Accidental spills of hydrocarbons, such as Light Non-Aqueous Phase Liquids (LNAPLs), are one of the most common sources of subsurface contamination. Migration of LNAPL in a porous medium is influenced by various factors such as the number of fluids present in the unsaturated/saturated zones and the proportion of pores occupied by each fluid. The results for relationship between matric suction and degree of saturation are presented in this paper for water–air, water–LNAPL and LNAPL–air systems in a sand. A simple and reliable setup using Buchner funnel was designed to obtain these relations. It was found that the relationship between matric suction head and degree of saturation is hysteretic for all the fluid systems (water–air, water–LNAPL and LNAPL–air). Furthermore, the amount of hysteresis depended upon the fluid system, with the maximum hysteresis occurring for water–air system. The results suggest that the amount of trapped air depends upon the reversal degree of saturation from drying to wetting. 相似文献
The Malpica–Tui complex (NW Iberian Massif) consists of a Lower Continental Unit of variably deformed and recrystallized granitoids, metasediments and sparse metabasites, overridden by an upper unit with rocks of oceanic affinities. Metamorphic minerals dated by the 40Ar/39Ar method record a coherent temporal history of progressive deformation during Variscan metamorphism and exhumation. The earliest stages of deformation (D1) under high-pressure conditions are recorded in phengitic white micas from eclogite-facies rocks at 365–370 Ma. Following this eclogite-facies peak-metamorphism, the continental slab became attached to the overriding plate at deep-crustal levels at ca. 340–350 Ma (D2). Exhumation was accompanied by pervasive deformation (D3) within the continental slab at ca. 330 Ma and major deformation (D4) in the underlying para-autochthon at 315–325 Ma. Final tectonothermal evolution included late folding, localized shearing and granitic intrusions at 280–310 Ma.
Dating of high-pressure rocks by the 40Ar/39Ar method yields ages that are synchronous with published Rb–Sr and Sm–Nd ages obtained for both the Malpica–Tui complex and its correlative, the Champtoceaux complex in the French Armorican Massif. The results indicate that phengitic white mica retains its radiogenic argon despite been subjected to relatively high temperatures (500–600 °C) for a period of 20–30 My corresponding to the time-span from the static, eclogite-facies M1 peak-metamorphism through D1-M2 eclogite-facies deformation to amphibolite-facies D2-M3. Our study provides additional evidence that under certain geological conditions (i.e., strain partitioning, fluid deficiency) argon isotope mobility is limited at high temperatures, and that 40Ar/39Ar geochronology can be a reliable method for dating high pressure metamorphism. 相似文献
Natural production of the radionuclide chlorine-36 (36Cl) has provided a valuable tracer for groundwater studies. The nuclear industry, especially the testing of thermonuclear
weapons, has also produced large amounts of 36Cl that can be detected in many samples of groundwater. In order to be most useful in hydrologic studies, the natural production
prior to 1952 should be distinguished from more recent artificial sources. The object of this study was to reconstruct the
probable preanthropogenic levels of 36Cl in groundwater in the United States. Although significant local variations exist, they are superimposed on a broad regional
pattern of 36Cl/Cl ratios in the United States. Owing to the influence of atmospherically transported ocean salt, natural ratios of 36Cl/total Cl are lowest near the coast and increase to a maximum in the central Rocky Mountains of the United States.
Electronic Publication 相似文献
Oscillatory zoning in low δ18O skarn garnet from the Willsboro wollastonite deposit, NE Adirondack Mts, NY, USA, preserves a record of the temporal evolution of mixing hydrothermal fluids from different sources. Garnet with oscillatory zoning are large (1–3 cm diameter) euhedral crystals that grew in formerly fluid filled cavities. They contain millimetre‐scale oscillatory zoning of varying grossular–andradite composition (XAdr = 0.13–0.36). The δ18O values of the garnet zones vary from 0.80 to 6.26‰ VSMOW and correlate with XAdr. The shape, pattern and number of garnet zones varies from crystal to crystal, as does the magnitude of the correlated chemistry changes, suggesting fluid system variability, temporal and/or spatial, over the time of garnet growth. The zones of correlated Fe content and δ18O indicate that a high Fe3+/Al, high δ18O fluid mixed with a lower Fe3+/Al and δ18O fluid. The high δ18O, Fe enriched fluids were likely magmatic fluids expelled from crystallizing anorthosite. The low δ18O fluids were meteoric in origin. These are the first skarn garnet with oscillatory zoning reported from granulite facies rocks. Geochronologic, stable isotope, petrologic and field evidence indicates that the Adirondacks are a polymetamorphic terrane, where localized contact metamorphism around shallowly intruded anorthosite was followed by a regional granulite facies overprint. The growth of these garnet in equilibrium with meteoric and magmatic fluids indicates an origin in the shallow contact aureole of the anorthosite prior to regional metamorphism. The zoning was preserved due to the slow diffusion of oxygen and cations in the large garnet and protection from deformation and recrystallization in zones of low strain in thick, rigid, garnetite layers. The garnet provide new information about the hydrothermal system adjacent to the shallowly intruded massif anorthosite that predates regional metamorphism in this geologically complex, polymetamorphic terrane. 相似文献
Mafic high-pressure granulite, eclogite and pyroxenite xenoliths have been collected from a Mesozoic volcaniclastic diatreme in Xinyang, near south margin of the Sino-Korean Craton (SKC). The high-pressure granulite xenoliths are mainly composed of fine-grained granoblasts of Grt+Cpx+Pl+Hbl±Kfs±Q±Ilm with relict porphyritic mineral assemblage of Grt+Cpx±Pl±Rt. P–T estimation indicates that the granoblastic assemblage crystallized at 765–890 °C and 1.25–1.59 GPa, corresponding to crustal depths of ca. 41–52 km with a geotherm of 75–80 mW/m2. Calculated seismic velocities (Vp) of high-pressure granulites range from 7.04 to 7.56 km/s and densities (D) from 3.05 to 3.30 g/cm3. These high-pressure granulite xenoliths have different petrographic and geochemical features from the Archean mafic granulites. Elevated geotherm and petrographic evidence imply that the lithosphere of this craton was thermally disturbed in the Mesozoic prior to eruption of the host diatreme. These samples have sub-alkaline basaltic compositions, equivalent to olivine– and quartz–tholeiite. REE patterns are flat to variably LREE-enriched (LaN/YbN=0.98–9.47) without Eu anomaly (Eu/Eu*=0.95–1.11). They possess 48–127 ppm Ni and 2–20 ppm Nb with Nb/U and La/Nb ratios of 13–54 and 0.93–4.75, respectively, suggesting that these high-pressure granulites may be products of mantle-derived magma underplated and contaminated at the base of the lower crust. This study also implies that up to 10 km Mesozoic lowermost crust was delaminated prior to eruption of the Cenozoic basalts on the craton. 相似文献
The relative significance of early (Finnmarkian) and late (Scandian) Caledonian deformation in N. Norway is uncertain. Early studies suggested pervasive Finnmarkian deformation whilst later results indicated a restricted Finnmarkian domain. The present work suggests it was more widespread than accepted and that inter Finnmarkian–Scandian deformation occurred. 40Ar/39Ar dating of 2–6 and 6–11 μm pelitic fractions from the lower to mid-greenschist facies Tanahorn Nappe (five samples; base Middle Allochthon) and the epizone Løkvikfjellet and Barents Sea Groups (three samples; North Varanger Region) in the north Scandinavian Caledonides show slightly discordant spectra. Most spectra from the Tanahorn Nappe preserve possible evidence of an early Caledonian event in the high temperature steps, with recoil/excess Ar effects in the low temperature steps; no pre-Caledonian relict component has been recorded. The results indicate Finnmarkian deformation continued to 460 Ma, with Scandian reactivation at 425–415 Ma. From the North Varanger Region, a strongly crenulated sample yielded plateau ages (444–442 Ma); means of combined young steps from weakly to uncrenulated samples gave 470–450 Ma, suggesting penetrative strike-slip deformation occurred in the late Finnmarkian to inter-Finnmarkian–Scandian period. No Scandian ages were recorded in the North Varanger Region. Reassessment of published data from the Laksefjord Nappe and Gaissa Thrust Belt suggests they were affected by Finnmarkian deformation. 相似文献