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111.
峨嵋玄武岩同生流体包裹体在800℃爆裂后,2.0g/L NH4Cl溶液提取流体中Pt、Pd,C-410树脂富集-电感耦合等离子体质谱测定,方法相对误差小于25%。激光拉曼光谱与四级质谱测定包裹体的气液成分结果表明:流体中存在一定量的有机组分,这对Pt、Pd以有机螯合态形式进入流体提供了可能。 相似文献
112.
安徽铜陵矿集区海底喷流沉积体系的流体包裹体微量元素对比 总被引:7,自引:3,他引:7
铜陵矿集区与铜-金(多金属)矿床有关的热液活动主要有两大体系。即与海西期海底喷流沉积有关的热液体系和与矽卡岩矿化有关的燕山期岩浆热液体系。查明这两类热液体系的流体包裹体特征对区域找矿和矿床成因研究都有实际意义。在包裹体岩相学研究基础上,应用ICP-MS技术和热爆提取方法,研究了新桥、冬瓜山、峙门口、铜官山、朝山等矿床具代表性的热液石英中流体包裹体的微量元素、稀土元素特征。结果表明,两类热液体系在流体包裹体特征上有较大的区别,在流体的微量元素和稀土元素特征方面也很不相同。海底喷流沉积体系的热液石英中流体包裹体与岩浆热液体系的相比。稀土总量较高,LREE/HREE比值较大,δEu不明显。且Mo/(W Sn)比值较高,反映流体中成矿物质的深源特征;Ga/T1、Rb/Cs大。Zr/Hf低,也不同于岩浆热液体系。 相似文献
113.
南秦岭十里坪锑矿床成矿时代及成因的初步研究 总被引:1,自引:1,他引:1
十里坪锑矿床受赵川陆缘隆_滑构造的主滑脱拆离带的控制。矿体呈脉状赋存于韧_脆性主滑脱带上部的脆性次级断层_节理中,矿石类型主要为萤石石英辉锑矿型。围岩为太古宙_元古宙变质岩系,围岩蚀变弱。成矿流体属H2O_CO2_NaCl体系,流体包裹体盐度w(NaCleq)为3.6%~11.3%,均一温度为109~232℃,形成压力大致为800×105Pa。硫、铅同位素研究表明,矿质主要来源于变火山岩围岩;氢、氧同位素显示,成矿流体以大气降水为主,初步将该矿床定为变质岩源就地式大气降水热液矿床。矿石中萤石Sm_Nd等时线年龄为(392±24)Ma,与南秦岭北部晚古生代拗陷区热水喷流_沉积成矿时代相一致,它们都形成于秦岭微板块泥盆纪非造山裂解阶段。 相似文献
114.
Genesis of Kanggur Gold Deposit in Eastern Tianshan Orogenic Belt, NW China: Fluid Inclusion and Oxygen and Hydrogen Isotope Constraints 总被引:3,自引:0,他引:3
Abstract. Primary fluid inclusions in quartz and carbonates from the Kanggur gold deposit are dominated by aqueous inclusions, with subsidiary CO2 -H2 O inclusions that have a constant range in CO2 content (10–20 vol %). Microthermometric results indicate that total homogenization temperatures have a wide but similar range for both aqueous inclusions (120 to 310C) and CO2 -H2 O inclusions (140 to 340C). Estimates of fluid salinity for CO2 -H2 O inclusions are quite restricted (5.9∼10.3 equiv. wt% NaCl), whereas aqueous inclusions show much wider salinity ranging from 2.2 to 15.6 equivalent wt %NaCl.
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ18 O and δD values of the ore-forming fluids can be achieved by exchanged meteoric water after isotopic equilibration with wall rock by fluid/rock interaction at a low water/rock ratio. However, the exchanged meteoric water alone cannot explain the full range of δ18 O and δD values, magmatic and/or meta-morphic water should also be involved. The wide salinity in aqueous inclusions may also result from mixing of meteoric water and magmatic and/or metamorphic water. 相似文献
The 6D values of fluid inclusions in carbonates vary from -45 to -61 %, in well accord with the published δD values of fluid inclusions in quartz (-46 to -66 %). Most of the δ
115.
Methane-rich fluid inclusions in skarn near the giant REE–Nb–Fe deposit at Bayan Obo, Northern China
We report fluid inclusion data for skarn, formed at the contact between Hercynian granitoids and dolomite of the Proterozoic Bayan Obo Group, in the vicinity of Bayan Obo REE–Nb–Fe deposit, Inner Mongolia, China. Three types of fluid inclusions are identified: two-phase CH4-rich, three-phase liquid–vapour–solid and two-phase aqueous inclusions. Using microthermometry and laser Raman microprobe analysis to calculate isochores for CH4-bearing inclusions, we estimate fluid trapping conditions at T=280 to 344 °C and P<1 to 2.3 kbar. Such conditions are compatible with formation of CH4 inclusions as a result of reaction between graphite in the country rocks (black slate sequence) and fluids derived from magma. The lack of carbonaceous material in the inclusions supports the hypothesis that CH4 was generated during fluid migration rather than by in situ reaction. In contrast to the skarn, and despite the fact that similar graphite-bearing slates are found in the host rocks, no CH4-bearing inclusions have been so far reported from Bayan Obo REE ores. We therefore conclude that the skarn-forming fluids in the contact aureole of the Hercynian granitoids were not involved at any stage in the formation of the Bayan Obo deposit. 相似文献
116.
简要叙述了一种新型地下连续墙施工稳定液——聚合物溶液的研制及其与细分散泥浆性能的对比,这种新型聚合物溶液克服了目前使用的地下连续墙稳定液品种单一、性能较差的缺点,满足复杂地层的地下连续墙施工需要。同时阐述了这种稳定液的组成成分和性能及其主要特点。 相似文献
117.
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119.
Experiments were carried out on granular flows generated by instantaneous release of gas-fluidised, bidisperse mixtures and propagating into a horizontal channel. The mixture consists of fine (< 100 μm) and coarse (> 100 μm) particles of same density, with corresponding grain size ratios of ∼ 2 to 9. Initial fluidisation of the mixture destroys the interparticle frictional contacts, and the flow behaviour then depends on the initial bed packing and on the timescale required to re-establish strong frictional contacts. At a fines mass fraction (α) below that of optimal packing (∼ 40%), the initial mixtures consist of a continuous network of coarse particles with fines in interstitial voids. Strong frictional contacts between the coarse particles are probably rapidly re-established and the flows steadily decelerate. Some internal friction reduction appears to occur as α and the grain size ratio increases, possibly due to particle rolling and the lower roughness of internal shear surfaces. Segregation only occurs at large grain size ratio due to dynamical sieving with fines concentrated at the flow base. In contrast, at α above that for optimal packing, the initial mixtures consist of coarse particles embedded in a matrix of fines. Flow velocities and run-outs are similar to that of the monodisperse fine end-member, thus showing that the coarse particles are transported passively within the matrix whatever their amount and grain size are. These flows propagate at constant height and velocity as inviscid fluid gravity currents, thus suggesting negligible interparticle friction. We have determined a Froude number of 2.61 ± 0.08 consistent with the dam-break model for fluid flows, and with no significant variation as a function of α, the grain size ratio, and the initial bed expansion. Very little segregation occurs, which suggests low intensity particle interactions during flow propagation and that active fluidisation is not taking place. Strong frictional contacts are only re-established in the final stages of emplacement and stop the flow motion. We infer that fines-rich (i.e. matrix-supported) pyroclastic flows propagate as inviscid fluid gravity currents for most of their emplacement, and this is consistent with some field data. 相似文献
120.
WANG Min 《中国地球化学学报》2005,24(4):297-305
Systematic microthermometric measurements of fluid inclusions in the PGE-polymetallic deposits hosted in the Lower Cambrian black rock series in southern China were performed, and the results suggest: (1) there exist two types of fluid inclusions. TypeⅠis of NaCl-H2O system with low-medium salinity, and its homogenization temperatures (Th) and salinities are 106.9- 286.4℃ and ( 0.8- 21.8) wt%NaCl eq. respectively; TypeⅡ is of CaCl2-NaCl-H2O system with medium-high salinities, and its homogenization temperatures and salinities range from 120.1℃ to 269.6℃ and ( 11.4- 31.4) wt%NaCl eq., respectively. The typeⅡ fluid inclusions have been discovered for the first time in this kind of deposits; (2) two generations of ore-forming fluids were recognized. Characteristics of fluid inclusions in the PGE-polymetallic ores and carbonate-quartz stockworks in the underlying phosphorites are almost of no difference, they may represent ore-forming fluids at the main metallogenic stage. The peak value of homogenization temperature of those fluid inclusions is about 170℃, while their salinities possess a remarkable bimodal distribution pattern with two peak values of (27-31) wt%NaCl eq. and (4-6) wt%NaCl eq. On the contrary, fluid inclusions in the carbonate-quartz veins in the hanging wall may represent ore-forming fluids at the post-metallogenetic stage. The homogenization temperatures and the peak values of salinities are mostly 130-170℃ and (12-14) wt%NaCl eq., respectively; (3) nobel gas isotopic composition analyses in combination with the microthermometric measurements of fluid inclusions suggest that the ore-forming fluids at the main metallogenetic stage were probably derived from mixing of basinal hot brines with the CaCl2-NaCl-H2O system and seawater with the NaCl-H2O system; (4) in the Early Cambrian, the basinal hot brines were trapped in the Caledonian basins, which were distributed along the southern margin of the Yangtze Craton, and where giant thick sediments were accumulated, and expelled and migrated laterally along the strata because of the pressure caused by overlying sediments. The basinal hot brines absorbed Ni, Mo, V, PGE from the surrounding rocks and were transformed into ore-bearing hydrothermal fluids with the CaCl2-NaCl-H2O system and medium-high salinities, then ascended along faults and mixed with seawater of the NaCl-H2O system, and finally PGE-polymetallic deposits or occurrences were formed in the black rock series. 相似文献