Electron Probe Microanalysis of Environmental Samples: Preparation of Reference Materials, Correction for Particle Size Effects and Representative Results on Sediments Recovered from Snow, Power Station Fly Ash and Bone Samples

In this paper we report the results of electron probe X-ray microanalysis (EPMA) that was used to study environmental materials. The mode of preparation and certification of reference samples based on a basaltic glass matrix for environmental applications of EPMA is described. These samples were prepared containing scandium, strontium and barium (from 0.03 up to 7% m/m) and an evaluation was made of homogeneity, their stability to local heating, followed by analysis by independent methods for certification of composition. Matrix correction procedures for the EPMA technique have been developed for particles having a size commensurable with the volume of X-ray generation. An analytical equation for the size factor is proposed and two techniques for selecting optimum conditions for the analysis of environmental samples by EPMA are reported. These procedures provided satisfactory results when utilized in analysing sediments recovered from snow, coal fly ash and the bones of animals and fish, results from which can be used as indicators for evaluating the pollution level of the lower atmosphere, surface and ground water, as well as revealing pollution mechanisms.     

Geochemistry, mineralogy, and technological properties of the main Stephanian (Carboniferous) coal seams from the Puertollano Basin, Spain

This study is focused on the occurrence and distribution of mineral matter and major and trace elements in the high volatile bituminous coal from Puertollano (south-central Spain). The relationship between ash behaviour and inorganic composition, as well as the possible formation of fouling and slagging deposits in boilers during the conversion process, were investigated. The Puertollano coals do not exhibit plastic properties, despite their rank, probably because of their high ash and inertinite contents.The Puertollano coal has medium to low total S content (0.48% to 1.63% db, with a mean of 1.0% db) and is characterised by relatively high contents of Si, Pb, Sb, and Cs. Some elements such as As, Cd, Co, Cr, Cu, Ge, Li, Mn, Ni, W, and Zn are also present in relatively high contents. The enrichment in a number of heavy metals could be attributed to the common sulphide ores occurring near the Puertollano coal deposit.The following trace elements affinities are deduced: (a) sulphide affinity: As, Co, Cd, Cu, Ni, Sb, Tl, and Zn; (b) aluminum–silicate affinity: K, Ti, B, Co, Cr, Cs, Cu Ga, Hf, Li, Nb, Rb, Sn, Ta, Th, V, Zr, and LREE; (c) Carbonate affinity: Ca, Mg, Mn, and B; (d) organic affinity: B.The very high Si levels and the anomalous enrichment in Cs, Ge, Pb, Sb, and Zn shown by the Puertollano coals account for the high contents of these elements in the Puertollano fly ash when compared with the other Spanish coal fly ashes.The chemical composition of the high temperature ash (HTA) is consistent with the trend shown by the ash fusion temperatures (AFT) and also with the predictive indices related to slagging and fouling propensities. Thus, the ash fusion temperatures increase with high values of Al₂O₃ as well as with the decrease in Fe₂O₃, CaO, and MgO.     

粉煤灰扰动样现场取样问题初步探讨

本文结合福州电厂粉煤灰室内试验结果分析，探讨粉煤灰扰动样现场取样及试验控制干密度的等问题，该电厂粉煤灰的沉积规律与其它电厂有所不同，灰料颗粒组细分布和距排灰口远近基本无关，取样也不能按以往经验进行。     

Tephrochronology of the Kamchatka–Kurile and Aleutian arcs: evidence for volcanic episodicity

Volcanic ash layers in North Pacific deep-sea sediment provide a record of episodic explosive volcanism in the Kamchatka–Kurile and Aleutian arcs over the past five million years. We counted 450 ash layers, determined layer thickness and cumulative ash thickness to quantify the flux of ash with time. We use this record to investigate the eruptive history of these arcs, test the reliability of the marine ash record, and inquire into the regional episodicity of North Pacific explosive volcanic history. Episodes of explosive volcanism occurred at approximately 0.2–0.5, 0.7–0.9, 1.5–1.7, and 2.5–2.65 Ma in the Kamchatka arc and 0.15–0.4, 1.7–1.8, 2.55–2.65, and at 3.0–3.1 Ma in the eastern Aleutian arc. These generally coeval eruptive episodes suggest that the pulses in explosive volcanism in the North Pacific enumerated here and recognized by others are regionally episodic over a wide portion of the Pacific rim and not just a response to local volcanogenic processes.     

华北石炭二叠纪煤系中I／S间层矿物的研究

华北石炭二叠煤系中的Ｉ／Ｓ间层粘土岩夹矸或粘土岩层，在太行山以东较为发育。Ｉ／Ｓ间层矿物的类型有累托石、ＩＳ有序间层矿物、Ｓ／Ｉ无序间层矿物，它们是在近岸泥岩沼泽或沼泽环境中由同期降落的火山灰蚀变而成，在酸性介质的影响下，形成ＩＳ有序间层矿物，在偏碱性的介质条件下，形成Ｓ／Ｉ无序间层矿物；高压异常区则形成累托石。     

控制粉煤灰密实度以替代砂类土的原位测试

本文是一例研究粉煤灰替代排水砂沟中以黄砂为材料的原位试验。通过建立静力触探比贯入阻力与干容重的相关关系,找出达到设计要求的7.5 KN/m干容重的最佳夯实击数(振密遍数),从而有效地控制了粉煤灰的密实度。     

The importance of grain size and shape in controlling the dispersion of the Vedde cryptotephra

Volcanic ash is dispersed in the atmosphere according to meteorology and particle properties, including size and shape. However, the multiple definitions of size and shape for non-spherical particles affect our ability to use physical particle properties to understand tephra transport. Moreover, although particles are often excluded from operational ash dispersion model setups, ash in tephra deposits 1000 km from source can exceed . Here we measure the shape and size of samples of Vedde ash from Iceland, an exceptionally widespread tephra layer in Europe, collected in Iceland and Norway. Using X-ray computed tomography and optical microscopy, we show that distal ash is more anisotropic than proximate ash, suggesting that shape exerts an important control on tephra dispersion. Shape also impacts particle size measurements. Particle long axis, a parameter often reported by tephrochronologists, is on average greater than geometric size, used by dispersion modellers. By using geometric size and quantifying shape, we can explain the transport of Vedde ash particles more than 1200 km from source. We define a set of best practices for measuring the size and shape of cryptotephra shards and discuss the benefits and limitations of using physical particle properties to understand cryptotephra transport.     

Relationship of chemical fractions of heavy metals with microbial and enzyme activities in sludge and ash-amended acid lateritic soil from India

The influence of metals, Cd, Cr, Cu, Ni, Pb and Zn, on the microbial biomass and enzyme activities of an amended acid lateritic soil were investigated under field conditions receiving a one-time application of 52 t ha^–1 of sludge, coal ash and their mixtures at 1:3, 1:1 and 3:1 proportions, and including control and chemical fertilizer treatment at crop-specific recommended doses. Paddies and peanuts were grown in the experimental plots and soil was sampled twice after 6 months and 1 year after amendment application. The heavy metals in the soil were fractionated using sequential extraction and the increments in their concentrations in amended soil with respect to the control were determined. Concentrations of Cd, Ni and Zn were determined to have increased in their mobile fractions and were more pronounced in soil collected during the second sampling, which was associated with a decrease in soil organic carbon. The size of the microbial biomass carbon and the soil enzyme activities increased with the addition of an amendment and was highest at equal proportions of coal ash and sludge. Further increase in the proportion of sludge resulted in a significant decrease in biomass carbon. Simple correlation revealed significant and strong negative relations of mobile fractions of Cd and Ni with the ratio between microbial biomass C and organic carbon in soil, while the organic carbon content and the pH were positively correlated. The microbial activities were determined to be sensitive to the concentrations of some heavy metals in mobile fractions and therefore indicated possibilities of being useful as indicators for evaluation of toxic effects of sludge-borne metals on soil organisms.     

Integrated satellite observations of the 2001 eruption of Mt. Cleveland, Alaska

Satellite data were the primary source of information for the eruption of Mt. Cleveland, Alaska on 19 February, and 11 and 19 March 2001. Multiple data sets were used pre-, syn- and post-eruption to mitigate the hazard and determine an eruption chronology. The 19 February eruption was the largest of the three, resulting in a volcanic cloud that formed an arc over 1000 km long, moved to the NE across Alaska and was tracked using satellite data over more than a 50-h period. The volcanic cloud was “concurrently” detected on the GOES, AVHRR and MODIS data at various times and their respective signals compared. All three sensors detected a cloud that had a very similar shape and position but there were differences in their areal extent and internal structural detail. GOES data showed the largest volcanic cloud in terms of area, probably due to its oblique geometry. MODIS bands 31 and 32, which are comparable to GOES and AVHRR thermal infrared wavelengths, were the least effective single channels at detecting the volcanic cloud of those investigated (MODIS bands 28, 29, 31 and 32). MODIS bands 28 and 29 detected the largest volcanic clouds that could easily be distinguished from weather clouds. Of the split-window data, MODIS bands 29 minus band 32 detected the largest cloud, but the band 31 minus band 32 data showed the volcanic cloud with the most internal structural detail. The Puff tracking model accurately tracked the movement, and predicted the extent and shape of this complex cloud even into areas beyond satellite detection. Numerous thermal anomalies were also observed during the eruption on the twice-daily AVHRR data and the high spatial-resolution Landsat data. The high-resolution Radarsat data showed that the AVHRR thermal anomalies were due to lava and debris flow features and a newly formed fan along the west coast of the island. Field observations and images from a hand-held Forward Looking Infrared Radiometer (FLIR) showed that the flow features were ′a′a lava, debris flows and a warm debris fan along the west coast. Real-time satellite data were the primary tool used to monitor the eruption, track changes and to mitigate hazards. High-resolution data, even though coverage is infrequent, were critical in helping to identify volcanic processes and to compile an eruption chronology.     

A model for the numerical simulation of tephra fall deposits

A simple semianalytical model to simulate ash dispersion and deposition produced by sustained Plinian and sub-Plinian eruption columns based on the 2D advection–dispersion equation was applied. The eruption column acts as a vertical line source with a given mass distribution and neglects the complex dynamics within the eruption column. Thus, the use of the model is limited to areas far from the vent where the dynamics of the eruption column play a minor role. Vertical wind and diffusion components are considered negligible with respect to the horizontal ones. The dispersion and deposition of particles in the model is only governed by gravitational settling, horizontal eddy diffusion, and wind advection. The model accounts for different types and size classes of a user-defined number of particle classes and changing settling velocity with altitude. In as much as wind profiles are considered constant on the entire domain, the model validity is limited to medium-range distances (about 30–200 km away from the source).The model was used to reconstruct the tephra fall deposit from the documented Plinian eruption of Mt. Vesuvius, Italy, in 79 A.D. In this case, the model was able to broadly reproduce the characteristic medium-range tephra deposit. The results support the validity of the model, which has the advantage of being simple and fast to compute. It has the potential to serve as a simple tool for predicting the distribution of ash fall of hypothetical or real eruptions of a given magnitude and a given wind profile. Using a statistical set of frequent wind profiles, it also was used to construct air fall hazard maps of the most likely affected areas around active volcanoes where a large eruption is expected to occur.