values and t_DM2 (Hf) model ages ranging from −5.6 to +3.9 and 1.4 to 1.9 Ga. These data suggest that the early Neoproterozoic magma in the AQNQ was predominately derived from a late Paleoproterozoic–early Mesoproterozoic crustal source between 1.4 and 1.9 Ga, marking an important episode of crustal growth in the AQNQ. The Neoproterozoic magmatism is geochemically characterized by (1) high SiO₂, K₂O, and low P₂O₅; (2) A/CNK ratios >1.0, ranging from 1.03 to 1.09; (3) enrichment in Rb, Th and U, and depletion in Ba, Nb, Ta, Sr, Ti, and Eu. Based on the geochemical resemblance to high-K calc-alkaline I-type granite and zircon Lu–Hf isotope signatures, the Neoproterozoic magmatism in the AQNQ was probably derived from ancient mafic-intermediate igneous rocks in an active continental margin. The Neoproterozoic tectono-magmatic–metamorphic history of the AQNQ, directly associated with the South China block (SCB) and the Tarim block (TB), indicates that the AQNQ and the TB coexisted as a single block in the early Neoproterozoic, which was temporarily connected to the SCB to the north or west in Rodinia during the late stages of the Grenvillian orogeny (950–900 Ma).     

A new coral reef province in the Gulf of Carpentaria, Australia: Colonisation, growth and submergence during the early Holocene

Multibeam sonar mapping, drill cores and underwater video data have confirmed the existence of a previously unknown coral reef province in the Gulf of Carpentaria, Australia. Seven reefs, comprised of coral limestone that support living corals have been mapped so far and as many as 50 other reefs may exist in the region. U/Th ages show that reef growth commenced shortly after limestone pedestals were submerged by rising sea level around 10.5 kyr BP, making them the oldest Holocene reefs known in Australia. Reef growth persisted for ~ 2.0 kyr but it had ceased at most locations by ~ 7.0 kyr BP. Measurements of reef growth rates (0.95 to 4 m kyr^− 1), indicate that the reefs were unable to keep pace with contemporaneous rapid sea level rise (> 10 m kyr^− 1), which is consistent with a “give up” reef growth history. Core samples from reef platforms demonstrate that Pleistocene limestone is exposed at depths of 27 and 30 m below present mean sea level. These depths represent regionally significant phases of reef growth during a prolonged sea level still stand. We conclude that the reefs are therefore mostly relict features, whose major phase of growth and development relates to an earlier, pre-Holocene sea level still stand.     

Variations of the Nutrients Loads to the Mainland U.K. Estuaries: Correlation with Catchment Areas, Urbanization and Coastal Eutrophication

The annual loads of nutrients (TO_xN equal to nitrate+nitrite; ammonium, phosphate, silicate) to all the estuaries on the mainland of the United Kingdom were estimated from data on water flow through gauging stations at the tidal limits of estuaries, and from concentration measurements under the Harmonised Monitoring Scheme of nutrient concentrations in water samples from these stations. The annual loads of nutrients showed distinct regional variations, with estuaries along the west coast of Wales and northern Scotland having much smaller loads than those along the east coast of England. The largest nitrogen loads were of TO_xN, and ammonium loads were usually small in comparison. The Severn, Mersey, Humber and Thames had the highest loads, although these were small in relation to the larger continental European estuaries. Loads of TO_xN per unit of catchment area were surprisingly constant (about 10⁵ moles N km⁻² y⁻¹). The nutrient loads showed that most U.K. catchments were influenced by human activity, the majority being in the ‘ moderately influenced ’ category. Nutrient loads were also normalized for the area of each estuary, as a measure of the relative influence of nutrients on the receiving estuaries. The ratios of N:P, N:Si and P:Si in the annual loads suggested that most estuaries were likely to be, if anything, P limited rather than N or Si limited. However, crude annual loads may conceal significant seasonal variations.The spring maximum chlorophylla concentrations in coastal waters adjacent to each estuary were significantly correlated with the log total annual loads of TO_xN, ammonium and phosphate (but not silicate) for each estuary, providing a direct link between a measure of the degree of biological response in coastal waters and the nutrient load through the estuaries. There were no significant correlations between spring maximum chlorophyll a concentrations and either catchment-normalized or estuary-normalized nutrient loads. There was significant correlation between catchment area-normalized loads of phosphate and an urbanization index for the catchments, but not with the catchment area-normalized loads of the other nutrients.