Retrieval of stratospheric O3 and NO2 vertical profiles using zenith scattered light observations

Daily zenith scattered light intensity observations were carried out in the morning twilight hours using home-made UV-visible spectrometer over the tropical station Pune (18‡31′, 73‡51′) for the years 2000–2003. These observations are obtained in the spectral range 462–498 nm for the solar zenith angles (SZAs) varying from 87‡ to 91.5‡. An algorithm has been developed to retrieve vertical profiles of ozone (O₃) and nitrogen dioxide (NO₂) from ground-based measurements using the Chahine iteration method. This retrieval method has been checked using measured and recalculated slant column densities (SCDs) and they are found to be well matching. O₃ and NO₂ vertical profiles have been retrieved using a set of their air mass factors (AMFs) and SCDs measured over a range of 87–91.5‡ SZA during the morning. The vertical profiles obtained by this method are compared with Umkehr profiles and ozonesondes and they are found to be in good agreement. The bulk of the column density is found near layer 20–25 km. Daily total column densities (TCDs) of O₃ and NO₂ along with their stratospheric and tropospheric counterparts are derived using their vertical profiles for the period 2000–2003. The total column, stratospheric column and tropospheric column amounts of both trace gases are found to be maximum in summer and minimum in the winter season. Increasing trend is found in column density of NO₂ in stratospheric, tropospheric and surface layers, but no trend is observed in O₃ columns for above layers during the period 2000–2003     

裂缝性岩石裂缝扩展的光弹构造物理模拟——以南华北盆地户部寨沙河阶组为例

以南华北盆地户部寨第三系沙河阶组粉砂岩低渗透储层为例,总结了其中发育的5种类型构造裂缝组合,即:①南北向雁形张节理组成的共轭剪节理带;②东西向雁形张节理组成的共轭剪节理带;③缠结状多组剪切构造裂缝;④组合状交切的多组剪切构造裂缝及张裂缝;⑤散状无序排列的构造裂缝。在此基础上,建立光弹性试验构造物理模型,沿现应力场96°方向,均匀地对该模型逐步增加外载力。结果表明,沿各组合裂缝尖端分别形成对称于裂缝走向、且主轴垂直于裂缝的Ⅰ型等色线条纹;对称于裂缝走向、且主轴平行于裂缝走向的Ⅱ型条纹和斜交于裂缝走向的复合型(Ⅲ型)条纹。第①类组合裂缝尖端以Ⅰ型等色线条纹的拉张应力和张剪应力为主;第②类组合裂缝尖端以复合型(Ⅲ型)等色线条纹的挤压应力为主;第③、④和⑤类组合裂缝尖端的应力分布较为复杂。当模型外载荷接近1000kg时,裂缝尖端起裂,并开始发育显微裂缝,而当外载荷达1100-1200 kg时,沿裂缝尖端部位形成宏观裂缝,并开始扩展。5种类型的裂缝组合扩展发育程度由强至弱依次为:①,③,⑤,②,④。其中第①类共轭裂缝组合起裂最早,扩展最快,裂缝间的连通趋势最好,说明规则分布的构造裂缝组合,在垂直于外施加载衙时更易达到连通的目的。     

黑龙江省中部森林沼泽区 超低密度深穿透地球化学调查采样介质的确定

通过对王水溶矿法与四酸溶矿法的对比,元素在泛滥平原A层、B层沉积物及水系沉积物中的分配,以及这3种介质圈定的异常对比等综合因素的研究,确定了泛滥平原A层沉积物是黑龙江省中部森林沼泽区开展超低密度深穿透地球化学调查的有效采样介质。     

地球化学异常再现性与可对比性

不同密度采样是否可以获得稳定的和可追索的地球化学模式是检验采样是否具有代表性，分析技术是否成熟的重要依据。笔者选择新疆哈密大南湖地区约6400km^2面积，进行了从超低密度(1个样／100km^2)，甚低密度(1个样／25km^2)直到低密度(1个样／4km^2)地球化学采样，对比了3种密度地球化学采样所获得的地球化学数据和异常分布模式。得出如下结论：超低密度、甚低密度、低密度地球化学调查获得的元素含量平均值和背景值非常接近；超低密度、甚低密度、低密度调查所圈定的地球化学省在形态上和变化趋势上非常相似，浓集中心的位置重合，表明不同调查阶段可获得稳定的和可追索的地球化学模式；采样密度越大数据离散程度越高，即最小值更小，最大值更大，表明元素分布的局部不均匀性，正是这种局部的不均匀性才能通过加密采样刻画出地球化学模式的细节变化，为逐步追踪矿化体奠定了基础；超低密度和甚低密度采样可以有效圈定矿集区所形成的大规模地球化学异常，低密度地球化学调查不仅可以圈定矿集区异常，同时可以圈定分散矿化的小规模局部异常。     

北京及其周边地区夏季地闪活动时空特征分析

利用M-LDARS闪电定位系统对北京及其周边地区1995～1997年6～9月的闪电观测数据, 分析闪电活动的时空分布特征。结果表明:闪电活动在时间分布上存在两个峰值时段, 13 :00～21:00和23:00～次日05 :00。通过对总地闪、分时段及峰值时段的地闪密度分析, 发现北京及周边地区闪电活动有几个明显的集中区域, 地闪高密度区主要出现在下垫面为山脉和水体的地方, 闪电活动与下垫面的水汽条件关系密切, 且正、负地闪的空间分布也呈现较大差异, 表明雷暴云的电荷结构存在一定差异。     

地质雷达及浅层地震在泥质粉砂岩中断裂带上的曲线特征

探讨了如何利用地质雷达及浅层地震有关原理判释泥质粉砂岩中隐伏断裂带的性质和特征。主要的工作方法是通过现场实测，分析地质雷达反映在张性断裂带和压性断裂带上的曲线特征，分析浅层地震相遇时距曲线在断裂带上的曲线特征。后者的主要特征有：（1）在断裂带上初至时间延长；（2）在断裂带上左右支时距曲线上下跳动的幅度均等；（3）在断裂带上跳动的长度不一；（4）在断裂带左右支时距曲线上下跳动或反相；（5）时距曲线呈喇叭口。阐明了地质雷达和浅层地震的原理及其在泥质粉砂岩中勘查断裂构造的效果     

H2O-CH4-H2-CO2-CO-O2在高温、高压和高密度条件下的状态方程

为了计算高温，高压和高密度流体的热力学性质，提出了一个具有19个参数的维里型状态方程，其中参数与温度间的函数关系采用由Sutherland位能函数导出的维里系数近似式。除临界点附近以外，在已报道的pVT数据所覆盖的大部分超临界区域内，该方程均可适用。用该方程对H2O，CH4，H2，CO2，CO和O2等流体pVT关系的计算结果令人满意，其中pVT上限分别为：91-610GPa,1.6-11.0cm^3/mol,4000-5000K。计算体积的平均偏 小于0．8％，最大偏差小于5．4％。     

离散裂隙渗流方法与裂隙化渗透介质建模

流体渗流模拟的连续介质方法通常适用于多孔地质体，并不一定适用于裂隙岩体，由于裂隙分布及其特征与孔隙差异较大。若流体渗流主要受裂隙的控制，对于一定尺寸的裂隙岩体，多孔介质假设则较难刻划裂隙岩体的渗流特征。离散裂隙渗流方法不但可直接用于模拟裂隙岩体非均质性和各向异性等渗流特征，而且可用其确定所研究的裂隙岩体典型单元体及其水力传导（渗透）张量大小。主要讨论了以下问题：（1）饱和裂隙介质中一般的离散流体渗流模拟；（2）裂隙岩体中的REV（典型单元体）及其水力传导（渗透）张量的确定；（3）利用离散裂隙网络流体渗流模型研究裂隙方向几何参数对水力传导系数和REV的影响；（4）在二维和三维离散裂隙流体渗流模型中对区域大裂隙和局部小裂隙的处理方法。调查结果显示离散裂隙流体渗流数学模型可用来评价不同尺度上的裂隙岩体的水力特征，以及裂隙方向对裂隙化岩体的水力特征有着不可忽视的影响。同时，局部小裂隙、区域大裂隙应当区别对待，以便据其所起的作用及水力特征，建立裂隙化岩体相应的流体渗流模型。     

Analogue study of particle segregation in pyroclastic density currents, with implications for the emplacement mechanisms of large ignimbrites

Abstract Analogue flume experiments were conducted to investigate the transport and sedimentation behaviour of turbulent pyroclastic density currents. The experimental currents were scaled approximately to the natural environment in three ways: (1) they were fully turbulent; (2) they had a very wide range of particle sizes and associated Rouse numbers (the ratio of particle settling velocity to effective turbulent eddy velocity in the current); and (3) they contained particles of two different densities. Two sets of surge‐type experiments were conducted in a 5 m long, water‐filled lock‐exchange flume at five different volumetric particle concentrations from 0·6% to 23%. In one set (one‐component experiments), the currents contained just dense particles; in the other set (two‐component experiments), they contained both light and dense particles in equal volume proportions. In both sets of experiments, the population of each component had a log‐normal size distribution. In the two‐component experiments, the size range of the light particle population was selected in order to be in hydrodynamic equivalence with that of the dense particles. Dense particles were normally graded, both vertically and downstream, in the deposits from both sets of experiments. The mass loading (normalized to the initial mass of the suspension) and grain size of the dense component in the deposits decreased with distance from the reservoir and were insensitive to initial total particle concentration in the currents. On the other hand, in the two‐component experiments, the light particles were extremely sensitive to concentration. They were deposited in hydrodynamic equivalence with the dense particles from dilute currents, but were segregated efficiently at concentrations higher than a few per cent. With increasing particle concentration, the large, light particles were carried progressively further down the flume because of buoyancy effects. Deposits from the high‐concentration currents exhibited reverse vertical grading of the large, light particles. Efficient segregation of the light component was observed even if the bulk density of the current was less than that of the light particles. In both sets of experiments, marked inflexions in the rate of downstream decline in mass loading and maximum grain size of the dense component can be attributed to the presence of two different particle settling regimes in the flow: (1) particles with Rouse numbers >2·5, which did not respond to the turbulence and settled rapidly; and (2) particles with Rouse numbers <2·5, which followed the turbulent eddies and settled slowly. The results are applied to the transport and sedimentation dynamics of pyroclastic density currents that generate large, widespread ignimbrites. Field data fail to reveal significant departures from aerodynamic equivalence between pumice and lithic clasts in three such ignimbrites: the particulate loads of some large ignimbrites are transported principally in turbulent suspensions of low concentration. In some ignimbrites, the well‐developed inflexions in curves of maximum lithic (ML) size vs. distance can be attributed to the existence of distinct high and low Rouse number particle settling regimes that mark the transition from an overcharged state to one in which the residual particulate load is transported more effectively by turbulence.     

Probability Density Functions as Botanical-Climatological Transfer Functions for Climate Reconstruction

We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.