The upper Cenomanian–lower Turonian carbonate platform of the Preafrican Trough,Morocco: Biostratigraphic,paleoecological and paleobiogeographical distribution of ostracods

The upper Cenomanian–lower Turonian paleoenvironments of the Preafrican Trough carbonate platform is characterized by analyzing the structure of the ostracod assemblages and the information provided by other groups, and also by linking together the paleontological and geochemical data (detrital influx-redox-paleoproductivity proxies, δ¹³C curve). Two different domains (eastern and western) can be recognized on the platform during the late Cenomanian, before the onset of the OAE2. The western domain corresponds to a low-energy environment developed on a mid and/or outer ramp with hypoxic waters, low detrital influx and low paleoproductivity. The paleoecological assemblages show limited specific diversity but variable density. The ostracods are opportunistic and unspecialized (r strategists), being associated with Buliminidae, surface and intermediate-water planktonic foraminifera, and fishes. The eastern domain corresponds to an inner ramp and/or peritidal environment with oxic waters, low detrital influx and low paleoproductivity, developed in a higher energy environment with paleoecological assemblages showing high diversity but variable density. The ostracods are more specialized (K strategists), being represented by diverse and constant assemblages associated with diversified benthic foraminifera, calcareous sponges and echinoderms, as well as intermediate- and deep-water planktonic foraminifera. The onset of the OAE2 has no influence on the western ostracod assemblages, but leads to the decline of the ostracod fauna and the disappearance of the deep-water planktonic foraminifera in the eastern domain. During the early Turonian, after the OAE2, the platform becomes an outer ramp with increased paleoproductivity, but is associated with a decrease of taxonomic diversity in hypoxic waters. The ostracods are very sparse and unspecialized, associated with siliceous sponges, Buliminidae, surface-living planktonic foraminifera, fishes and pelagic crinoids. Marine paleobiogeographic communication is relatively easy across the carbonate platforms between the Preafrican Trough and other Moroccan regions, as well as between Morocco and different parts of the South Tethyan and East Atlantic margins belonging to the Cenomanian–Turonian South Tethyan Ostracod Province (STOP). Thirteen new species are described: Cytherella tazzouguertensis n. sp., Bairdiacypris chaabetensis n. sp., Bythocypris amelkisensis n. sp., Pontocypris tadighoustensis n. sp., Procytherura? elongatissima n. sp., Loxoconcha akrabouensis n. sp., Hemiparacytheridea sagittaemucronata n. sp., Rehacythereis errachidiaensis n. sp., Rehacythereis zizensis n. sp., Veenia (Nigeria) tardaensis n. sp., Veenia (Nigeria) mediacostarobusta n. sp., Xestoleberis? preafricanensis n. sp., and Xestoleberis circinatus n. sp.     

Gas generation and expulsion characteristics of Middle–Upper Triassic source rocks,eastern Kuqa Depression,Tarim Basin,China: implications for shale gas resource potential

Frontier exploration in the Kuqa Depression, western China, has identified the continuous tight-sand gas accumulation in the Lower Cretaceous and Lower Jurassic as a major unconventional gas pool. However, assessment of the shale gas resource in the Kuqa Depression is new. The shale succession in the Middle–Upper Triassic comprises the Taliqike Formation (T₃t), the Huangshanjie Formation (T₃h) and the middle–upper Karamay Formation (T_2–3k), with an average accumulated thickness of 260 m. The high-quality shale is dominated by type III kerogen with high maturity and an average original total organic carbon (TOC) of about 2.68 wt%. An improved hydrocarbon generation and expulsion model was applied to this self-contained source–reservoir system to reveal the gas generation and expulsion (intensity, efficiency and volume) characteristics of Middle–Upper Triassic source rocks. The maximum volume of shale gas in the source rocks was obtained by determining the difference between generation and expulsion volumes. The results indicate that source rocks reached the hydrocarbon expulsion threshold of 1.1% VR and the hydrocarbon generation and expulsion reached their peak at 1.0% VR and 1.28% VR, with the maximum rate of 56 mg HC/0.1% TOC and 62.8 mg HC/0.1% TOC, respectively. The volumes of gas generation and expulsion from Middle–Upper Triassic source rocks were 12.02 × 10¹² m³ and 5.98 × 10¹² m³, respectively, with the residual volume of 6.04 × 10¹² m³, giving an average gas expulsion efficiency of 44.38% and retention efficiency of 55.62%. Based on the gas generation and expulsion characteristics, the predicted shale gas potential volume is 6.04 × 10¹² m³, indicating a significant shale gas resource in the Middle–Upper Triassic in the eastern Kuqa Depression.     

A laboratory study of the self sealing behaviour of a compacted sand–bentonite mixture

Bricks made of compacted sand–bentonite mixture are considered as a possible engineered barrier to isolate high-level radioactive waste at great depth. This work is aimed at investigating some specific effects related to the presence of discontinuities at the contact between the bricks and the excavation wall. In order to do this, an experimental device was developed in the laboratory. The model is made up of a specially designed infiltration cylinder which allows the precise definition of a planar discontinuity between the compacted specimen (a sand–bentonite mixture made up of sand and Kunigel clay from Japan) and a metal wall. During hydration and subsequent specimen swelling, the planar wall is filled, resulting in a healing process. Three total pressure gauges placed along the wall allow a detailed observation of the increase in total stress against the wall. After different periods of swelling, the maximum resistance of the specimen–wall interface to pressure was tested by imposing a pressure increase through a porous stone placed at one end of the cylinder. It was found that the maximum pressure supported by the interface is a function of the initial thickness of the discontinuity and the initial density of the specimen. It was also found that the maximum sustainable pressure depends linearly on the elapsed time. These results are of interest for optimizing water infiltration procedures in either mock-up tests or real disposal systems. If the maximum sustainable pressure at the interface is known, it is possible either to ensure homogeneous hydration of a mass of bricks by respecting the maximum injection pressure limit or to accelerate hydration by forcing water paths along the discontinuities.     

最优化的矿物扩散地质速率计:北大别黄土岭麻粒岩缓慢冷却的证据

对北大别黄土岭麻粒岩中石榴子石进行了详细的电子探针工作，并根据一颗石榴子石的成分环带，建立了扩散模型并进行了数值模拟，结合最优化的方法，得到了极其缓慢的冷却速率0.1℃/a。从扩散动力学数值模拟的角度对大别山造山带的冷却速率进行了探索性研究。该结果表明，黄土岭麻粒岩在受麻粒岩相改造后经历的是一个极其缓慢、持续时间很长的冷却过程。     

固溶体矿物的性质对计算河南西峡红柱石矿形成条件的影响

自然界的大多数造岩矿的是由两种或多种组分混合而成的固溶体。因此，在矿物，岩石和矿床等地质体的平衡热力学研究中不可避免地要涉及固溶体矿物热力学地为的问题。河南省西峡县杨乃沟红柱石矿泥质片岩中仅出现红柱石而没有蓝晶石和夕线石，红柱石矿物包裹体测温结果为420－600℃。通过矿物共生平衡p-t曲线所计算出的片岩形成温度和压力条件也应位于上述岩石学和岩相学等特征所限定的范围内。以此为基础，通过构筑矿物共生p-t平衡曲线的方法，对片岩中若干固溶体矿物理想性／非理想性问题进行了研究。其中斜长石必须以非理想固溶体处理，而石榴子石，黑云母和白云母视作理想固溶体的计算结果同片岩的岩石学和岩相学等特征相一致。     

Geobarometry for Peridotites: Experiments in Simple and Natural Systems from 6 to 10 GPa

Experiments with peridotite minerals in simple (MgO–Al₂O₃–SiO₂,CaO–MgO–SiO₂ and CaO–MgO–Al₂O₃–SiO₂)and natural systems were conducted at 1300–1500°Cand 6–10 GPa using a multi-anvil apparatus. The experimentsin simple systems demonstrated consistency with previous lowerpressure experiments in belt and piston–cylinder set-ups.The analysis of spatial variations in pyroxene compositionswithin experimental samples was used to demonstrate that pressureand temperature variations within the samples were less than0·4 GPa and 50°C. Olivine capsules were used in natural-systemexperiments with two mineral mixtures: SC1 (olivine + high-Alorthopyroxene + high-Al clinopyroxene + spinel) and J4 (olivine+ low-Al orthopyroxene + low-Al clinopyroxene + garnet). Theexperiments produced olivine + orthopyroxene + garnet ±clinopyroxene assemblages, occasionally with magnesite and carbonate-richmelt. Equilibrium compositions were derived by the analysisof grain rims and evaluation of mineral zoning. They were comparedwith our previous experiments with the same starting mixturesat 2·8–6·0 GPa and the results from simplesystems. The compositions of minerals from experiments withnatural mixtures show smooth pressure and temperature dependencesup to a pressure of 8 GPa. The experiments at 9 and 10 GPa producedandradite-rich garnets and pyroxene compositions deviating fromthe trends defined by the lower pressure experiments (e.g. higherAl in orthopyroxene and Ca in clinopyroxene). This discrepancyis attributed to a higher degree of oxidation in the high-pressureexperiments and an orthopyroxene–high-P clinopyroxenephase transition at 9 GPa. Based on new and previous resultsin simple and natural systems, a new version of the Al-in-orthopyroxenebarometer is presented. The new barometer adequately reproducesexperimental pressures up to 8 GPa. KEY WORDS: garnet; mineral equilibrium; multi-anvil apparatus; orthopyroxene; geobarometry     

Roles for fluid and/or melt advection in forming high-P mafic migmatites, Fiordland, New Zealand

A series of striking migmatitic structures occur in rectilinear networks through western Fiordland, New Zealand, involving, for the most part, narrow anorthositic dykes that cut hornblende‐bearing orthogneiss. Adjacent to the dykes, host rocks show patchy, spatially restricted recrystallization and dehydration on a decimetre‐scale to garnet granulite. Although there is general agreement that the migration of silicate melt has formed at least parts of the structures, there is disagreement on the role of silicate melt in dehydrating the host rock. A variety of causal processes have been inferred, including metasomatism due to the ingress of a carbonic, mantle‐derived fluid; hornblende‐breakdown leading to water release and limited partial melting of host rocks; and dehydration induced by volatile scavenging by a migrating silicate melt. Variability in dyke assemblage, together with the correlation between dehydration structures and host rock silica content, are inconsistent with macroscopic metasomatism, and best match open system behaviour involving volatile scavenging by a migrating trondhjemitic liquid.     

Origin of the alkali tonsteins from southwest China: Implications for alkaline magmatism associated with the waning stages of the Emeishan Large Igneous Province

A unique type of Nb–Zr–REE–Ga-enriched alkali tonstein of pyroclastic origin occurs exclusively within the late Permian coal measures of southwest China. The alkali tonsteins are located within the lowest Xuanwei or Longtan formations of Wuchiapingian age, indicating that their age is later than the main episode of Emeishan Large Igneous Province (ELIP) magmatism. The alkali tonsteins have intermediate–felsic Al₂O₃/TiO₂ values (12.6–34.2, mean 22.0), light rare earth element-enriched chondrite-normalised patterns, negative δEu and incompatible element ratios similar to those of ELIP alkaline Nb–Ta-enriched syenites. All available evidence shows that the alkali tonsteins from southwest China originated from coeval ELIP alkaline magmatism. The enrichment of Nb–Zr–REE–Ga in alkali tonsteins is derived from the ELIP alkaline Nb–Ta-enriched volcanic ashes and may represent the last stage of mineralisation associated with the Emeishan mantle plume activity.     

北京密云放马峪基性岩墙群LA-MC-ICP-MS锆石U-Pb年龄及其意义

太古宙基性岩墙群在北京密云地区广泛分布,其年代学研究一直备受关注,多年来取得了一些数据,但对太古宙变质片麻岩控制作用未做论述。利用LA-MC-ICP-MS U-Pb同位素测定技术,测得放马峪石榴辉石岩中锆石的年龄为2497±15Ma,此年龄被解释为区内变质片麻岩成岩年龄应早于基性岩墙群成岩年龄,其为研究区内太古宙片麻岩成岩年龄提供了重要的参考数据。