榴辉岩中石榴子石—单斜辉石地质温度计

通过对大别山双河榴辉岩的实例研究,对石榴子石-单斜辉石地质温度计的应用性和计算方法进行了讨论。与其他地质温度计（如氧同位素温度计）相比较,结合动力学研究,有助于进一步深入了解石榴子石-单斜辉石温度计的应用。该温度计能够较为准确地反映榴辉岩的顶峰变质温度,并且使恢复岩石体系的冷却历史成为可能。     

Calcite–dolomite geothermometry in the system CaCO3–MgCO3–FeCO3: an experimental study

Abstract An experimental study of the system CaCO₃–MgCO₃–FeCO₃ was undertaken in order to calibrate the iron correction to the calcite–dolomite geothermometer, which is based on the solubility of magnesium in calcite in the assemblage calcite + dolomite. The experiments, at 450°C and lower temperatures, resulted in products with a very small grain size and incomplete equilibration. However, application of a carefully-devised automatic data processing algorithm to analyses of the phases in experimental charges, combined with a thermodynamic analysis, results in geothermometer diagrams which should be preferred to previous theoretical predictions.     

Submarine hydrothermal brine seeps off Milos, Greece. Observations and geochemistry

A shallow hydrothermal brine seep located off the Greek island of Milos in the Aegean Sea was studied. The brine fluid outcropped as a pool of water in a seabed depression and was detected in the surrounding pore-waters of sediments colonised by the sulphur bacterium Achromatium volutans. The seep fluid was highly saline and sulphidic, depleted in Mg²⁺ and SO₄²⁻, but enriched over seawater in Na⁺, Ca²⁺, K⁺, Cl⁻, SiO₂, reduced species and dissolved gases. The high concentrations of Na⁺, Ca²⁺ and K⁺ were consistent with the Milos tectonic setting. Na-K and Na-K-Ca geothermometers predicted a reservoir temperature of 300–325 °C for the most concentrated seep samples. The deep geothermal reservoir within the metamorphic basement of Milos island has already been located and studied and may represent the source of the seep fluid. Faunal diversity was lowest in seep-influenced sediments, but a sulphide-intolerant species was found in areas of the bacterial mat where salinity and temperature were much lower. Pressure-induced variations in the vertical depth of the brine interface may be occurring in the sediment.     

拉萨地块东南缘晚白垩世高温变质作用及其地质意义:来自石英出溶金红石的证据和锆石U-Pb定年

文中对拉萨地块东南缘林芝杂岩中的含榴斜长角闪岩进行了详细的岩相学研究和锆石U-Pb定年。岩相学观察表明,含榴斜长角闪岩经历了峰期麻粒岩相变质和角闪岩相退变质作用。峰期麻粒岩相矿物组合为石榴子石+高Ti角闪石+紫苏辉石+斜长石+石英+金红石,其中的石榴子石、石英和角闪石中含有大量金红石出溶体,说明这些矿物的初始成分具有高Ti含量。角闪岩相退变质矿物组合为低Ti角闪石+斜长石+斜黝帘石+石英+金红石。利用Ti在石英中的含量(TitaniQ)温度计计算得到峰期麻粒岩相变质温度为803～924℃,后期角闪岩相退变质温度为555～732℃。样品中的锆石具有明显的核边结构,核部为典型岩浆型锆石,具有高的Th/U值,强烈富集HREE,明显的正Ce异常和负Eu异常,206Pb/238U年龄为(89.3±0.6)Ma,代表含榴斜长角闪岩原岩结晶年龄。锆石边部呈无环带结构,同核部相比,具有低的Th/U值,低的M-HREE和弱的Eu负异常,为变质峰期生长的锆石,206Pb/238U年龄为(81.1±0.8)Ma,代表麻粒岩相峰期变质年龄。我们认为约81Ma高温麻粒岩相变质作用可能与洋中脊俯冲造成的板片窗导致的软流圈上涌有关。     

福建东山县澳角村澳角群花岗质石榴黑云片麻岩锆石SHRIMP U-Pb定年及其地质意义

本文对福建东山县澳角村澳角群花岗质石榴黑云片麻岩中17颗锆石进行了SHRIMP U-Pb同位素年龄测定。结果显示锆石Th/U比值变化于0.31~1.01,平均值为0.48,为典型的岩浆锆石;其中16个分析点在谐和图上分布较为集中,206Pb/238U年龄加权平均值为(152.8±1.6)Ma(n=17,MSWD=1.12);结合锆石自形、发育岩浆环带等特点,该年龄被解释为澳角群亲营山组花岗质石榴黑云片麻岩的形成年龄。其所指示的地质意义:(1)福建东山县澳角村澳角群亲营山组花岗质石榴黑云片麻岩形成于晚侏罗纪,而非前泥盆纪;(2)福建东山县澳角村澳角群亲营山组应解体为表壳岩与变质侵入体。     

腾冲火山区壳内岩浆囊现今温度:来自温泉逸出气体 CO2、CH4间碳同位素分馏的估计

温度是岩浆囊的重要物理参数,获取温度参数并监测其变化对更好地理解岩浆囊的物理化学性质和行为、评价火山的活动性和喷发危险性具有重要的理论和现实意义.本文通过对温泉逸出气体CO2和CH4碳同位素样品的采集、分析测试,利用Horita通过实验矫正的Richet的平衡分馏系数的理论计算数据,通过拟合得到的CO2-CH4碳同位素平衡分馏方程T(K)=3880.3(10001nα(CO2-CH4))-0.5984,计算了腾冲火山区现存3个岩浆囊的温度.结果表明:在整个腾冲火山区,由CO2和CH4的碳同位素分馏值计算的气体源区平衡温度最低397℃,最高1163℃,平均615℃.腾冲火山区的3个岩浆囊中,南部五合-龙江-浦川岩浆囊的现今温度在464～1163℃,平均773℃,温度最高;中部腾冲-和顺-热海岩浆囊的现今温度在438 ～773℃间,平均达566℃,温度次之;北部马站-曲石-永安岩浆囊的现今温度在397～651℃间,平均达524℃,温度最低.我们认为,腾冲火山区地下岩浆囊顶部气体富集区目前的温度变化范围为400～ 1200℃,岩浆囊的实际温度应高于平均值615℃.3个岩浆囊的边缘温度可能在400 ～600℃间,中心温度可能在700～1200℃间.3个岩浆囊中心的现今温度已达到流纹岩浆(600～900℃)、安山岩(800 ～ 1100℃)和玄武岩浆(1000～1250℃)的形成温度,进一步说明腾冲火山区目前3个岩浆囊是客观存在的.另外,我们发现在用δ-△图解法判断CO2-CH4间碳同位素分馏平衡的过程中,在保持2条拟合直线的斜率符号相反的条件下,无论如何剔除数据点,都不能使δ13CCO2-ΔCO2-CH4拟合直线的截距bCO2和δ13 CCH4-ΔCO2-CH14拟合直线的截距bCH4之差bΔ小于0.1245,说明2条拟合直线的交点不能落于δ轴上,而这一数值与Horita方程的常数项接近,这说明CO2-CH4间碳同位素分馏方程中确实存在常数项,CO2和CH4间在再高的温度下都存在碳同位素的分馏.δ-△图解法判断CO2-CH4间碳同位素分馏平衡准则应修正为:在保持2条拟合直线的斜率符号相反的条件下,δ13 CCO2-ΔCO2-CH4拟合直线和δ13CCH4-ΔCO2-CH4拟合直线应相交于δ轴附近截距差0.1245处.     

宁洱火山区壳内岩浆囊现今温度:来自CO_2-CH_4碳同位素地质温度计的估计

温度是岩浆囊的重要物理参数,获取温度参数并监测其变化对更好地理解岩浆囊的物理化学性质和行为、评价火山的活动性和喷发危险性具有重要的理论和现实意义。火山岩浆-水热系统丰富的含碳气体,这些含碳气体间碳同位素温度计为我们解决休眠火山区地下岩浆囊的温度问题提供了可能。我们对宁洱火山区地表地热异常强度最高区的4个温泉点CO_2、CH_4碳同位素组成进行了2年的连续观测和2次平行观测,利用观测数据对CO_2、CH_4气体的岩浆来源进行了甄别,对CO_2-CH_4间碳同位素分馏是否发到平衡进行了判断,然后利用Horita CO_2-CH_4碳同位素平衡分馏方程计算了宁洱-通关火山区逸出气体的源区温度。结果表明:宁洱火山区4个样点中,1个样点的CO_2和CH_4均为非岩浆成因,其他3个样点的主要属于岩浆来源。剔除了非岩浆来源的数据后的δ-Δ图解法判断CO_2-CH_4间碳同位素分馏达到了平衡。3个样点的CO_2、CH_4碳气体源区温度分别为425~475℃、941~995℃和1179~1578℃。结合最上部地壳温度场结果,我们认为,宁洱火山区现今存在2个壳内岩浆房,分别位于宁洱火山以南和通关火山以北,宁洱岩浆房的温度为1179~1578℃,通关岩浆房的温度为941~995℃。2个岩浆房的现今温度已达到流纹岩浆(600~900℃)、安山岩(800~1100℃)和玄武岩浆(1000~1250℃)的形成温度。思普地震带空间上密集的6级地震丛集活动可以用宁洱岩浆房的高活动性来解释。δ-Δ图解法判断CO_2-CH_4间碳同位素分馏平衡准则应修正为:在保持两拟合直线的斜率符号相反的条件下,δ~(13)CCO_2-ΔCO_2-CH_4拟合直线和δ~(13)CCH_4-ΔCO_2-CH_4拟合直线应相交于δ轴附近截距差Δb≤0.16处。     

Reconstruction of deep fluid chemical constituents for estimation of geothermal reservoir temperature using chemical geothermometers

This paper elaborates the chemical constituent change principles of deep geothermal fluid during the process of upward movement. It summarizes research methods of hydrochemistry, isotope and numerical modelling technique for the physiochemical processes such as decreasing temperature, shallow groundwater infusion, and degassing. The multi-component chemical geothermometry methods including gas geochemical method are discussed. High-temperature geothermal fields in China are mostly located in the southwest with frequent new tectonic movements, especially in Tibet high-temperature geothermal areas. Therefore the paper also focuses the status of high-temperature geothermal fluid research. At last, it’s pointed out in the paper that in the future we can start from typical high-temperature geothermal zones and geothermal fields to explore optimization of the multi-component geothermometry method and use it in the reconstruction and analogue of the formation mechanism and internal relevancy of regional geothermal systems.     

Heat flow and the geothermal potential of Egypt

Preliminary heat flow values ranging from 42 to 175 mW m^–2 have been estimated for Egypt from numerous geothermal gradient determinations with a reasonably good geographical distribution, and a limited number of thermal conductivity determinations. For northern Egypt and the Gulf of Suez, gradients were calculated from oil well bottom hole temperature data; east of the Nile, and at three sites west of the Nile, gradients were calculated from detailed temperature logs in shallow boreholes. With one exception, the heat flow west of the Nile and in northern Egypt is estimated to be low, 40–45 mW m^–2, typical of a Precambrian Platform province. A local high, 175 mW m^–2, is probably due to local oxidational heating or water movement associated with a phosphate mineralized zone. East of the Nile, however, including the Gulf of Suez, elevated heat flow is indicated at several sites, with a high of 175 mW m^–2 measured in a Precambrian granitic gneiss approximately 2 km from the Red Sea coast. These data indicate potential for development of geothermal resources along the Red Sea and Gulf of Suez coasts. Water geochemistry data confirm the high heat flow, but do not indicate any deep hot aquifers. Microearthquake monitoring and gravity data indicate that the high heat flow is associated with the opening of the Red Sea.     

山西娄烦变质岩中蓝晶石、十字石和红柱石的特征及形成条件

通过电子探针成分分析和矿物共生组合分析,利用地质温度计估算十字石、蓝晶石和红柱石的形成温压条件,以揭示十字石、蓝晶石和红柱石的形成与本区西川河断裂区域变质作用的关系。研究结果表明:本区西川河断裂以北地区出露的十字石和蓝晶石形成条件受压力控制(P=5.5-7Kpa),变质温度为520-550℃;而西川河断裂以南地区出露的红柱石的形成条件主要受温度控制(T=570-600℃),压力小于3Kpa。西川河断裂控制了南北地区的变质条件,进而控制了特征变质矿物十字石、蓝晶石和红柱石的空间分布。