25～75℃酸性NaCl溶液中方铅矿的溶解动力学

在25～75℃、pH=0.43～2.45的1mol/LNaCl溶液中进行了方铅矿的溶解动力学实验。发现在远平衡条件下,方铅矿的溶解速率r与氢离子活度犤H+犦呈线性关系,溶解速率方程(速率定律)为:r=k犤H+犦,即对H+而言,溶解反应为一级。其中速率常数k为2.344×10-7mol/m2·s(25℃)、1.380×10-6mol/m2·s(50℃)、7.079×10-6mol/m2·s(75℃)。溶解反应的活化能为43.54kJ/mol,方铅矿的溶解机理为表面化学反应,速率决定步骤为表面配合物的离解。     

Analyzing CO2 emissions mitigation by technology improvement in Central and Eastern Europe

As a legacy of the centrally planned economy, the economies in transition of Central and Eastern Europe (CEE) have a unique potential to reduce their greenhouse gas emissions through the improvement in their high energy intensities. Since much of this `low-hanging fruit' in energy-efficiency improvements can be highly cost-effective, many developed countries facing difficulties in meeting their greenhouse gas (GHG) emission targets domestically are eager to find such opportunities in the CEE region. Therefore, studies analysing the potentials and costs of carbon dioxide reduction through technology improvement in the region have come into the limelight. While there are a few excellent studies in the region aimed at analysing climate change abatement potentials, they all embark on different assumptions, methodologies and boundary conditions. It is hence difficult, if not impossible, to compare and analyse the results of these studies across different authors, countries or time horizons. Consequently, the purpose of this paper is to place four leading studies on GHG mitigation through technology improvement from the CEE region into an internationally comparable framework. Four studies were selected from three countries, Poland, Hungary and Estonia, which are all the results of major national and international efforts to assess costs and potentials of GHG reduction. The paper places their assumptions, methods and final results into a framework which enables policy-makers and project designers to compare these across geographical and technological boundaries. Since other studies from around the globe have been analysed in this framework in the literature, this paper provides a vehicle for the findings of these four studies to be compared to others worldwide. In addition, the paper highlights a few areas where similar studies to be completed in the future in the region may be enhanced by incorporating features used in GHG mitigation research in other parts of the world. This revised version was published online in July 2006 with corrections to the Cover Date.     

A methodology for the evaluation of long-term volcanic risk from pyroclastic flows in Campi Flegrei (Italy)

The volcanological history of Campi Flegrei suggests that the most frequent eruptions are characterized by the emplacement of pyroclastic flow and surge deposits erupted from different vents scattered over a 150-km² caldera. The evaluation of volcanic risk in volcanic fields is complex because of the lack of a central vent. To approach this problem, we subdivided the entire area of Campi Flegrei into a regular grid and evaluated the relative spatial probability of opening of vents based on geological, geophysical and geochemical data. We evaluated the volcanic risk caused by pyroclastic flows based on the formula proposed by UNESCO (1972), R=H×V×Va, where H is the hazard, V is the vulnerability and Va is the value of the elements at risk. The product H×V was obtained by performing simulations of type eruptions centered in each cell of the grid. The simulation is based on the energy cone scheme proposed by Sheridan and Malin [J. Volcanol. Geotherm. Res. 17 (1983) 187–202], hypothesizing a column collapse height of 100 m for eruptions of VEI=3 and 300 m for eruptions of VEI=4 with a slope angle of 6°. Each simulation has been given the relative probability value associated with the corresponding cell. We made use of the GIS software ArcView 3.2 to evaluate the intersection between the energy cone and the topography. The superposition of the areas invaded by pyroclastic flows (124 simulations for VEI=3 and 37 for VEI=4) was used to obtain the relative hazard map of the area. The relative volcanic risk map is obtained by superimposing the urbanization maps.     

南京地区新近沉积土的动剪切模量和阻尼比的初步研究

本文通过对南京地区两个工程场地漫滩相成因的砂土和淤泥质粉粘土与粉砂互层土的自振动柱试验结果进行分析，探讨了围压对剪切模量G及阻力比λ的影响，通过与Seed和Idriss建议的砂土G/Gmax-γ和λ-γ曲线变化范围的对比，认为不能简单地把淤泥质粉质粘土与粉砂层土当作砂土或粉质粘土对待。     

Nonlinear earthquake response analysis and energy calculation for seismic slit shear wall structures

Based on the concept of structural passive control, a new type of slit shear wall, with improved seismic performance when compared to an ordinary solid shear wall, was proposed by the authors in 1996. The idea has been verified by a series of pseudo-static and dynamic tests. In this paper a macro numerical model is developed for the wall element and the energy dissipation device. Then, nonlinear time history analysis is carried out for a 10-story slit shear wall model tested on a shaking table. Furthermore, the seismic input energy and the individual energy dissipated by the components are calculated by a method based on Newmark-β assumptions for this shear wall model, and the advantages of this shear wall are further demonstrated by the calculation results from the viewpoint of energy. Finally, according to the seismic damage criterion on the basis of plastic accumulative energy and maximum response, the optimal analysis is carried out to select design parameters for the energy dissipation device.     

Study of the Earth’s free core nutation by tidal gravity data recorded with international superconducting gravimeters

By stacking high-precision tidal gravity observations obtained with superconducting gravimeters at six stations in China, Japan, Belgium, France, Germany and Finland, the local systematical discrepancies in the parameter fitting, caused by atmospheric, oceanic tidal loading and the other local environmental perturbations, are eliminated effectively. As a result, the resonance parameters of the Earth’s free core nutation are accurately determined. In this study, the eigenperiod of free core nutation is given as 429.0 sidereal days, which is in agreement with those published in the previous studies. It is about 30 sidereal days less than those calculated in theoretical models (about 460 sidereal days), which confirms the real ellipticity of the fluid core of the Earth to be about 5% larger than the one expected in assumption of hydrostatic equilibrium. The quality factor (Q value) of free core nutation is given as about 9543, which, compared with those determined before based on the body tide observations, is much larger, but more close to those obtained using the VLBI observations. The complex resonance strength is also determined as (−6.10×10⁻⁴, −0.01 ×10⁻⁴)°/h, which can principally describe the deformation characteristics of an anelastic mantle.     

钢筋砼摩擦耗能支撑框架结构的单元刚度和力学模型分析

为研究钢筋砼摩擦耗能支撑框架结构的动力反应性能 ,对其中的摩擦耗能器单元和框架杆单元的单元刚度和力学模型做了分析。钢筋砼摩擦耗能支撑单元由支撑杆单元和钢板—橡胶摩擦耗能器单元组成 ,支撑单元可取空间杆单元 ,摩擦耗能器单元为平面应力矩形单元。摩擦耗能器单元的剪切恢复力曲线为理想的弹塑性曲线 ,根据耗能器单元的力学模型 ,可确定其在每一时刻的刚度 ;框架结构空间杆单元的恢复力模型采用双线型模型 ,根据杆单元的力学模型 ,可确定其在每一时刻的刚度。并利用所编制的程序对十层单榀两跨空间普通框架和摩擦耗能支撑框架在地震作用下进行了弹塑性反应时程分析 ,结果表明耗能支撑框架的顶层最大位移明显小于普通框架     

青藏高原土壤水热分布特征及冻融过程在季节转换中的作用

利用GAME-Tibet期间所取得的高分辩率土壤温度和含水量资料，对青藏高原（主要是藏北高原）土壤水热分布特征及冻融过程在季节转换中的作用进行了分析。指出藏北高原4cm学深处土壤在10月份开始冻结，次年4-5月份开始消融，冻结持续时间长达5-7个月。冻结过程有利于土壤维持其水分，因此，在刚刚开始消融时土壤含水量仍然很高。从而为夏季风爆发前土壤通过蒸发向大气提供水分打下了基础。指出土壤冻融过程可能在高原季节转换中起着重要作用。     

改进的灰色模型在中国能源消费及其CO2排放预测中的研究

中国高速的经济发展导致了快速的能源消费和地球温暖化气体的排放量。本文应用灰色理论建立了中国的终端能源消费量的动态预测模型，同时应用等维递补及带有马尔科夫链符号估计的残差修正，对原始模型进行了改进。后验检验的结果证明了改进的预测模型具有较高的计算精度。预测结果表明，两种经济发展情况（高速及低速）下，从2000年到2030年期间的终端能源消费量的平均增长率将分别达到3．06％和2．18％，2030年CO2 的排放量将分别达到2000年的 2． 15及 1．60倍。其中工业及居民生活的能源消费量的增加速度快于其他部门。这表明了中国将要加快其工业化及都市化的进程．终端消费中，煤炭的消费量所占的比例将要逐年减少，而电力的比例则将逐年增大。     

南极无冰区典型沉积环境石英砂表面结构特征及其在沉积环境识别中的应用

本文利用电镜扫描方法 (SEM)对比分析了南极乔治王岛无冰区海滩沉积、冰碛物以及阿德雷岛湖泊沉积等典型沉积环境中的石英砂表面结构特征 ,得出了乔治王岛各典型沉积环境中石英砂表面结构特征的颗粒频率曲线。结果表明 :不同沉积环境下的石英砂颗粒表面结构特征具有相似性 ,这主要和南极地区广泛发育的冰川作用有关 ,同时 ,它们也有各自典型的特征组合 ,这些典型特征组合的不同反映了石英砂后期的搬运历史和沉积环境的差异。本文还依据石英砂表面特征的颗粒出现频率 ,利用聚类分析方法对研究区内三级海岸阶地上的沉积物和一个未知成因的样品进行了沉积环境的判别分析 ,结果证明石英砂微形貌特征可以作为南极地区沉积环境识别的有效手段