Geochemistry of S-type granitic rocks from the reversely zoned Castelo Branco pluton (central Portugal)

The zoned pluton from Castelo Branco consists of Variscan peraluminous S-type granitic rocks. A muscovite>biotite granite in the pluton's core is surrounded successively by biotite>muscovite granodiorite, porphyritic biotite>muscovite granodiorite grading to biotite=muscovite granite, and finally by muscovite>biotite granite. ID-TIMS U–Pb ages for zircon and monazite indicate that all phases of the pluton formed at 310 ± 1 Ma. Whole-rock analyses show slight variation in ⁸⁷Sr/⁸⁶Sr_310 Ma between 0.708 and 0.712, Nd_310 Ma values between − 1 and − 4 and δ¹⁸O values between 12.2 and 13.6. These geological, mineralogical, geochemical and isotopic data indicate a crustal origin of the suite, probably from partial melting of heterogeneous Early Paleozoic pelitic country rock. In detail there is evidence for derivation from different sources, but also fractional crystallization linking some of internal plutonic phases. Least-squares analysis of major elements and modelling of trace elements indicate that the porphyritic granodiorite and biotite=muscovite granite were derived from the granodiorite magma by fractional crystallization of plagioclase, quartz, biotite and ilmenite. By contrast variation diagrams of major and trace elements in biotite and muscovite, the behaviours of Ba in microcline and whole-rock δ¹⁸O, the REE patterns of rocks and isotopic data indicate that both muscovite-dominant granites were probably originated by two distinct pulses of granite magma.     

湖北徐家山锑矿床流体包裹体特征及其意义

文章利用激光拉曼光谱和显微测温学方法,对湖北徐家山锑矿床成矿期的石英、重晶石和方解石中的流体包裹体进行了研究。研究表明,这些矿物中的流体包裹体主要有纯液体包裹体和液体包裹体(气相 液相)2类,其液体包裹体的气相成分为H2O±CO2±N2;石英、重晶石和方解石的均一温度分别为134~258℃、154~259℃和145~230℃,主要集中于150~200℃;流体的盐度w(NaCleq)和密度分别集中于3%~6%和0.90~0.96g/cm3。流体包裹体资料揭示出该矿床为典型的中低温热液锑矿床,其成矿流体为中低温、低盐度、中等密度热液。结合H、O、Sr、Pb同位素等研究结果,进一步推断该成矿热液主要是经深部循环演化的大气降水。     

新疆阿尔泰蒙库铁矿床的成矿流体及成矿作用

蒙库大型铁矿床赋存于上志留统—下泥盆统康布铁堡组变质火山-沉积岩系中,容矿岩石为石榴子石矽卡岩、变粒岩、浅粒岩和大理岩。矿体总体顺层分布,空间上与矽卡岩密切相关。研究表明,矽卡岩期石榴子石以发育玻璃质熔融包裹体、流体熔融包裹体和流体包裹体为特征,晚期矽卡岩阶段矿物中发育液相包裹体,变质期矿物中主要发育液相包裹体和含子矿物包裹体。矽卡岩期熔融包裹体的均一温度为1100℃,早期矽卡岩阶段流体包裹体均一温度变化于193～499℃,在450℃、350℃和230℃出现峰值。中期矽卡岩阶段均一温度变化于236～550℃,峰值为350℃。区域变质期均一温度介于132～513℃,在350℃、230℃和190℃出现峰值。流体包裹体的盐度w(NaCleq)介于1.23%～60.31%,流体密度变化于0.60～1.16g/cm3。石榴子石、石英和方解石的δ18OSMOW变化于0.2‰～8.4‰,δ18OH2O介于-5.1‰～5.33‰,δD为-127‰～-81‰,表明矽卡岩期成矿流体主要是岩浆水,混合少量大气降水;变质期流体主要为大气降水,为混合变质水。方解石δ13CPDB变化于-6.1‰～-2.3‰,表明流体中碳来自深部或地幔。成矿时代为早泥盆世早期(略晚于404～400Ma),成矿作用与矽卡岩的退化变质作用有关。     

豫西前河构造蚀变岩型金矿成矿过程中的流体-岩石反应

前河金矿区位于华北地台南缘,赋存在中元古界熊耳群安山岩和英安岩中,矿体受断裂破碎带控制。含矿热液在迁移过程中与围岩发生了广泛的流体-岩石反应而引起热液蚀变。本区石英中有4种类型的流体包裹体,均一温度范围为145～331℃,其中含CO2包裹体的完全均一温度主要分布在中-高温区。成矿流体的密度和压力变化范围分别是0.68～0.94g/cm3和(367.01～896.55)×105Pa。金大量沉淀成矿时的流体特征为:温度213～260℃、密度0.80～0.89g/cm3和压力(502.86～710.57)×105Pa。流体相为SO42->Na >Cl->K 型,CO2/H2O比值及N2、H2S、Ar、C2H6等挥发分的含量明显增高,f(CO2)、f(H2S)、f(CH4)和Eh值增大;f(O2)、f(H2O)和pH值减小。在青磐岩化安山岩的基础上发生的流体-岩石反应是造成本矿床金沉淀成矿的最主要原因。     

Origin and mechanisms of K–Si-metasomatism of ca. 3.4–3.3 Ga volcaniclastic deposits and implications for Archean seawater evolution: Examples from cherts of Kittys Gap (Pilbara craton, Australia) and Msauli (Barberton Greenstone Belt, South Africa)

The effects of K–Si-metasomatism during the formation of Early Archean replacement cherts have been quantified in this study by the investigation of two well-known stratigraphic sections: the Msauli chert (MC, Barberton greenstone belt, South Africa) and the Kittys Gap chert (KGC, Pilbara craton, Western Australia). The KGCs have a dacitic precursor similar to Duffer Formation dacites (Pilbara craton), while the MCs are derived from Al-depleted komatiites similar to those from the Weltevreden Formation (Barberton greenstone belt). Mass balance calculations reveal that the volcaniclastic deposits had initial porosities of up to 85 vol.% for the KGC and of 65 vol.% for the MC. Secondary porosities (27 vol.%: MC, 8 vol.%: KGC) produced during K-metasomatism are proportional to the dissolution of Fe, Ca, Mg-rich glass and precursor minerals. Komatiites have a higher chemical exchange potential than dacites, each gram releasing 1.2 mmol Fe²⁺, 2.8 mmol Mg²⁺, 1.4 mmol Ca²⁺ and 1.1 mmol Na⁺ to seawater, together with 4.4 mmol O²⁻. K-metasomatism of 1 g of komatiite further implies an uptake of 0.67 mmol of K⁺ and 2.7 mmol of H⁺. The highest silica uptake is achieved for the KGC (82 mmol/g of precursor). This silica enrichment most likely operated in the water column and at the sediment–water interface by sorption mechanisms on the surface of detrital particles and particulate organic matter, as a result of seawater silica-saturation. Acidic conditions (pH 5.5–6.5) and hot temperatures (>70 °C) favored the formation of K-rich phyllosilicates by interaction with seawater during the early diagenetic alteration of the volcaniclastic particles. The widespread occurrence of K–Si-metasomatism in volcanic and sedimentary rocks can be regarded as a general alteration process of the Early Archean seafloor, with a major influence on seawater composition. The highly K-selective metasomatism confirms previous studies suggesting that the Archean ocean was acidic and probably in equilibrium with a CO₂-rich atmosphere.     

冀北—辽西早白垩世沉积有机质特征与古气候环境演变

本文对冀北—辽西地区早白垩世沉积盆地富有机质沉积岩进行了初步有机地球化学分析研究。结果显示,冀北—辽西沉积盆沉积有机质特征在时间和空间上存在很大差异,代表白垩系早期沉积的滦平盆地大北沟组有机质丰度低,这不仅显示其所代表的沉积相带不利于有机质的聚集,也反映了当时生物不够繁盛;大店子组时期沉积相带发生了变化,有机质类型随着发生了变化,丰度有所增高,但总体上显示环境条件不利于生物的发育和繁盛。到了桥头组和义县组沉积岩有机质丰度大幅升高,表明生物界非常繁盛,古气候环境有利于有机质的大量生成和堆积,总体上反映了温湿的气候条件;但同时也存在较为频繁或交替性寒冷气候波动,具体的古气候环境状态尚需进一步深入研究。     

中国南方志留系底部优质烃源岩发育的构造-环境模式

我们对宜昌王家湾和张家界三家馆两个剖面的上奥陶统-下志留统剖面的有机碳丰度、有机碳同位素、以及磷和硫元素进行了测定,并结合区域构造背景分析了有机质生产、聚集、保存的有利条件.研究表明,对于下志留统烃源岩而言,对有机质生产的主要贡献来自光合作用,所生成的有机质聚集在陆缘洼地型活动大陆边缘的分隔性盆地中,其有利保存的缺氧条件与冈瓦纳大陆北缘的区域性的缺氧有关.我们认为,扬子克拉通的志留系底部烃源岩与北非的"hot shale"一样,有很大的勘探前景.     

山东省济宁强磁异常区深部铁矿初步验证及其意义

山东省济宁磁异常是一个重、磁同源体,面积大于100 km2,磁异常峰值为3800nT。钻探验证在孔深1041.57～1796.54m位置发现铁矿体,矿体总厚度74.04～220m,磁性铁平均品位15.89～25.19%。矿石类型有条带状方解磁铁石英岩和条带状磁铁石英大理岩,矿石的主要组成矿物为石英、方解石、磁铁矿、磁赤铁矿、菱铁矿。矿体产于济宁岩群浅变质岩系中,矿床特征与条带状铁建造（BIF）铁矿或鞍山式铁矿有明显区别,铁矿成因类型属与千枚岩、变质中酸性火山岩、大理岩有关的沉积变质型铁矿床。该区铁矿资源潜力巨大。     

华北地台东部石炭系—二叠系优质煤储层形成分布控制因素

优质煤储层在此指厚度大、分布广、储集物性好的煤层。沉积相对优质煤储层的形成和分布有重要控制作用。通过浅海和泻湖淤积填平发育起来的潮坪环境和三角洲环境是最有利的优质煤储层形成环境,煤储层厚度大、分布广。沉积环境对煤储层中的灰分含量和镜质组含量有重要影响,而灰分含量和镜质组含量又直接影响煤储层的储集物性。灰分充填了煤储层中的孔隙,其含量越高,储集物性越差;镜质组有利于割理的形成,其含量越高,储集物性越好。由于在灰分含量、煤岩显微组分等方面的差异,潮坪环境沉积的煤储层的储集物性优于三角洲的煤储层,下三角洲平原沉积的煤储层优于上三角洲平原沉积的煤储层。海平面变化对优质煤储层的形成和分布也有重要控制作用。高位体系煤储层富集,单层厚度大,横向分布相当稳定,尤其是高位体系域晚期,是形成优质煤储层最有利的层位。而水进体系域煤储层稀少,单层厚度小,横向分布不稳定,不利于优质煤储层形成。     

西天山达巴特火山岩的形成环境及对斑岩型矿化的制约

本文通过对西天山地区比较典型的达巴特斑岩铜钼矿床矿区范围内出露上的英安岩和花岗斑岩进行了系统的岩石地球化学分析,对英安岩和流纹斑岩中的锆石进行了SHRIMP U-Pb定年研究,分别获得了315.9±5.9Ma和278.7±5.7Ma。岩石化学、微量以及稀土元素特征表明从英安岩到花岗斑岩,岩体具有明显的分异演化特征和很好的继承性。火山岩和次火山岩的精确定年为准确厘定火山岩形成的时限和地球动力学背景提供了依据。结合已有的Re-Os法获得的矿化年龄,表明晚石炭世末-早二叠世初（278.7±5.7Ma）,西天山地区进入板块碰撞-板内伸展阶段,由于板内幔根的部分熔化,造成深源斑岩岩浆侵位,在达巴特矿区形成了由花岗斑岩、流纹斑岩和流纹质凝灰熔岩组成的椭圆形火山机构,并导致相关矿床的形成。