Re–Os and U–Pb geochronology of the Shazigou Mo polymetallic ore field,Inner Mongolia: Implications for Permian–Triassic mineralization at the northern margin of the North China Craton

The recently discovered polymetallic Shazigou Mo–W–Pb–Zn ore field is located at the northern margin of the North China Craton. This integrated metallogenic system is comprised of quartz vein mineralization in three deposits: Shazigou Mo–W, Jindouzishan Pb–Zn and Mantougou Pb–Zn. The total reserves are estimated to be 50 kt Mo, 626 t WO₃, 244 kt Pb and 150 kt Zn. Molybdenite Re–Os dating of five quartz vein-type ores yielded a mean model age of 243.8 ± 1.6 Ma (MSWD = 0.81) and hydrothermal zircons yielded a concordant U–Pb age of 245 ± 2.6 Ma (MSWD = 0.65). These results suggest that the mineralization was formed in the early Triassic and could be related to Paleo-Asian Ocean subduction. Microthermometry and quartz fluid inclusion compositions indicate that fluids related to the Mo–W mineralization were mainly derived from magmatic sources and precipitated under relatively high temperature (280–340 °C) and salinity conditions (6–9 wt% NaCl equiv.), whereas subsequent Pb–Zn mineralization-related fluids may have been modified by metamorphic and meteoric waters. The discovery of the Shazigou ore field suggests conditions may be favourable for more extensive mineralization in the western Xilamulun Mo metallogenic belt at the northern margin of the North China Craton.     

Cenozoic metallogeny of Greece and potential for precious,critical and rare metals exploration

The Cenozoic metallogeny in Greece includes numerous major and minor hydrothermal mineral deposits, associated with the closure of the Western Tethyan Ocean and the collision with the Eurasian continental plate in the Aegean Sea, which started in the Cretaceous and is still ongoing. Mineral deposits formed in four main periods: Oligocene (33–25 Ma), early Miocene (22–19 Ma), middle to late Miocene (14–7 Ma), and Pliocene-Pleistocene (3–1.5 Ma). These metallogenic periods occurred in response to slab-rollback and migration of post-collisional calc-alkaline to shoshonitic magmatism in a back-arc extensional regime from the Rhodopes through the Cyclades, and to arc-related magmatism along the active south Aegean volcanic arc. Invasion of asthenospheric melts into the lower crust occurred due to slab retreat, and were responsible for partial melting of metasomatized lithosphere and lower crustal cumulates. These geodynamic events took place during the collapse of the Hellenic orogen along large detachment faults, which exhumed extensive metamorphic core complexes in mainly two regions, the Rhodopes and the Cyclades. The detachment faults and supra-detachment basins controlled magma emplacement, fluid circulation, and mineralization.The most significant mineralization styles comprise porphyry, epithermal, carbonate-replacement, reduced intrusion-related gold, intrusion-related Mo-W and polymetallic veins. Porphyry and epithermal deposits are commonly associated with extensive hydrothermal alteration halos, whereas in other cases alteration is of restricted development and mainly structurally controlled. Porphyry deposits include Cu-Au-, Cu-Mo-Au-Re, Mo-Re, and Mo-W variants. Epithermal deposits include mostly high- and intermediate-sulfidation (HS and IS) types hosted in volcanic rocks, although sedimentary and metamorphic rock hosted mineralized veins, breccias, and disseminations are also present. The main metal associations are Cu-Au-Ag-Te and Pb-Zn-Au-Ag-Te in HS and IS epithermal deposits, respectively. Major carbonate-replacement deposits in the Kassandra and Lavrion mining districts are rich in Au and Ag, and together with reduced intrusion-related gold systems played a critical role in ancient economies. Finally hundreds of polymetallic veins hosted by metamorphic rocks in the Rhodopes and Cyclades significantly add to the metal endowment of Greece.     

Combined zircon and cassiterite U–Pb dating of the Piaotang granite-related tungsten–tin deposit,southern Jiangxi tungsten district,China

The large low-grade Piaotang W–Sn deposit in the southern Jiangxi tungsten district of the eastern Nanling Range, South China, is related to a hidden granite pluton of Jurassic age. The magmatic-hydrothermal system displays a zonation from an inner greisen zone to quartz veins and to peripheral veinlets/stringers (Five-floor zonation model). Most mineralization is in quartz veins with wolframite > cassiterite. The hidden granite pluton in underground exposures comprises three intrusive units, i.e. biotite granite, two-mica granite and muscovite granite. The latter unit is spatially associated with the W–Sn deposit.Combined LA-MC-ICP-MS U–Pb dating of igneous zircon and LA-ICP-MS U–Pb dating of hydrothermal cassiterite are used to constrain the timing of granitic magmatism and hydrothermal mineralization. Zircon from the three granite units has a weighted average ²⁰⁶Pb/²³⁸U age of 159.8 ± 0.3 Ma (2 σ, MSWD = 0.3). The cathodoluminescence (CL) textures indicate that some of the cassiterite crystals from the wolframite-cassiterite quartz vein system have growth zonations, i.e. zone I in the core and zone II in the rim. Dating on cassiterite (zone II) yields a weighted average ²⁰⁶Pb/²³⁸U age of 159.5 ± 1.5 Ma (2 σ, MSWD = 0.4), i.e. the magmatic and hydrothermal systems are synchronous. This confirms the classical model of granite-related tin–tungsten mineralization, and is against the view of a broader time gap of >6 Myr between granite magmatism and W–Sn mineralization which has been previously proposed for the southern Jiangxi tungsten district. The elevated trace element concentrations of Zr, U, Nb, Ta, W and Ti suggest that cassiterite (zone II) formed in a high-temperature quartz vein system related to the Piaotang granite pluton.     

The Cenomanian–Turonian Boundary Event (CTBE) on the southern slope of the Subalpine Basin (SE France) and its bearing on a probable tectonic pulse on a larger scale

The Cenomanian–Turonian Boundary Event (CTBE) event is not associated with a transgression on the southern margin of the Subalpine Basin, but with a steady shallowing-up trend beginning in the lower half of the δ¹³C positive shift. The SW–NE Rouaine Fault had a complex role, first in isolating a black shale basin to the west and a large, deep submarine plateau devoid of black shale to the east, then by a strike-slip movement that induced a forced progradation to the north of the southern platform in the eastern compartment. This compressive tectonic reactivation of the southern margin began around the deposition of the local equivalent of the Plenus bed of boreal basins, as shown by correlation supported by both isotope and palaeontological data. Other local data are pieced together to suggest that the whole of SE France underwent a short-lived transpressive tectonic pulse around the Cenomanian–Turonian boundary, probably connected with the early compressive movement of Africa vs. Europe. On a larger scale, other published data suggest that this pulse could be a global one. It is coeval with renewed thrust loading, volcanism and transgression in the North-American Western Interior, local emergences during the event along the eastern Atlantic margin, suggesting a slight tendency to inversion of the margin, and a tilting to the east of the North-Africa plate that could explain the large transgression recorded from Morocco to Tunisia on the Saharan Craton.New isotope and palaeontological (coiling ratio of Muricohedbergella delrioensis) data from SE France suggest that two coolings of suprabasinal importance occurred just before and during the build-up of the d¹³C shift, including the boreal “Plenus Marls“, especially its middle limestone bed and its SE France equivalent.Regarding the extinction of the genus Thalmaninella and Rotalipora and during the event, neither anoxia nor climate changes can fully explain the palaeontological crisis, given that Rotalipora cushmani crosses the first phase of anoxia without harm, as well as the two coolings, not only in SE France but on a large scale, as shown by the correlation of the published data. This extinction needs alternative explanations as we challenge both anoxia and climate as major causes.     

A 2.5-D coupled FE–BE model for the dynamic interaction between saturated soil and longitudinally invariant structures

A two-and-a-half-dimensional (2.5-D) coupled finite element–boundary element (FE–BE) model is presented to simulate the three-dimensional dynamic interaction between saturated soils and structures with longitudinally invariant geometries. A regularized 2.5-D boundary integral equation for saturated porous media is derived that avoids the evaluation of singular traction integrals. The 2.5-D coupled FE–BE model is established by using the continuity conditions on the soil–structure interface. The developed model is verified through comparison with an existing semi-analytical method. Two case studies of a tunnel embedded in a poroelastic half-space and the efficiency of a vibration isolating screen are presented.     

滇黔桂卡林型金矿区水系沉积物和岩石金含量与时空分布

为研究滇黔桂卡林型金矿区水系沉积物和岩石中金的地球化学时空分布及其与金矿规模的对应关系,系统收集了该区1:20万区域化探全国扫面计划水系沉积物和全国地球化学基准计划岩石金的地球化学数据,绘制了水系沉积物和岩石金的地球化学分布图.滇黔桂卡林型金矿区以水系沉积物金地球化学异常面积大于1000 km2为准,共圈定5处金的地球化学省,这些金的地球化学省同时也是矿床大规模产出的部位.区内右江盆地水系沉积物金背景值(1.94×10–9)高于扬子克拉通(1.68×10–9),其内以泥岩、页岩、砂岩、灰岩为代表的容矿岩石金背景值(0.51×10–9)也高于扬子克拉通(0.39×10–9).研究区不同构造单元及沉积相中水系沉积物金背景值受岩石金背景值的制约.金的地球化学省是地壳演化过程中不均匀分布的高金背景岩石、金矿化作用及金矿床次生风化作用相互叠加的结果.该研究有助于有效判断异常成因、识别成矿作用存在,对研究金的区域成矿规律和聚焦找矿靶区具有重要意义.     

黑龙江省中部森林沼泽区金在土壤A层中的富集规律

探讨了金在黑龙江省中部森林沼泽区A层土壤-10~+60目、-60~+100目、-100~+160目及-160目粒级中的含量分布特征和富集规律.经对比研究认为,-100目可以满足低密度深穿透地球化学详细测量采样要求,该粒级能够有效地发现异常.     

广西崇左三合巨猿大洞早更新世小哺乳动物群

最近在广西崇左三合大洞发现了步氏巨猿和似人似猿共生的新层位,与之伴生的有52种小哺乳动物,占三合大洞巨猿动物群总数的62%,其中苏门答腊兔（Nesolagus）是东南亚地区首次发现的化石。小哺乳动物群以南方早更新世常见的偏皮氏毛耳飞鼠（Belomys parapearsoni）、中间猪尾鼠（Typhlomys intermedius）、拟低冠竹鼠（Rhizomys brachyrhizomyoides）、硕豪猪（Hystrix magna）、先社鼠（Niviventer preconfucianus）、拟爱氏巨鼠（Leopoldamysedwardioidesi）等为代表,根据小哺乳动物群性质和与其他动物群对比以及磁性地层年代测定,表明其时代应是早更新世中期（约距今120160万年前）。该动物群由树鼩、扁颅蝠、小彩蝠、飞松鼠、笔尾树鼠、猪尾鼠等几乎是旧大陆热带-亚热带森林型动物组成,缺少北方类型,基本上属于热带森林动物群,这表明了当时的自然景观为温暖湿润的热带雨林环境。三合大洞小哺乳动物群是广西地区的首次发现,对华南早更新世巨猿动物群详细划分,探讨步氏巨猿演化和早期人类环境背景等目前科学界关注的问题具有重要的意义。     

Strategies towards robust interpretations of in situ zircon Lu-Hf isotope analyses

The combination of U-Pb and Lu-Hf compositions measured in zircon crystals is a remarkably powerful isotopic couplet that provides measures on both the timing of mineral growth and the radiogenic enrichment of the source from which the zircon grew.The U-Pb age documents the timing of zircon crystallization/recrystallization and Hf isotopes inform on the degree to which the host melt was derived from a radiogenic reservoir(e.g.depleted mantle) versus an unradiogenic reservoir(e.g.ancient continental crust),or some mixture of these sources.The ease of generating large quantities of zircon U-Pb and Lu-Hf data has been in large part facilitated by instrument advances.However,the dramatic increase in time constrained zircon Lu-Hf analyses in the Earth science community has brought to the fore the importance of careful data collection and reduction workflows,onto which robust geological interpretations may be based.In this work,we discuss the fundamentals of Lu-Hf isotopes in zircon,which then allows us to provide a robust,accessible,methodology for the assessment of data quality.Additionally,we discuss some novel techniques for:data visualization—that facilitates better transparency of data interpretation;integration of geographic information—that may reveal spatial trends where temporal trends were only apparent before;and some novel statistical evaluation tools—that may provide more rigorous interand intra-sample comparisons.     

Early Cretaceous sedimentary provenance and structural evolution of the central Sanandaj–Sirjan Zone,Iran: implications for palaeogeographic reconstructions of the northern Neo-Tethyan margin

ABSTRACT

The Early Cretaceous was an important epoch in the evolution of the Earth system in which major tectonic episodes occurred, especially along the Alpine–Himalayan belt. The paucity of reliable palaeogeographic data from the central segment of this geological puzzle, however, hampers the reconstruction of a panoramic view of its Early Cretaceous palaeogeography and geodynamic setting. Here we present multidisciplinary provenance data from Lower Cretaceous strata of the overriding plate of the Neo-Tethyan subduction zone (the Sanandaj–Sirjan Zone; SSZ, of central Iran), including structural, basin-fill evolution, petrographic and geochemical analyses. Sandstone provenance analysis of Lower Cretaceous red beds suggests the occurrence of sub-mature litho-quartzose sandstones attributed to an active continental arc margin in convergent setting predominantly derived from plutonic, quartzose sedimentary and metamorphic rocks exposed in the central SSZ. Weathering indices indicate moderate chemical weathering in the source area which may be related to close source-to-sink relationships or arid climate. Our palaeogeographic reconstructions and original geological mapping indicate that the erosion of uplifted basement rocks exposed in horst blocks provided the sediment sources for the syn-extensional deposition of uppermost Jurassic–lowermost Cretaceous conglomerates and Lower Cretaceous siliciclastic red beds within a continental retro-arc basin during initiation of the ‘Neo-Tethys 2?. The polyphase tectonic reactivation along the principal fault of the study area controlled the syn- and post-extensional tectonostratigraphic evolution that reflect the corresponding mechanical decoupling/coupling along the northern Neo-Tethyan plate margin.