Poynting and polarization vectors based wavefield decomposition and their application on elastic reverse time migration in 2D transversely isotropic media

With the progress in computational power and seismic acquisition, elastic reverse time migration is becoming increasingly feasible and helpful in characterizing the physical properties of subsurface structures. To achieve high-resolution seismic imaging using elastic reverse time migration, it is necessary to separate the compressional (P-wave) and shear (S-wave) waves for both isotropic and anisotropic media. In elastic isotropic media, the conventional method for wave-mode separation is to use the divergence and curl operators. However, in anisotropic media, the polarization direction of P waves is not exactly parallel to the direction of wave propagation. Also, the polarization direction of S-waves is not totally perpendicular to the direction of wave propagation. For this reason, the conventional divergence and curl operators show poor performance in anisotropic media. Moreover, conventional methods only perform well in the space domain of regular grids, and they are not suitable for elastic numerical simulation algorithms based on non-regular grids. Besides, these methods distort the original wavefield by taking spatial derivatives. In this case, a new anisotropic wave-mode separation scheme is developed using Poynting vectors. This scheme can be performed in the angle domain by constructing the relationship between group and polarization angles of different wave modes. Also, it is performed pointwise, independent of adjacent space points, suitable for parallel computing. Moreover, there is no need to correct the changes in phase and amplitude caused by the derivative operators. By using this scheme, the anisotropic elastic reverse time migration is more efficiently performed on the unstructured mesh. The effectiveness of our scheme is verified by several numerical examples.     

Non-point source pollution estimation in the Pingqiao River Basin,China, using a spatial hydrograph-separation approach

For efficient and targeted management, this study demonstrates a recently developed non-point source (NPS) pollution model for a year-long estimation in the Pingqiao River Basin (22.3 km²) in China. This simple but physically reasonable model estimates NPS export in terms of land use by reflecting spatial hydrological features and source runoff measurements under different land-use types. The NPS export was separately analysed by a distributed hydrological model, a spatial hydrograph-separation technique, and an empirical water quality sub-model. Simulation results suggest that 57 890 kg of total nitrogen (TN) and 1148 kg of total phosphorus (TP) were delivered. The results, validated with observed stream concentrations, show relative errors of 23.3% for TN and 47.4% for TP. Countermeasures for urban areas (5.3% of total area) were prioritized because of the high contribution rate to TN (14.1%) and TP (26.2%) which is caused by the high degree of runoff (8.5%) and pollution source.     

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Na+,K+,Rb+,Cs+//SO2-4-H2O体系固液相平衡热力学模拟

锂云母、铯榴石等矿物的硫酸盐焙烧浸出,是从中提取锂铷铯钾等碱金属元素的重要步骤,所得硫酸盐浸出液可近似看作Li⁺,Na⁺,K⁺,Rb⁺,Cs+ // SO₄2--H₂O六元水盐体系;其在浓缩过程呈现复杂的成盐特征,增加了各碱金属元素分离提取的难度,研究其相关水盐体系相图和相平衡性质对理解浸出液中碱金属的分离具有重要的理论指导意义。本文采用Pitzer-Simonson-Clegg超额Gibbs自由能方程和具有内在热力学一致性的CALPHAD方法,构建了Na⁺,K⁺,Rb⁺,Cs⁺//SO₄2--H₂O五元体系的多温固液相平衡热力学模型。借助该模型:1)实现了对Na₂SO₄₊Rb₂SO₄₊H₂O、Na₂SO₄₊Cs₂SO₄₊H₂O和K₂SO₄₊Cs₂SO₄₊H₂O三元体系的多温溶解度等温线的准确描述,并进一步构建了这些体系在240.15~380.15 K温度范围内的多温相图;2)实现了对K₂SO₄+Rb₂SO₄₊H₂O和Rb₂SO₄₊Cs₂SO₄₊H₂O体系中存在的固溶体相—水溶液平衡关系的准确描述,确认了(K,Rb)₂SO₄连续固溶体、以及(Rb,Cs)₂SO₄(α)和(Rb,Cs)₂SO₄(β)间断固溶体存在的合理性;3)预测了上述五元体系中所包含的全部4个四元子体系(Na₂SO₄₊ K₂SO₄₊ Rb₂SO₄+H₂O、Na₂SO₄ + K₂SO₄₊Cs₂SO₄₊ H₂O、Na₂SO₄₊ Rb₂SO₄₊Cs₂SO₄ + H₂O和K₂SO₄₊Rb₂SO₄₊Cs₂SO₄₊ H₂O)的相图,明确了四元相图中固溶体的类型及形成区域。然而,模型预测结果与现有四元体系实验数据间存在普遍的不一致性,尤其是固溶体形成区域,但模型预测结果从非实验角度给出了重要参考,对现有实验提出了挑战,未来对这些体系开展更为精细的实验研究非常必要。     

离线固相萃取螯合富集分离-ICP-MS测定海水中的稀土元素

通过测定条件优化、方法比对等实验建立了一种固相萃取小柱离线螯合富集分离电感耦合等离子体质谱仪测定海水中稀土元素的方法。海水样品通过调节p H后,进入VAC ELUT SPS24 Agilent圆形固相萃取装置,其主要基体物质的去除率高于97%;萃取富集的优化条件是海水样品p H 4.0~7.0,海水进入萃取柱速率2 m L/min,硝酸洗脱液浓度为1 mol/L;方法对稀土元素的加标回收率为83%~108%,14种稀土元素的检出限为0.057~0.613 ng/L,RSD10%;该方法与氢氧化铁共沉淀法富集稀土元素比对测定结果一致,方法具有准确度与精密度高、操作简便快速等优点,可用于海水样品中稀土元素的定量精确测量。     

天山山区典型内陆河流域径流组分特征分析

通过对天山南北坡的两个典型流域降水、地下水、河流、融冰雪水δD和δ¹⁸O及水化学检测,基于同位素径流分割模型定量分析了年内径流组分特征。结果表明：（1）两条河流的径流组成中地下水为构成径流的主要成分,其次是冰川融水,融雪水及降水,但南北坡径流组分表现出较明显的差异,乌鲁木齐河流域中冰川融水的比重要大于黄水沟流域,对气候变化响应明显。（2）两条河流在不同季节径流组分也表现出较大差异,春季径流组分差异最为明显。     

中国城市居民的家庭代际分/合居行为及其影响要素——以成都市为例

1978年以来,中国家庭小型化趋向非常显著,尤以代际分居为核心诱因,代际分居对转型期中国的社会稳定、家庭和睦乃至住房市场都构成了很大的影响。而且,中国的代际分居现象及其机制和西方社会存在根本的不同,此文讨论了转型期基于代际分居率和家庭生命周期的中国城市居民分/合居行为的概念模型,随后选择成都市主城区进行了实证,因为该地区不但社会经济发展速度快,户籍居民的老龄化趋向明显,而且兼受中国传统文化和西方文化的耦合影响。与西方发达社会基于家庭生命周期先合居、后分居的规律不同,中国城市居民家庭居住行为呈现出合居—（小）分居—合居—分居—（小）合居—（小）分居—（小）合居的变化过程。采用2012-2013年的实地调研数据,采用Pearson相关性分析法提取主要影响因素,后采用二元logistic 回归方法研究了主要因素对居民分/合居行为的显著性和正负影响,并对不同年龄段的城市居民家庭代际分/合居行为的代际分/合居选择及其影响因素进行了分析。结论如下：① 文化程度、配偶健在、家庭人均收入、父母应帮子女成家、父母应帮子女买房、与子女/父母代际分居意愿、作息习惯、饮食习惯、安静/热闹偏好、卫生习惯、居家习惯和私密空间习惯与家庭代际分居率正向显著;② 年龄、家庭居住面积、父母应帮忙抚养孙辈、（子女）应该养老、父母/子女应临近居住、养儿防老、养育习惯等变量与家庭代际分居率负向显著;③ 不同年龄段居民的代际分/合居选择的影响因素及其显著度有所差异。     

基于桩身应力测试的静压PHC管桩贯入机制

压桩过程中PHC管桩侧摩阻力与端阻力的分离是制约其贯入机制及承载力研究的瓶颈。通过桩身预埋准分布式FBG光纤传感器,对贯入成层土地基中5根足尺开口PHC管桩侧摩阻力及端阻力发展变化情况进行了监测。试验表明,准分布式光纤传感测试技术现场可操作性强,粗放施工环境下贯入阻力分离效果较为理想。成层土地基中压桩力曲线基本反映地层土性变化,桩端土层性状对压桩力影响较大。硬质土层界面处试桩压桩力平均增幅约为64.06%,端阻力受地层变化影响更为显著,平均增长幅度约为97.41%,侧摩阻力平均增长幅度约为17.92%;桩端位于非硬质土层试桩压桩力变化不明显。贯入过程中现场足尺试验桩身应力变化不同于室内模型试验,桩身上、下部侧摩阻力发挥的力学机制不同。受现场粗放施工条件及深度方向土层变化影响,贯入成层土地基中桩侧摩阻力临界深度现象不明显。     

top-hat变换与庐枞矿集区大地电磁强干扰分离

作为一种非线性信号处理方法,基于数学形态学的广义形态滤波已经展现出其在大地电磁时间域信号去噪中的作用;然而,广义形态滤波在滤除大地电磁时间域信号中噪声波形的同时,也滤除了时间域信号中包含有用信息的缓变化。针对这一问题,提出一种基于数学形态学top-hat变换的大地电磁时间域噪声压制方案,利用top-hat变换对波峰和波谷的检测能力,采用直线型结构元素,对大地电磁时间域信号进行去噪。用该方法对庐枞矿集区大地电磁实测数据进行处理后,数据的标准差与曲线相似性参数都优于处理前数据,表明所提方法能够去除噪声波形并保留时间域信号的缓变化,恢复受噪声污染的大地电磁时间域信号,提高大地电磁视电阻率曲线的质量。     

High-Frequency Rayleigh-Wave Method

High-frequency (≥2 Hz) Rayleigh-wave data acquired with a multichannei recording sys-tem have been utilized to determine shear (S)-wave velocities in near-surface geophysics since the early 1980s. This overview article discusses the main research results of high-frequency surface-wave tech-niques achieved by research groups at the Kansas Geological Survey and China University of Geosciences in the last 15 years. The multichannel analysis of surface wave (MASW) method is a nou-iuvasive acoustic approach to estimate near-surface S-wave velocity. The differences between MASW results and direct borehole measurements are approximately 15% or less and random. Studies show that simultaneous inversion with higher modes and the fundamental mode can increase model resolution and an investigation depth. The other important seismic property, quality factor (Q), can also be estimated with the MASW method by inverting attenuation coefficients of Rayleigh waves. An inverted model (S-wave velocity or Q) obtained using a damped least-squares method can be assessed by an optimal damping vector in a vicinity of the inverted model determined by an objective function, which is the trace of a weighted sum of model-resolution and model-covariance matrices. Current developments include modeling high-frequency Rayleigh-waves in near-surface media, which builds a foundation for shallow seismic or Rayleigh-wave inversion in the time-offset domain; imaging dispersive energy with high resolution in the frequency-velocity domain and possibly with data in an arbitrary acquisition geometry, which opens a door for 3D surface-wave techniques; and successfully separating surface-wave modes, which provides a valuable tool to perform S-wave velocity profiling with high-horizontal resolution.