Geotechnical Properties of Low Calcium and High Calcium Fly Ash

In this paper, a comparative study has been made for physical and engineering properties of low calcium and high calcium Indian fly ash. The grain size distribution of fly ash is independent of lime content. Fly ash particles of size >75 μm are mostly irregular in shape whereas finer fractions are spherical for low calcium fly ash. For high calcium fly ash, chemical and mineralogical differences have been observed for different size fractions. Compared to low calcium fly ash, optimum moisture content is low and maximum dry density is high for high calcium fly ash. Optimum moisture content is directly proportional and maximum dry density is inversely proportional to the carbon content. The mode and duration of curing have significant effect on strength and stress–strain behavior of compacted fly ash. The gain in strength with time for high calcium fly ash is very high compared to that of low calcium fly ash due to presence of reactive minerals and glassy phase.     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

上海洋山建港后港域夏季水文泥沙状况分析

对2007年9月17-26日在上海洋山港海域固定观测点(平均水深13 m)观测得到的水文泥沙要素,以及悬沙和底质样品分析.分析结果为:1)港域有效波高0.21-1.37 m(风速0.6～14.0 m/s),平均0.61 m(平均风速5.5 m/s).平静天气(平均风速小于5.0 m/s)下,波高随水深变化,两者的相关系数为0.899;而在强风天气下,波高受风况控制.2)最大表层流速超过2.00 m/s.大潮涨潮流占优势,小潮时落潮流占优势;与北岛链汉道封堵前相比,大潮涨、落潮平均流速分别减小15%和30%,小潮涨、落潮平均流速均减小30%～40%.各层余流均为西北方向,与涨潮流方向一致;垂向平均余流速0.11 cm/s,表层达0.25 m/s.3)离底高程1.35 m层和0.35m层最大悬沙浓度均大于3 kg/m3,两层平均悬沙浓度分别为0.89和0.95 kg/m3.无论大潮还是小潮涨潮悬沙浓度均大于落潮,这种现象在大潮时更为显著,潮周期中最大悬沙浓度出现在涨急.与工程前相比悬沙浓度明显降低,大、小潮降低均达20%.4)港区底质平均粒径9.0μm,工程后有变细的趋势.     

海洋环境下粉煤灰混凝土的抗冻性与抗氯离子渗透性的耦合

针对海洋环境条件,重点研究了粉煤灰混凝土的抗冻性和氯离子渗透性能的相互关系.试验分别研究了水胶比、粉煤灰等量取代水泥掺量大小、引气剂掺量等因素对抗冻性和抗氯离子渗透性能的影响,并与普通混凝土进行了对比.结果表明,粉煤灰不增加混凝土的抗海水冻融耐久性;粉煤灰增加混凝土的抗氯离子渗透性能,但是掺量超过30%,抗氯离子渗透性能下降;粉煤灰对混凝土抗冻性和抗氯离子渗透性的耦合影响在30%左右存在一个最佳掺量.为评估混凝土的抗冻性和氯离子扩散性的耦合性能,提出了新的评价方法--冻渗比(R值方法),并进行了试验验证.SEM和MIP微观分析与R值方法评价的结果是吻合的.     

用伽玛—伽玛测井的低能组分测定煤灰分的可能

伽玛—伽玛测井中的散射伽玛射线低能部分的强度和地层的原子序数有关,因而能用来对煤层的灰分值作原位测量。对8个矿区164个煤样的计算表明,这种用煤层等效原子序数来确定灰分值的方法对煤的变质程度、水分含量变化不敏感,但对灰的元素组成变化,尤其是Fe     

初始中主应力系数对中密粉煤灰动模量阻尼比影响的试验研究

利用土工静力-动力液压三轴-扭转多功能剪切仪,开展了在三向非均等固结状态下的饱和中密粉煤灰循环扭剪试验。着重探讨了初始中主应力系数对饱和中密粉煤灰的动模量和阻尼比特性的影响。试验结果表明：初始中主应力系数对粉煤灰动剪切模量有一定的影响,对阻尼比没有影响。根据仪器量测系统的特点,采用了大小位移计联合测量角位移的方法,不仅能够提高测试精度,而且能够获得完整的动模量和阻尼比随动剪应变幅值的变化过程。     

油页岩灰渣提取氧化铝制备铝酸盐发光材料

利用干馏后的油页岩灰渣,湿法提取氧化铝作为发光材料基质,经采用高温固相法合成 CaAl2O4 : Eu3 + ,R + ( R = Li,Na,K,Rb) 荧光粉。最佳合成条件为: 烧结温度1 200 ℃,烧结时间3 h,助熔剂加入量3 wt%,激活离子配比3 mol%; 实验发现辅助激活离子为Li + 时,CaAl2O4 : Eu3 + , Li + 的发光强度最强。样品荧光光谱分析结果表明,发射光谱在615 nm 处出现强谱峰,归属为Eu3 + 的5D0→7F2 跃迁辐射。     

Removal of Cu(Ⅱ) from Wastewater Using Acidified Sewage Sludge Ash

Sewage sludge ash (SSA), the waste generated in sewage sludge incineration, was obtained from Wuhan Sewage Treatment Plant and used as a low-cost sorbent for removing Cu(Ⅱ) from wastewaters. The sorbent was first modified with 5 % sulfuric acid to increase its sorption capacity. The specific surface area, porosity, cation-exchange capacity (CEC) and pHZPC of the sorbent were measured. Batch experiments were made to study the effect of contact time, solution pH value and temperature on sorption. Both Langmuir and Freundlich models well described the Cu(Ⅱ) sorption process, with correlation coefficient (R2) values of 0.993 4 and 0.989 9 respectively. And the sorption process follows the Lagergren first order kinetic model. The equilibrium sorption capacity of acidified SSA to Cu(Ⅱ) is estimated to be 7.78 mg/g under optimal conditions.     

重复利用的城市垃圾炉渣无侧限抗压强度实验

以江苏某城市的垃圾炉渣为实验材料,通过标准分析筛得到粒径小于等于2mm的颗粒,将制样重复利用后的炉渣颗粒配比成不同含水率后,通过分层击实实验制成不同干密度的试样,制样干密度为d=1.4、1.5和1.6的试样,制样模具为高80mm、直径39.1mm。不同干密度的试样分别做龄期为3d、7d、14d、28d无侧限抗压强度试验,其中一种干密度试样在某一龄期做5组实验以降低离散性的影响。通过大量的实验数据,研究重复利用后炉渣颗粒制成试样的强度随龄期、干密度的变化趋势,并与炉渣初次使用时制成的试样强度进行对比,得出炉渣的强度具有一定的离散性,但总体上随龄期和干密度的增加而增加,且炉渣颗粒重复利用后制成的试样强度有很明显的降低。对炉渣材料做XRD分析,以获得炉渣的主要组成成分来更好的理解炉渣试样的强度特性。文中得出的结论为更好的将炉渣应用到具体的工程中提供参考意见。     

Block‐and‐ash flow deposit of the Narcondam Volcano: Product of dacite–andesite dome collapse in the Burma–Java subduction complex

Narcondam Island in the Andaman Sea represents a dacite–andesite dome volcano in the volcanic chain of the Burma–Java subduction complex. The pyroclasts of andesitic composition are restricted to the periphery of the dome predominantly in the form of block‐and‐ash deposits and minor base surge deposits. Besides pyroclastic deposits, andesitic lava occurs dominantly at the basal part of the dome whereas dacitic lava occupies the central part of the dome. The pyroclasts are represented by non‐vesiculated to poorly vesiculated blocks of andesite, lapilli, and ash. The hot debris derived from dome collapse was deposited initially as massive to reversely‐graded beds with the grain support at the lower part and matrix support at the upper part. This sequence is overlain by repetitive beds of lapilli breccia to tuff breccia. These deposits are recognized as a basal avalanche rather than lahar deposit. This basal avalanche was punctuated by an ash‐cloud surge deposit representing a sequence of thinly bedded units of normal graded unit to parallel laminated beds.