氯化钠存在下氯化亚锡—罗丹明B—水体系浮选分离铱

研究了Ir（Ⅲ）在NaCl存在下SnCl2－罗丹明B－水体系中的浮选行为，在1.0mol/L HCl介质中，Ir（Ⅲ）与Pd,Pt,Rh,Au同时被浮选，Ir（Ⅲ）的浮选率为99.2％，并与常见贱金属离子分离，被浮选分离的Ir可采用原子吸收法测定，结果与火试金分离富集法相符。精密度试验，相对标准偏差（RSD，n＝5）＜3％。     

彩色地图图像分色的研究及算法实现

研究了目前国内外现有的彩色地图图像分色算法 ,并在此基础上提出一种新的彩色地图图像自动分色算法。该算法直接利用彩色地图图像的颜色特点 ,并充分考虑图像的空间相关信息进行自动分色 ,最终可得到理想的分版图。     

The Impact Of Air-Flow Separation On The Drag Of The Sea Surface

An approach that allows assessment ofthe impact of air-flow separation (AFS) fromwave breaking fronts on the sea-surface drag is presented. Wave breaking fronts are modelled by the discontinuities of the sea-surface slope. It is assumedthat the dynamics of the AFS from wave breaking crests is similar to thatfrom the backward facing step. The form drag supported by an individualbreaker is described by the action of the pressure drop distributed alongthe forward face of the breaking front. The total stress due to the AFS isobtained as a sum of contributions from breaking fronts of different scales.Outside the breaking fronts the drag of the sea surface is supported by theviscous surface stress and the wave-induced stress. To calculate the stressdue to the AFS and the wave-induced stress a physical model of the wind-wavespectrum is used. Together with the model of the air flow described in termsof surface stresses it forms a self-consistent dynamical system for the seasurface-atmosphere where the air flow and wind waves are strongly coupled.Model calculations of the drag coefficient agree with measurements. It is shownthat the dimensionless Charnock parameter (roughness length normalized onthe square of the friction velocity and the acceleration of gravity)increases with the increase of the wind speed in agreement with fieldmeasurements. The stress due to the AFS normalized on the square of thefriction velocity is proportional to the cube of wind speed. At low windsthe viscous surface stress dominates the drag. The role of the form drag,which is the sum of the stress due to the AFS and the wave-induced stress, isnegligible. At moderate and high winds the form drag dominates. At windspeeds higher than 10 m s^-1 the stress supported by the AFS becomescomparable to the wave-induced stress and supports up to 50% of the totalstress.     

用载炭泡塑吸附原子吸收法测定地质样品中金

为达到简便、快速、准确测Au的目的，以泡塑为载体负载一定量的活性炭制成载炭泡塑，研究标准回收、酸度、流速及干扰试验结果，制定用载炭泡塑吸附，火焰原子吸收法测定地质样品中Au的实验方法，对部级含Au标样进行精度分析，并将测定外检样品的结果与活性炭富集及泡塑吸附法的测定结果做对照，表明该法具有较好的精密度和准确度，检出限为0.1ug/g，适合地质样品中Au的测定。     

新型环境矿物材料——堇青石质泡沫陶瓷的研制

以聚氨脂泡沫塑料为前驱体，高岭土、铝土矿和滑石为原料，经配方和工艺设计，制备了以堇青石为主晶相的泡沫陶瓷，制成品密度为0．310－0．447g/cm^3，气孔率为81．7％－87．6％，孔径为0．2－0．5mm,平均抗压强度为0．98MPa。探讨了烧成温度对材料气孔率、抗压强度和吸水率等性能的影响。     

Studies on Separation of Heavy Metals from Acidic Solutions by Foam Fractionation with Respect to an Application on Acidic Soil Extracts

An experimental investigation is presented on the batch foam fractionation of the heavy metal cations Pb²⁺, Cd²⁺, Cu²⁺, Sb³⁺ and As⁵⁺ from diluted aqueous solutions with hexamethylenedithiocarbamate (HMDC) as complexing agent and sodiumdodecylsulfate (SDS) as surfactant. Among the considered pH-values of 2,4 and 7 the pH 2 experiments allow a direct application of foam fractionation on acidic extracts from heavy metal contaminated soil. The experiments at pH 2 and pH 4 show better results than those at neutral pH. Although a simple device was used, a maximum enrichment factor of 13.8 and a minimum removal factor of 0.01 have been measured. The flotation with weak organic acids like citric acid (CA) and acetic acid (AA) show about 50–70% smaller enrichment factors than those acidified with hydrochloric acid. The dissolution and mixing of the reacting components as well as the concentration of the detergent and the gaseous volume flow can be regarded as basic parameters of foam fractionation.     

等离子体发射光谱法分析毒砂单矿物

研究了大孔膦酸树脂对毒砂中主、次和痕量元素的吸附行为及洗脱条件,结合巯基棉和TBP柱分离技术,建立了两个分离流程。在J-A1160型多道直读光谱仪上实现了毒砂单矿物中包括主量元素Fe和As在内的20个元素测定。主量元素As和Fe的相对标准偏差(n为5～10)分别为1.03％和0.9％,其它元素在5％～11％范围。流程经实际试样分析验证,结果与化学法相符。     

二苯硫脲－甲基异丁酮泡塑富集液珠萃取比色法测定化探样品中的金银

在１０％ＨＣＩ介质中，采用二苯硫脲（ＤＰＴＵ）－甲基异丁酮（ＭＩＢＫ）泡沫塑料富集，以金试剂液珠萃取比色法测定了化探样品中的Ａｕ和Ａｇ。方法的检出限：Ａｕ０．５×１０￣－９；Ａｓ５×１０￣－９（１０ｇ称样）。利用此方法制备了“野外快速分析箱”，可在野外简陋条件下进行现场测定。     

三相泡沫钻井液流变特性研究

三相泡沫钻进液流变模式可通过灰色关联分析法进行优选，卡森模式是描述该钻井液流变特性的主要模式，该钻井液表观粘度高，工应力较大，剪切稀释特性强，流变参数主要受气比和基浆性能影响。