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101.
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103.
中国东部幔源气体同位素地球化学 总被引:11,自引:0,他引:11
中国东部地幔岩包体及其单矿物中发育有大量的流体包裹体,采用阶段加热真空热爆的 方法脱出幔源包裹体中的气体,测试了气体的碳、氧、氦、氮等同位素组成。CO2的σ13℃普遍较低, 主峰值为(-18~-22)×10-3 ,多数样品在高温下的 σ13℃普遍小于低温下的对应值。氧同位素变 化也很大,从-3.4×10-3至25.5×10-3(SMOW),并呈现多峰的特征。σ18O与σ1C3具有很好的相 关性,可能受控于同种分馏机制。C、O同位素组成特征表明,中国东部大陆地幔具有很大的化学不 均一性,可能是由地幔碳的多样性、源区的不均一性或地幔交代作用所致。氧同位素的变化可能是 结晶作用、去气作用或地壳物质混染所至。4He含量变化范围为(0.24~25.00)×10-8,3He/4He变 化范围为(0.46~12.80)×10-6,40Ar含量从0.97×10-6到34.18×10-6,40Ar/36Ar变化范围为 250.58~1202。3He/4He的变化反映了亏损地幔和富集地幔的存在。不同地区40Ar/36Ar的巨大差 异显示了地幔脱气程度的不同,也说明在地幔演化中Ar、He同位素地球化学行为的差异。 相似文献
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105.
四川牦牛坪稀土矿床矿物流体包裹体研究 总被引:18,自引:0,他引:18
对矿物流体包裹体进行分析的结果表明,牦牛坪稀土矿床的矿物中存在4种类型包裹体:(1)液-所耵;(2)液-气-固相;(3)纯气相;(4)固相,矿物包裹体显微测温结果显示牦牛坪矿床成矿温度从423℃至122℃;成矿流体的盐度ω(NaCl)为11.46%-14.36%质量分数,包裹体的成分分析结果显示流体中富含CO2和其他挥发性组分,并富含大量的不同成分的矿物雏晶,根据矿床地质特征和矿物包裹体的研究结果,作者认为本矿床的成矿作用是由碳酸岩岩浆气液流体的沸腾、充填和交代过程而实现的。 相似文献
106.
Fault-controlled dolomitization at Swan Hills Simonette oil field (Devonian), deep basin west-central Alberta, Canada 总被引:6,自引:0,他引:6
The partly dolomitized Swan Hills Formation (Middle‐Upper Devonian) in the Simonette oil field of west‐central Alberta underwent a complex diagenetic history, which occurred in environments ranging from near surface to deep (>2500 m) burial. Five petrographically and geochemically distinct dolomites that include both cementing and replacive varieties post‐date stylolites in limestones (depths >500 m). These include early planar varieties and later saddle dolomites. Fluid inclusion data from saddle dolomite cements (Th=137–190 °C) suggest that some precipitated at burial temperatures higher than the temperatures indicated by reflectance data (Tpeak=160 °C). Thus, at least some dolomitizing fluids were ‘hydrothermal’. Fluorescence microscopy identified three populations of primary hydrocarbon‐bearing fluid inclusions and confirms that saddle dolomitization overlapped with Upper Cretaceous oil migration. The source of early dolomitizing fluids probably was Devonian or Mississippian seawater that was mixed with a more 87Sr‐rich fluid. Fabric‐destructive and fabric‐preserving dolostones are over 35 m thick in the Swan Hills buildup and basal platform adjacent to faults, thinning to less than 10 cm thick in the buildup between 5 and 8 km away from the faults. This ‘plume‐like’ geometry suggests that early and late dolomitization events were fault controlled. Late diagenetic fluids were, in part, derived from the crystalline basement or Palaeozoic siliciclastic aquifers, based on 87Sr/86Sr values up to 0·7370 from saddle dolomite, calcite and sphalerite cements, and 206Pb/204Pb of 22·86 from galena samples. Flow of dolomitizing and mineralizing fluids occurred during burial greater than 500 m, both vertically along reactivated faults and laterally in the buildup along units that retained primary and/or secondary porosity. 相似文献
107.
Abstract: The Dajing Cu–Sn–Ag–Pb–Zn ore deposit, Inner Mongolia of China, is a fissure‐filling hydrothermal ore deposit that occurs within the Upper Permian Linxi group. No magmatic pluton and volcanic rocks outcrop on the surface of the deposit. Most of ore veins show clear‐cut boundary with country rocks. Wallrock alterations that include silicification, carbonation, chlori–tization, and sericitization are generally weak and occur in the close vicinity of ore veins. Mineralization is divided into three stages: (1) cassiterite–arsenopyrite–quartz stage, (2) sulfide stage, and (3) Pb–Zn–Ag–carbonate stage. These mineralization stages have distinct ranges of homogenization temperatures, 290–350C for Stage 1, 260–320C for Stage 2, and 150–250C for Stage 3. However, salinities for Stages 1, 2, and 3 overlap and range between 2.2 and 10.4 wt % NaCl equivalent. The dD values relative to V‐SMOW of inclusion water from quartz are lower than –88% and centered at –100 to –130%. The δ34S values relative to CDT of sulfide ore minerals and δ13C values relative to PDB of carbonate gangue minerals, vary from –0.3 to +2.6%, and from –7.0 to –2.9%, respectively. Integrated isotopic data point to two major contributions to the mineralizing fluid that include a dominant meteoric‐derived water and the other from hypogene magma for sulfur and carbon species. Analyses of inclusion gas and liquid compositions are performed. The H2O and CO2 are the two most abundant gaseous components, whereas SO42‐ and Cl‐, and Na+, Ca2+, and K+ are the major anions and cations, respectively. A linear trend is shown on the gaseous H2O versus CO2 plot. Phase separation is excluded as cause for the trend on the basis of isotope data and fluid inclusion microthermometry. In addition, a weak wallrock alteration does not support fluid‐rock interaction as an efficient mechanism. Hence, the linear H2O–CO2 trend is interpreted in terms of absorption or dilution of CO2–dominant magmatic vapor by meteoric‐derived water. Cooling effects resulting from dilution may have caused precipitation of ore minerals. Major and trace element compositions of regional granites show a high‐K calc–alkaline characteristics and an arc–affinity. Lead isotopic compositions of galena samples from the Dajing deposit exhibit elevated U/Pb and Th/Pb ratios. These characteristics indicate a common source of supra subduction zone mantle wedge for regional granites and metals from the Dajing deposit. 相似文献
108.
Abstract: Synchrotron X-ray fluorescence analyses on individual hypersaline fluid inclusions were tested to using synchrotron source at Tsukuba (KEK), Japan. The XRF instrumentation at KEK meets the purpose of fluid inclusion analysis, nondestructive, multi–element, ppm detection limits, with micro spatial resolution. In practice, however, the quantitative chemical analysis of fluid inclusion requires further considerable data accumulation. Semi-quantitative distribution of elements (mass number > 25) in single fluid inclusion was obtained. 相似文献
109.
Victor B. MAGLAMBAYAN Daizo ISHIYAMA Toshio MIZUTA Osamu MATSUBAYA Yohei ISHIKAWA 《Resource Geology》2001,51(2):107-116
Abstract: The disseminated Au‐Ag telluride Bulawan deposit, Negros island, Philippines, is hosted by dacite porphyry breccia pipes which formed in a Middle Miocene dacite porphyry stock. Electrum and Au‐Ag tellurides occur mostly as grains intergrown with or filling voids between sphalerite, pyrite, chalcopyrite, galena and tennantite. Calcite, quartz and rare dolomite are the principal gangue minerals. Four types of alteration were recognized in the deposit, namely; propylitic, K‐feldspar‐sericitic, sericitic and carbonate alteration. Carbonate alteration is correlatable to the gold deposition stage and occurs mostly along fault zones. The δ18O and δ13C compositions of calcite and dolomite in propylite zone and ore‐stage dacite porphyry breccia were determined. The δ18O values of calcite in propylitized andesite range from +12.2 to +14.7%, and their δ13C values range from ‐6.1 to ‐1.0%. The δ18O values of calcite and dolomite in sericite‐ and carbonate‐altered, mineralized dacite porphyry breccia and dacite porphyry rocks range from +15.1 to +23.1%, and the δ13C values of calcite and dolomite range from ‐3.9 to +0.9%. The δ18O and δ13C values of the hydrothermal fluids were estimated from inferred temperatures of formation on the basis of fluid inclusion microthermometry. The δ18O values of hydrothermal fluid for the propylitic alteration were calculated to be +8.5 ‐ +9.5%, assuming 375°C. On the other hand, the δ18O values of ore solutions for base metal and Au mineralization were computed to be +13.6 ‐ +14.6%, assuming 270°C. The hydrothermal fluids that formed the Bulawan deposit are dilute and 18O‐enriched fluids which reacted with 18O‐ and 13C‐rich wallrocks such as limestone. 相似文献
110.
北京大庄科花岗杂岩普遍含有微粒—细粒暗色包体,其中石英闪长岩和石英二长岩含包体较多,二长花岗岩含少量包体,淡色花岗岩和闪长岩含包体甚少。在含包体较多的岩体内,包体在岩体中部的分布量较多。计算结果表明,包体越小沉浮半径愈大、参数F值愈小的岩体,含包体愈多;岩体内岩浆上升速度大、包体下沉速度小以及F值小的部位,包体滞留量大。各岩体包体分布的多少,是由包体在寄主岩浆内的扩散系数、混合程度、岩浆携带力和基性岩浆混入量等因素综合决定的。 相似文献