有机农药六六六对胶州湾海域水质的影响Ⅰ.含量的年份变化

根据1979～1984年(缺少1980年)的胶州湾水域调查资料,分析有机农药六六六(HCH)在胶州湾水域的含量大小、年份变化和季节变化。研究结果表明:在1979～1984年(缺1980年)期间,在胶州湾水体中HCH的含量逐年都在减少。在1983年,中国禁止HCH的使用,在禁用后,水体中HCH的含量全部低于一类海水的水质标准。在禁用后,水体中HCH的含量很低,几乎没有季节变化。因此,中国禁止HCH的使用对环境的改善取得显著的成效。     

Geological control factors of micro oil distribution in tight reservoirs

Understanding the oil distribution characteristics in unconventional tight reservoirs is crucial for hydrocarbon evaluation and oil/gas extraction from such reservoirs. Previous studies on tight oil distribution characteristics are mostly concerned with the basin scale. Based on Lucaogou core samples, geochemical approaches including Soxhlet extraction, total organic carbon (TOC), and Rock-Eval are combined with reservoir physical approaches including mercury injection capillary pressure (MICP) and porosity-permeability analysis, to quantitatively evaluate oil distribution of tight reservoirs on micro scale. The emphasis is to identify the key geological control factors of micro oil distribution in such tight reservoirs. Dolomicrites and non-detrital mudstones have excellent hydrocarbon generation capacity while detritus-containing dolomites, siltstones, and silty mudstones have higher porosity and oil content, and coarser pore throat radius. Oil content is mainly controlled by porosity, pore throat radius, and hydrocarbon generation capacity. Porosity is positively correlated with oil content in almost all samples including various lithologies, indicating that it is a primary constraint for providing storage space. Pore throat radius is also an important factor, as oil migration is inhibited by the capillary pressure which must be overcome. If the reservoir rock with suitable porosity has no hydrocarbon generation capacity, pore throat radius will be decisive. As tight reservoirs are generally characterized by widely distributed nanoscale pore throats and high capillary pressure, hydrocarbon generation capacity plays an important role in reservoir rocks with suitable porosity and fine pore throats. Because such reservoir rocks cannot be charged completely. The positive correlation between hydrocarbon generation capacity and oil content in three types of high porosity lithologies (detritus-containing dolomites, siltstones, and silty mudstones) supports this assertion.     

Effects of Mudstone Particle Content on Shear Strength of a Crushed Sandstone–Mudstone Particle Mixture

The present study focuses on the shear strength, deformation, and particle crushing of sand which is mixed by crushed sandstone and mudstone particles. Two triaxial tests—one for unsaturated specimens and the other for saturated specimens—were performed, along with sieve analysis tests. Results obtained from the triaxial tests indicate that, with the increment of the mudstone particle content by weight, the angle of internal friction decreases, the cohesion increases and then decreases, and both the initial angle of shearing resistance at the atmospheric pressure and decremental angle increase and then decrease. Compared to the unsaturated specimens, the deviator stress or normalized deviator stress of the saturated specimens at the same axial stress may decrease due to the wetting action. Thus, the shear strength of the tested materials may be reduced by the wetting action. Results of sieve analysis tests indicate that the mixing of some mudstone particles into the sandstone particle mixture may reduce the amount of particle crushing, but the wetting action may increase the amount. The amount of the crushed particle may arrive at a minimum of 40% of mudstone particle content by weight.     

热带西太平洋海洋上层热含量的分布特征及其年际变化的分析

选用海面至20℃等温线所处深度水层的平均温度来表征研究海域海洋上层热含量。利用这一特征值，分析1986—1990年期间热带西太平洋边缘海域海洋上层热含量在秋季的分布特征和年际变化。结果表明：（1）热含量呈南高北低分布，在7．5－22．1°N范围内。以130°E断面为代表，热含量的平均递减率为0．179（℃／纬度）；（2）热含量的分布主要取决于环流系统，其等值线因受黑潮和棉兰老海流的影响而由纬向分布转向经向分布。某些区域因受暖涡及冷涡的影响而呈封闭状分布；（3）热含量的年际变化与E1Nino事件存在着很好的相关性，在E1Nino事件发生期间，热含量变得很低，高热含量（大于26．5℃）海区的分布范围明显缩小。     

Study of fluoride in polluted and unpolluted estuarine environments

Mindhola River estuary, which receives industrial waste containing high concentrations of fluoride, and Purna River estuary, which is free from fluoride contamination, have been investigated. While fluoride behaved conservatively in Purna River estuary, significant deviation from the theoretical dilution line (TDL) in the chlorinity range 0·5–8‰ was observed in Mindhola River estuary due to the externally added fluoride which largely remained in solution. The excess of fluroide over the theoretically calculated value was at a maximum around a chlorinity of 3‰. High natural fluoride content of the river waters resulted in F/Cl ratios exceeding 300 × 10⁻⁵ at low chlorinities. The ratio decreased rapidly with increasing chlorinity and the value near to that of seawater was observed at chlorinities above 14‰.     

黄、东海海域水团发育对底质沉积物分布的影响

通过对黄、东海海域底质沉积物中的细粒级粘土矿物组合特征和全粒级碳酸盐含量分析、对比上覆水团和悬浮体资料，探讨研究区水团发育消长对底质沉积物分布的影响作用。结果表明研究区可以划分为长江冲淡水影响的长江型物质沉积区；黄海水影响的黄河型物质沉积区和黑潮水以及东海次表层水影响的残留型物质沉积区。而水团发育消长可直接影响下伏底质的分布特征。黄河型物质沉积区与残留型物质沉积区的分界相应于黄海冷水向东南扩展与黑潮次中层混合水向陆架爬升互为消长的长期综合平衡位置，而黄海冷水向东南的扩展范围代表着黄河物质在陆架向东南扩展沉积的最大范围．     

低场核磁共振定量测定松散沉积物中含水量的方法

核磁共振通过测定体系中氢质子弛豫的T2谱来确定液态水的含量。采用低场核磁共振技术定量测定松散沉积物体系中的含水量,探讨了沉积物粒径、黏土矿物种类与含量、孔隙水盐度、温度及气体压力等因素对测试结果的影响。由于不同介质体系中孔隙水表面弛豫机制不同,导致低场核磁测定松散沉积物中的含水量偏小。引入校正系数Cm对水量测试值进行了修正,结果表明：沉积物及孔隙水介质本身特性对水量测试结果几乎无影响,相对误差<0.5%,测试精密度<0.20%;温度变化对测试结果影响较大且呈负相关,温度从25 ℃降至1.7 ℃,水量测试值增加了10.71%;压力变化对测试结果的影响与充注气体是否含氢密切相关,不含氢气体的压力变化对测试结果没有影响,而对于含氢气体如甲烷,水量测试结果随压力变化线性增加,甲烷增加到5.05 MPa时,测试结果增加了12.15%。因此,在采用该法测量甲烷水合物生成分解过程中沉积物孔隙水的变化时,必须考虑体系的温度、压力对测试结果的影响,恒温恒压条件下监测的含水量变化能够准确指示甲烷水合物生成分解的微观过程,可望在海洋天然气水合物生成分解微观动力学研究方面得到广泛应用。     

On the recent warming of the southeastern Bering Sea shelf

During the last decade, the southeastern Bering Sea shelf has undergone a warming of 3 °C that is closely associated with a marked decrease of sea ice over the area. This shift in the physical environment of the shelf can be attributed to a combination of mechanisms, including the presence over the eastern Bering Sea shelf of a relatively mild air mass during the winter, especially from 2000 to 2005; a shorter ice season caused by a later fall transition and/or an earlier spring transition; increased flow through Unimak Pass during winter, which introduces warm Gulf of Alaska water onto the southeastern shelf; and the feedback mechanism whereby warmer ocean temperatures during the summer delay the southward advection of sea ice during winter. While the relative importance of these four mechanisms is difficult to quantify, it is evident that for sea ice to form, cold arctic winds must cool the water column. Sea ice is then formed in the polynyas during periods of cold north winds, and this ice is advected southward over the eastern shelf. The other three mechanisms can modify ice formation and melt, and hence its extent. In combination, these four mechanisms have served to temporally and spatially limit ice during the 5-year period (2001–2005). Warming of the eastern Bering Sea shelf could have profound influences on the ecosystem of the Bering Sea—from modification of the timing of the spring phytoplankton bloom to the northward advance of subarctic species and the northward retreat of arctic species.     

Seasonal Changes in Soluble Carbohydrates, Starch, and Energy Content in Mediterranean Seagrasses

Abstract. In all scagrass species investigated, rhizomes were the main storage organs for soluble carbohydrate reserves, and the highest levels were found in Cymodocea nodosa (U cria ) A scherson . Sucrose was the primary soluble carbohydrate identified in Posidonia oceanica (L.) D elile , and Zostera noltii H ornem . This disaccharide was dominant in Cymodocea nodosa roots, as well as in its rhizome in winter. Myo-inositol was the main cyclitol in Zostera noltii. In Cymodocea nodosa leaves 1-chiro-inositol was the main sugar component; it was also present to a lesser extent in the roots and rhizomes. The amounts of glucose and fructose were correlated with growth to a certain extent in all species. Higher amounts of starch were stored in the rhizomes of Posidonia oceanica and Zostera noltii. The energy content of Mediterranean scagrasses was significantly higher than in tropical species. No distinct seasonal trend in energy content could be observed.     

菲律宾海热含量分布及其变化的初步探讨

本文利用1986年及1987年秋季在菲律宾以东海域进行的CTD观测资料,分析了该海域上层海水热含量分布及变化,得出,热含量由南向北随纬度逐渐增大,这主要是北赤道流引起的等温线自南向北下倾造成的,另外也与南部和北部的冷涡和暖涡有关。本文认为,两年里热含量的差异可能与1986年生成的El Nin有关。另外,北太平洋赤道流体积输送量的变化与菲律宾海热含量的变化也有一定的联系。