Genesis and distribution of mineral waters as a consequence of recent lithospheric dynamics: the Rhenish Massif,Central Europe

Three major, interdependent processes control the genesis and distribution of mineral and thermal waters in the Rhenish Massif, Central Europe: (a) Magmatic processes in the upper mantle provide most of the CO₂ to produce bicarbonate waters in shallow aquifers. (b) Extension of the brittle upper crust enables the ascent of sodium chloride waters. (c) Uplift and erosion shape the massif's relief, which determines the extent of flow systems and the distribution of thermal springs. The chemistry of mineral waters further depends on the aquifers' mineral composition. A comprehensive set of hydrological, chemical, tectonic and geophysical data on the Rhenish Massif has been compiled. It was used to classify the mineral waters and to map the spatial distribution of water properties. The composition of cuttings from several representative wells producing different water types shows that the hydrothermal alteration of the aquifer rocks consists mainly of kaolinization of chlorite and dissolution of feldspar. Numerical transport simulations favour two modes of groundwater flow: topography-driven flow and the pressure-driven ascent of basement brines along active faults. Thermal convection is less important.     

内蒙大水清金矿带交代作用及其与金矿化关系

大水清金矿带是华北克拉通中有代表性的改造型绿岩金矿之一。它产于前东武纪绿岩地体中安家营子石英二长岩体内外接触带附近的剪切带中。金矿化交代主要受后阶段张性脆裂控制，而剪切带早阶段韧性剪切作用无明显矿化交代，后者主要为成矿交代提供有益的江游交代构造环，境即成矿交代蚀变作用和剪切带同步的两阶段演化模式。大水清金矿带的交代作用有四个阶段：即用长石化阶段，绿泥石化阶段，黄铁绢英岩化和石英－硫化物阶段以及石英－碳酸盐化阶段。第三阶段由五个亚阶段组成：即黄铁绢英岩化和强硅化－强黄铁矿化，石英－多金属硫化物交代，石英－贫扶矿充填交代和细粒黄铁矿充填交代。其中前四个亚阶段是本区金的主要成矿期．当韧性剪切转化为张性脆裂时产生的骤然扩容和伴随发生的交代体系转变为富硅体系的钾交代和石英－硫化物交代是金矿成矿的关键。本文还研究和探讨了该金矿成矿交代流体的性质及交代的物理化学环境。     

蚀变带元素地球化学成矿预测法──以金龙山微细浸染型金矿为例

金矿化作用伴围岩蚀变，且多受断裂控制，反映在地球化学上出现某些元素的异常。在已发现一害矿化体并掌握一般控制矿特征的地区，利用已有工程在蚀变带内连续捡块采样，分析有关批示元素，总结有关的地球化学指标，建立地球化学预测模式，对已知矿体及外围异常进行了地球化学评价。     

广东莲花山斑岩型钨-金矿床蚀变矿化特征及分带模式

莲花山斑岩型钨－金矿床蚀变类型可以分作钾化、云英岩化、绢云母化、绿泥石化和青盘岩化。矿化表现为黑钨矿化、白钨矿－硫化物矿化、多金属硫化物矿化及黄铁矿化。蚀变在水平和垂向上具有分带性。由内向外由钾化向云英岩化、叠加蚀变带、绿泥石化＋绢云母化、青盘岩化转化。由浅向深，钾化增强，云英岩化减弱，被叠加蚀变带和绿泥石化及绢云母化所代替。矿化由内向外表现为由黑钨矿化向白钨矿化、多金属硫化物矿化、黄铁矿化转变，由浅向深由钨矿化转变为金矿化及多金属硫化物矿化。与典型斑岩型矿床蚀变分带对比，莲花山斑岩型矿床不同原岩类型蚀变特征变化较大，矿化则表现出富钨、金贫铜及钨金共同产出的特征。     

The Activity of Major Faults and the Hydrothermal Alteration Zone at Tianchi Volcano of Changbaishan

It is found by field investigation that the near horizontal top surface of the brown or brick-red hydrothermai alteration zone varies obviously in elevation at different sections of the same layer on the caldera‘s inner wall of Tianchi, with that at the north section near the Tianwen Peak about 110 m higher than that at the south near the Jiangjun Peak in Korea. The top surface of the hydrothermai alteration zone can be taken as key horizon to tectonic movement. The difference indicates that the total uplift height of the NW wall of the Liudaogou-Tianchi-Jingfengshan fault, the principal fault trending NE at Tianchi, is bigger than that of the SE wall ever since the occurrence of hydrothermal alteration. This also explains why the topography in the northwest side of Tianchi is steeper and with more developed river system than in the southeast. The uplifting of the northeastern wall is bigger than that of the southwest along the principal NW-trend fault, namely, the Baishanzhen-Tianchi-Jince fault. It is observed from characters of hydrothermal alteration and the palaeoresiduum, that the recent vertical movement rate along the principal NE-trend fault is larger than that of the principal NW-trend fault. The two faults intersect at Tianchi, dividing the volcano into 4 blocks, with the uplift magnitudes decreasing successively in the order of the north, the west, the east and the south block. The biggest uplift of the north block corresponds well to the shallow magma batch in the north of Tianchi observed by DSS and telluric electromagnetic sounding, and etc. and they may be related with the causes.     

南秦岭夏家店卡林型金矿床构造特征与成矿关系

从地质背景、矿床地质、控矿构造分析了夏家店金矿床特征及其形成过程及成矿机理；矿床产于南秦岭陡岭古隆起边缘寒武系-震旦系碳-泥-硅质板岩及白云岩中；控矿构造具有二次韧性剪切变形、二次构造角砾岩化及二次脉体矿化的特征，显示出式样多种、性质多样、形式多变、活动期次与阶段多次叠加的特点；具体阐述了各构造作用阶段与矿化蚀变之间的关系，建立了地层建造-剪切与张裂构造-热液渗流的成矿系统。属于沉积岩系、构造、热液活动3种地质作用叠加改造的卡林型金矿床。     

新疆双峰山浅成低温热液金矿床特征与成矿机制

双峰山矿床位于新疆东天山北部西伯利亚板块陆缘晚古生代岛弧南部边缘，靠近克拉麦里板块缝合带．该矿区早石炭世浅海相玄武一安山质熔浆喷溢转为陆相流纹质熔浆喷发初期，火山热泉沿NW-NWW向线形管道(F2)形成以低Au品位硅质岩为中心的蚀变矿物晕(带)；火山间隙性隐爆，潜火山热液于硅质岩裂隙间发育微细石英(冰长石)网脉，构成矿体．这两个成矿阶段同源同位的蚀变矿物晕(带)套叠，显示双峰山矿床蚀变分带与成矿模式，从上至下为隐爆硅质角砾岩化带、低Au品位硅质岩化带、石英(冰长石)网脉带(矿体)、黄铁矿蒙脱石化带和青磐岩化带．铅、硫同位素和稀土元素等研究表明，该矿床成矿流体与晚古生代岛弧早石炭世流纹质熔浆的陆相喷发相联系：火山热泉循环形成蚀变晕阶段加入大气降水，潜火山热液成矿阶段发育的低温微细石英网脉含冰长石和绢云母，它是一处晚古生代火山地区冰长石-绢云母型浅成低温热液金矿床。     

高倍稀释熔融制样X射线荧光光谱测定钨砂和铬铁矿中主含量

用X射线荧光光谱测定钨砂中WO3和铬铁矿中Cr2O3,通过高倍稀释熔融玻璃片制样法,采用高纯WO3或Cr2O3作单一标准样测量X射线荧光强度计数,然后同未知样品测量所得X射线荧光强度计数相比,即可计算出WO3和Cr2O3的测量值.方法用于钨砂矿和铬铁矿中WO3和Cr2O3的测定,结果与标准值相符.     

内蒙古巴彦塔拉盆地砂岩型铀矿化的蚀变特征

巴彦塔拉盆地砂岩型铀矿床产于下白垩统赛汉塔拉组下段辫状河流相砂岩中。本文通过对含矿主岩沉积特征、矿化和矿床蚀变特征的分析研究 ,认为早期为潜水氧化蚀变成矿 ;晚期为层间氧化 油气还原蚀变成矿 ,即来自蚀源区和天窗补给的含铀、含氧地下水遇沿断裂 (F2 1)上升的含H2 S的油气还原叠加改造成矿     

Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献