海底热液沉积物中流体包裹体的研究进展

最近几个新兴起的海底热液沉积物中流体包裹体的研究可以解决许多利用常规矿物学和地球化学方法无法解决的重要科学问题,本文总结了该领域研究工作的进展,探讨了技术手段或方法上的发展及局限性,提出对热液沉积物中透明矿物的大范围显微测温对比分析和非透明矿物分温度段释放包裹体气候相结合,从而获取不同类型和不同成矿阶段包裹体物化指标及成分特征,进而研究热液循环机制及成矿作用过程的思路,对热液沉积物中流体包裹体研究     

柴达木盆地北缘冷湖七号构造油气成藏过程与模式

本文在对冷湖七号油气成藏条件综合分析的基础上,依据构造发育史与烃源岩生、排烃史,结合流体包裹体均一温度,分析了冷湖七号构造油气藏形成期次和过程,总结了东、西2个构造高点的油气成藏模式。研究结果表明:①冷七1井N12层包裹体主要为含烃盐水包裹体和气态烃有机包裹体,其均一温度明显分为60~70℃和110~130℃两个峰值区,对应地质时间分别为N21—N22时期和N2末—现今。结合源岩生、排烃史和构造演化史分析表明N12—N22时期为冷湖七号油气成藏的主要时期;②冷湖七号东高点N21气藏形成机理与模式为:断控同生隆起—单源供烃—不整合、断裂输导—浮力驱动—次生型断裂遮挡油气成藏模式;西高点E3油藏形成机理与模式为:同生隆起—双源供烃—不整合、断裂输导—浮力驱动—残留型原生油藏成藏模式。     

山东蓬莱地区侯格庄金矿床流体包裹体特征

侯格庄金矿床位于胶东栖(霞)-蓬(莱)金成矿带大柳行金矿田东南部。该文采用包裹体显微测温方法对金矿石中石英矿物内残留的流体包裹体进行研究,总结了金矿石石英矿物中的流体包裹体特征,并对该矿床成矿流体来源、矿床成因进行了研究。研究表明,该矿床石英矿物中流体包裹体以纯液包裹体为主,次为H_2O-CO_2气液两相包裹体及H_2O-CO_2三相包裹体,未见含子矿物包裹体。均一温度在109~396℃,盐度在2.9~22.44wt%NaCl,密度在0.64~1.06g/cm~3之间,估算成矿压力为128~340MPa,成矿深度约4.4~11.6km。该矿床至少经历了2个矿化期次,成矿流体为中低温、低盐度、低密度流体,流体来源于天水与岩浆水的混合产物,属中低温、中浅成热液矿床。     

Improved understanding of petroleum migration history in the Hongche fault zone,northwestern Junggar Basin (northwest China): Constrained by vein-calcite fluid inclusions and trace elements

Calcite veins and cements occur widely in Carboniferous and Permian reservoirs of the Hongche fault zone, northwestern Junggar Basin in northwest China. The calcites were investigated by fluid inclusion and trace-element analyses, providing an improved understanding of the petroleum migration history. It is indicated that the Hongche fault behaved as a migration pathway before the Early Cretaceous, allowing two oil charges to migrate into the hanging-wall, fault-core and footwall reservoirs across the fault. Since the Late Cretaceous, the Hongche fault has been sealed. As a consequence, meteoric water flowed down only into the hanging-wall and fault-core reservoirs. The meteoric-water incursion is likely an important cause for degradation of reservoir oils. In contrast, the footwall reservoirs received gas charge (the third hydrocarbon event) following the Late Cretaceous. This helps explain the distribution of petroleum across the fault. This study provides an example of how a fault may evolve as pathway and seal over time, and how reservoir diagenetic minerals can provide clues to complex petroleum migration histories.     

Petroleum accumulation and leakage in a deeply buried carbonate reservoir,Níspero field (Mexico)

The filling history of the Níspero deeply buried Lower Cretaceous carbonate reservoir (below 4000 m) from the south part of Gulf of Mexico was studied using a combination of data from petrography, stable isotopes and fluid inclusions and compared with a one-dimensional burial model to derive timing.     

油气包裹体在油气地质研究中的应用--概念、分类、形成机制及研究意义

油气包裹体己成为油气成藏研究的有力工具,在划分油气运移充注期次、确定油气藏的形成时间、反映油气的成熟度及来源等方面均有重要的应用价值。近年来,利用油气包裹体及其共生的盐水溶液包裹体估算油气藏形成时的pVT条件是油气包裹体研究中的一个新热点,它为更准确地计算油气藏形成的温度一压力条件提供了一种独立的、更准确的技术手段。研究表明,包裹体岩相学和流体体系的热力学研究仍将是今后的发展重点。油气包裹体的pVT模拟技术尚处于初始阶段,两种软件（VTFlinc和FIT）的准确性和精确性虽有待进一步提高,但已经成为今后一个重要的发展方向。     

油气包裹体的显微红外光谱测试技术及应用

单一油气包裹体的成分一直是地质学家关注的焦点,它能为油气成藏研究提供最直接的证据。显微红外光谱技术可以测定单个油气包裹体的成分、分子结构和其中油气包裹体的成熟度。本文应用显微红外光谱技术、包裹体的鉴定和均一温度测定技术,分析了大庆探区海拉尔盆地乌27井、巴16井、希3井等样品的包裹体。研究表明,乌27井有过两期成藏,并以第二期为主;巴16井也有过两期主要成藏,且第二期具混源的特点;希3井只有一次主要成藏期。同时利用红外光谱的CH2/CH3值、Xinc、Xstd划分了三口井的油气成藏期次,结果与镜下鉴定结论相一致,并确定了其中油气包裹体的成熟度。本文还探讨了显微-红外光谱测试单一油气包裹体的发展方向。     

Silurian and Devonian systems

The Ediacara mineral field is situated 30 km W of Beltana on the western margins of the Flinders Ranges, South Australia, and consists of silver‐lead and copper deposits in lower Cambrian carbonate rocks that contain anomalous base‐metal contents throughout the Adelaide Geosyncline. The lower Cambrian rocks, which consist of the basal Parachilna Formation and overlying Ajax Limestone, rest disconformably on the Precambrian, and at Ediacara occupy a shallow N‐S elongate syncline near the hinge zone of the Adelaide Geosyncline. The main primary ore minerals of the silver‐lead mineralization are galena and pyrite, with very minor chalcopyrite and sphalerite, and rare tetrahedrite and pearceite. The gangue consists mainly of silica (both chalcedony and quartz), with minor dolomite and rare barite. The mineralization is stratabound and occurs in conformable zones, the lowest of which commences about 30–50 m above the base of the Cambrian sequence. The host to the silver‐lead mineralization, the Ajax Limestone, can be subdivided into three units which represent a set of lithologies, structures and organic traces indicative of a shallow near‐shore carbonate environment. The silver‐lead mineralization is mainly present in sandy and laminated dolomites which were deposited in an environment ranging from sub‐tidal to bar and channel and tidal flat, respectively. Four types of mineralization have been recognized; disseminated sulphides of syngenetic and/or diagenetic origin and epigenetic concentrations along stylolites, in veins and as breccia fillings. Post‐depositional solution activity has affected a large proportion of the carbonate sequence. The effects of this activity range from stylolites through stylobreccias to solution collapse breccias. The epigenetic concentrations of mineralizations have apparently been formed by the remobilization of the disseminated sulphides during solution activity. The ore and gangue minerals of the epigenetic mineralization display both euhedral forms and distinct colloform banding, and framboidal textures have also been observed in both pyrite and galena. There is evidence of repeated episodic precipitation and no simple paragenetic sequence can be recognized. Fluid inclusions in silica and dolomite associated with the epigenetic mineralization have homogenization temperatures of 159 to 199°C and freezing temperatures that indicate the fluids to be saline brines containing NaCl with CaCl₂ and/or MgCl₂. Sulphur isotope analyses show a range of 8³⁴S values from ‐12.5 to +8.6 per mil, with no evidence of significant differences between the four types of mineralization. The data suggest deposition of the disseminated sulphides as a result of biological reduction of seawater sulphate in a system partially open with respect to sulphate supply. Subsequent remobilization of sulphides apparently involved little or no sulphur isotope fractionation. The Ediacara silver‐lead deposits have many features in common with Mississippi Valley‐type lead‐zinc deposits and appear to have similarities in terms of genesis, in that the epigenetic mineralization has been formed as a result of post‐depositional solution activity during diagenesis in a sedimentary basin. The scale of transport of the metals deposited as the epigenetic mineralization at Ediacara appears, however, to have been very much less than that of the metals in other Mississippi Valley‐type deposits.     

Element mobility during continental collision: insights from polymineralic metamorphic vein within UHP eclogite in the Dabie orogen

Metamorphic dehydration and partial melting are two important processes during continental collision. They have significant bearing on element transport at the slab interface under subduction‐zone P–T conditions. Petrological and geochemical insights into the two processes are provided by a comprehensive study of leucocratic veins in ultrahigh‐pressure (UHP) metamorphic rocks. This is exemplified by this study of a polymineralic vein within phengite‐bearing UHP eclogite in the Dabie orogen. The vein is primarily composed of quartz, kyanite, epidote and phengite, with minor accessory minerals such as garnet, rutile and zircon. Primary multiphase solid inclusions occur in garnet and epidote from the both vein and host eclogite. They are composed of quartz ± K‐feldspar ± plagioclase ± K‐bearing glass and exhibit irregular to negative crystal shapes that are surrounded by weak radial cracks. This suggests their precipitation from solute‐rich metamorphic fluid/melt that involved the reaction of phengite breakdown. Zircon U–Pb dating for the vein gave two groups of concordant ages at 217 ± 2 and 210 ± 2 Ma, indicating two episodes of zircon growth in the Late Triassic. The same minerals from the two rocks give consistent δ¹⁸O and δD values, suggesting that the vein‐forming fluid was directly derived from the host UHP eclogite. The vein is much richer in phengite and epidote than the host eclogite, suggesting that the fluid is associated with remarkable concentration of such water‐soluble elements as LILE and LREE migration. Garnet and rutile in the vein exhibit much higher contents of HREE (2.2–5.7 times) and Nb–Ta (1.8–2.0 times) than those in the eclogite, indicating that these normally water‐insoluble elements became mobile and then were sunken in the vein minerals. Thus, the vein‐forming agent would be primarily composed of the UHP aqueous fluid with minor amounts of the hydrous melt, which may even become a supercritical fluid to have a capacity to transport not only LILE and LREE but also HREE and HFSE at subduction‐zone metamorphic conditions. Taken together, significant amounts of trace elements were transported by the vein‐forming fluid due to the phengite breakdown inside the UHP eclogite during exhumation of the deeply subducted continental crust.     

利用U—1000型激光拉曼探针测定流体包裹体气体成分的研究

本文利用U－1000型激光拉曼探针成功地测量出单个流体包裹体中H2S、CH4、CO2气体成分，并讨论了包裹体中这些气体的拉曼谱峰位移与包裹体内压的关系，分析了影响激光拉曼探针定量测定包裹体气相成分的取面积和拉曼定量因子因素。