Comparative study on CO_2 emissions from different types of alpine meadows during grass exuberance period

1IntroductionTherisingatmosphericgreenhousegaseswerebelievedtobetheprimarycauseofglobalclimatechange(Tettetal.,1999;Crowley,2000).Amongthegreenhousegases,theconcentrationofatmosphericcarbondioxidehasincreasedfrom280ppmsincepre-industrialtimestocurrent355ppm,whichaccountedfor50%ofthetotalgreenhouseeffect(Nefteletal.,1985;Friedlietal.,1986;Rodhe,1990;Fanetal.,1998).ElevatedCO2hasamarkedeffectonterrestrialecosystemprocesses(Melilloetal.,1996).TheQinghai-TibetPlateau,thelargestgeomorphologica…     

Thermodynamic conditions of framework grain dissolution of clastic rocks and its application in Kela 2 gas field

Feldspar and clastic debris are the most important constituent framework grains of sedimentary clastic rocks and their chemical dissolution plays an essential role in the formation and evolution of the secondary pore in the reservoir rocks. On the basis of thermodynamic phase equilibrium, this study investigates the chemical equilibrium relationships between fluid and various plagioclase and K-feldspar in diagenesis of the sediments, particularly, the impact of temperature and fluid compositions (pH, activity of K+, Na+, Ca2+ and so on) on precipitation and dissolution equilibria of feldspars. Feldspar is extremely easily dissolved in the acid pore water with a low salinity when temperature decreases. The dissolution of anorthite end-member of plagioclase is related to the Ca content of the mineral and the fluid, higher Ca either in the mineral or in the fluid, easier dissolution of the feldspar. Moreover, the dissolution of albite end-member of plagioclase is related to Na of both the mineral and fluid,     

中国海相油气田勘探实例(之一) 四川盆地罗家寨大型气田的发现和探明

罗家寨气田发现于2000年,是四川盆地迄今为止发现的储量规模最大的一个气田,2002年探明储量为581.08×108m3。其下三叠统飞仙关组储层由碳酸盐岩蒸发台地边缘优质鲕粒滩白云岩构成,圈闭面积大,构造幅度高,具有一定的埋藏隐蔽性。论述了气田的发现和探明过程,气藏地质的特征,以及对碳酸盐岩气藏勘探的启示。     

Microthermometric measurement of fluid inclusions and its constraints on genesis of PGE-polymetallic deposits in Lower Cambrian black rock series, southern China

Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series.     

Interpretation of radon anomalies in seismotectonic and tectonic-gravitational settings: the south-eastern Crati graben (Northern Calabria, Italy)

The study area is located in the south-eastern part of the Crati valley (Northern Calabria, Italy), which is a graben bordered by N–S trending normal faults and crossed by NW–SE normal left-lateral faults. Numerous severe crustal earthquakes have affected the area in historical time. Present-day seismic activity is mainly related to the N–S faults located along the eastern border of the graben. In this area, much seismically induced deep-seated deformation has also been recognised.In the present paper, radon concentrations in soil gas have been measured and compared with (a) lithology, (b) Quaternary faults, (c) historical and instrumental seismicity, and (d) deep-seated deformation.The results highlight the following:

(a) There is no evidence of a strong correlation between lithology and the radon anomalies.

(b) A clear correlation between the N–S geometry of radon anomalies and the orientation of main fault systems has been recognised, except in the southernmost part of the area, where the radon concentrations are strongly affected by the superposition of the N–S and the NW–SE fault systems.

(c) Epicentral zones of instrumental and historical earthquakes correspond to the highest values of radon concentrations, probably indicating recent activated fault segments. In particular, high radon values occur in the zones struck by earthquakes in 1835, 1854, and 1870.

(d) Deep-seated gravitational deformation generally coincides with zones characterised by low radon concentrations.

In the studied area, the anisotropic distribution of radon concentrations is congruent with the presence of neotectonic features and deep-seated gravitational phenomena. The method used in this study could profitably contribute towards either seismic risk or deep-seated gravitational deformation analyses.     

惰性气体法测定地下水入渗补给量

地下水入渗补给量是重要的水文地质参数。本文介绍了测定地下水入渗补给量的最新方法——惰性气体法的原理与方法，该方法适用于封闭条件下的深层地下水。     

沙漠沙丘污水处理系统:原理、方法和效果

“沙漠沙丘系统(DDS)”是以地球化学工程学原理为指导的特殊水处理系统,它利用沙漠沙作为滤料,通过“机械过滤”、“化学作用”和“生物作用”净化污染水,一方面可使沙丘变得湿润而不再移动,以固定移动沙漠;另一方面又能净化污染水,最终起到“以害克害、固沙治水、一举多得”的良好综合生态环境效应。DDS是绿色的水处理系统,所需的原料和生成物都属于自然界存在的物质,无二次污染的发生。在DDS设计中,要注意的主要因素应包括:滤料的种类、湿干时间比、微生物培养方式、滤料层厚度、进水水质、时间、温度和pH等。DDS可以把官厅水库水由V类和超V类处理成2~3类水,从而恢复官厅水库的饮用水功能。     

Analysis of rock structure stability in coal mines

In this paper, the theory of limit point instability is used to analyse the stability of rock structures in coal mines. A general method of analysing stability of rock structures is put forward and a uniform instability condition of rock structures is set up. Some instability phenomena, such as rock bursts in circular roadways, pillars and long walls, and the outburst of coal and gas from circular roadways, are discussed analytically. At a later stage, the critical point of rock structure instability is determined. The influence of relative parameters (such as the mechanical properties of rock, coal, and the geometric sizes) on the stability of the rock structures is carefully analysed. Copyright © 2005 John Wiley & Sons, Ltd.     

Localization of mining-induced horizontal fractures along rock layer interfaces in overburden: field measurements and prediction

The locations of mining-induced horizontal fractures along rock interfaces in the overburden of Donetsk Coal Basin were identified using an original experimental device. The device traps methane from horizontal fracture zone (100–fold coal seam thickness) over an active longwall mining excavation. Presence or absence of horizontal fractures along rock layer interfaces is correlated with physical characteristics of the overburden, such as thickness, uniaxial compressive strength of overburden rock layers, location of rock layer interfaces and thickness of extracted coal seams. As a result, a combined criterion based on these physical characteristics is proposed to predict the presence of overburden horizontal fracturing in coal mine operations.     

Material selection for the gas containment system of a compressed natural gas carrier fleet

In this work, the possible exploitation of fiber-reinforced composites in the context of maritime transportation of compressed natural gas (CNG) is investigated. In addition to a more conventional steel configuration, two different fiber materials, carbon and glass, are considered as construction materials for pressure vessels (PVs) to be stored on board ships, with thickness optimized by FEM analysis.The considered scenario is represented by the transportation of CNG from an offshore well to a terminal on shore. Fleets of ships carrying CNG in pressure vessels manufactured with the investigated materials are generated by means of a ship synthesis model (SSM) software and compared on the basis of technical and economical indicators.The choice of the construction material influences considerably the weight of the PVs, which represent a major item of total ship weight and reflects directly on the general transport performances in terms of resistance, seakeeping and reliability in the service. On the other hand, capital as well as operating expenditures are considerably affected by the choice. When exploring the design space, the ship synthesis model is able, at a preliminary stage of the design, to account for the various technical and economical aspects, their implications and relationships. Results are presented of computations carried out in a specific case, identified by the annual gas production and other characteristics of the well terminal and a cruising route for the ships. The comparison is carried out on the basis of the cost per transported unit of gas and of the percentage of success in the transportation process. The computations show that the choice of the PV material has a key influence on the results in terms of optimal number, dimensions and speed of the ships.