天然气溶解过程中组分分馏模型及其应用

天然气不同组分在水中溶解度的差异,导致溶解相与残留游离相天然气组分组成不同,即发生组分的溶解分馏效应。溶解分馏效应在天然气水溶运移、溶解散失等过程中均有发生。揭示天然气组分的溶解分馏规律、建立定量分馏模型,有助于天然气气源对比和成藏过程示踪。以Henry定律为依据,对不同组分溶解特征分析,提出了溶解度分数的概念,并建立了溶解分馏模型。根据该模型和各组分的溶解度分数和天然气溶解量,可计算各组分的溶解分馏量,恢复天然气初始组成特征。计算表明,威远震旦系气藏初期的天然气组成为:CH4为72.70%,C2H6为0.09%,CO2为22.41%,N2为4.07%,干燥系数(C1/C1-5)为99.876%。溶解作用使天然气中CO2含量显著降低,烃类气体含量增加,而天然气干燥系数降低。结果有助于天然气成因判识和气源对比等。     

Fluid–Sediment Interaction in a Marine Shallow-Water Hydrothermal System in the Wakamiko Submarine Crater, South Kyushu, Japan

The Wakamiko submarine crater is a small depression located in Kagoshima Bay, southwest Japan. Marine shallow‐water hydrothermal activity associated with fumarolic gas emissions at the crater sea floor (water depth 200 m) is considered to be related with magmatic activity of the Aira Caldera. During the NT05‐13 dive expedition conducted in August 2005 using remotely operated vehicle Hyper‐Dolphine (Japan Agency for Marine‐Earth Science and Technology), an active shimmering site was discovered (tentatively named the North site) at approximately 1 km from the previously known site (tentatively named the South site). Surface sediment (up to 30 cm) was cored from six localities including these active sites, and the alteration minerals and pore fluid chemistry were studied. The pore fluids of these sites showed a drastic change in chemical profile from that of seawater, even at 30 cm below the surface, which is attributed to mixing of the ascending hydrothermal component and seawater. The hydrothermal component of the North site is estimated to be derived from a hydrothermal aquifer at 230°C based on the hydrothermal end‐member composition. Occurrence of illite/smectite interstratified minerals in the North site sediment is attributed to in situ fluid–sediment interaction at a temperature around 150°C, which is in accordance with the pore fluid chemistry. In contrast, montmorillonite was identified as the dominant alteration mineral in the South site sediment. Together with the significant low potassium concentration of the hydrothermal end‐member, the abundant occurrence of low‐temperature alteration mineral suggests that the hydrothermal aquifer in the South site is not as high as 200°C. Moreover, the montmorillonite is likely to be unstable with the present pore fluid chemistry at the measured temperature (117°C). This disagreement implies unstable hydrothermal activity at the South site, in contrast to the equilibrium between the pore fluid and alteration minerals in the North site sediment. This difference may reflect the thermal and/or hydrological structure of the Wakamiko Crater hydrothermal system.     

Numerical simulation of migration–accumulation of oil resources

Numerical simulation of oil migration and accumulation is to describe the history of oil migration and accumulation in basin evolution. It is of great value to the evaluation of oil resources and to the determination of the location and amount of oil deposits. This thesis discusses the characteristics of petroleum geology and permeation fluid mechanics. For the three-dimensional problems of Dongying hollow of Shengli Petroleum Oil Field, it puts forward a new model and a kind of modified method of upwind finite difference fractional steps implicit interactive scheme. For the famous hydraulic experiment of secondary migration–accumulation, the numerical simulation test has been done, and both the computational and experimental results are basically identical. For the actual problem of Dongying hollow, the numerical simulation test and the actual conditions are basically coincident. Thus, the well-known problem has been solved.     

The Glarus thrust: excursion guide and report of a field trip of the Swiss Tectonic Studies Group (Swiss Geological Society, 14.–16. 09. 2006)

This excursion guide results form a field trip to the Glarus nappe complex organized by the Swiss Tectonic Studies Group in 2006. The aim of the excursion was to discuss old and recent concepts related to the evolution of the Glarus thrust. The major aspects were (i) the interplay between deformation, fluid flow and geochemical alteration, (ii) episodic versus continuous deformation and fluid flow, and (iii) the link between large-scale structures, microstructures, and geochemical aspects. Despite 150 years of research in the Glarus nappe complex and the new results discussed during the excursion, there exist controversies that still are unsolved.     

New perspectives on Mars’ crustal magnetic field

The planet Mars lacks, today, a planetary, dynamic magnetic field, but strong, intense, localized magnetic fields of lithospheric origin, one to two orders of magnitude larger than the terrestrial lithospheric field, are present. This lithospheric magnetic field is the result of magnetization processes in the presence of a magnetic dynamo and of demagnetization processes after the dynamo shutdown, such as impact or volcanoes. This crude scenario can be more accurately specified by interpreting global and local models of the current magnetic field of Mars. Some specific areas are studied, including the intensely magnetized Terra Sirenum, as well as the magnetic anomaly associated with Apollinaris Patera. Magnetic minerals could be of primary and/or secondary origin; this latter would imply an early hydration of a basaltic crust. A scenario, in which Mars experienced a major polar wander due to the Tharsis bulge, prior to the cessation of its dynamo, is proposed and discussed.     

陕西关中盆地中部地下热水H、O同位素交换 及其影响因素

对关中盆地地下热水δ＆18O和8D数据的研究表明：盆地中部西安、咸阳深部的地压地热流体发生明显的δ^18O同位素交换,并出现^2H同位素交换,表明热储流体发生了强烈的水岩反应,盆地周边及中部的非地压地热流体^18O交换则不明显。根据研究区^18O同位素的交换程度（用^2H过量参数d表征）和水化学资料,可将关中盆地热储流体分为循环型和封闭型热储流体2类。地热水埋深越大、滞留时间越长、TDS和温度越高、地质环境越封闭,18^O交换程度就越大。西安和咸阳地下热水分属于不同的地热系统,具有不同的补给来源。     

西藏札达盆地控盆断裂有限元数值模拟

札达盆地是喜马拉雅构造带中的一个山间断陷盆地,其演化过程与盆地两侧的控盆构造密切相关。对控盆断裂的构造应力场进行模拟计算,将有助于进一步深化对本区构造控盆的认识。因此,在对盆地构造地质进行详细调查的基础上,结合本区的深部地质与地球物理资料,对札达盆地控盆断裂的构造应力场进行了模拟。计算结果表明,札达盆地的演化明显受盆地两侧边界断裂的控制,札达盆地是在整体南北向挤压应力的作用下,不同块体差异隆升作用的结果。其南侧的控盆断裂为北倾的正断层,北侧的控盆断裂为南倾的逆断层,二者共同形成了南降北升的翘板式断陷盆地运动过程,是喜马拉雅地块在陆内汇聚挤压构造环境中构造应力场调整的一种方式。     

鄂尔多斯盆地黄陵、东胜地区地温场对比

鄂尔多斯盆地黄陵、东胜铀矿区分别处于盆地南部渭北隆起的北侧边缘和盆地北部伊盟隆起的东部,赋矿层位都是中侏罗统直罗组。盆地南、北铀矿区在现今地温场及古地温场都存在明显差异,南部现今大地热值及热演化程度明显高于北部。对于下侏罗统延安组和石炭—二叠系煤层,黄陵地区镜质体反射率都高于东胜地区。通过镜质体反射率资料得出同一埋深的一套地层经历的最大古地温和对应的古地温梯度也有南部高于北部的现象。由于早白垩世后期盆地普遍整体抬升使得现今地温相对古地温降低,南部黄陵地区抬升剥蚀量大于北部东胜地区,导致古、今地温差异也大于后者。盆地南部庆阳—富县一带局部构造热运动,导致南部异常地温场的形成,使得南部热演化程度高于北部。     

人工边坡潜在滑动面研究——以广州科学城某人工高边坡为例

运用强度参数的改变对边坡破坏面形迹影响不明显这一特点,在数值模拟过程中通过改变岩体强度参数,有效地获取潜在滑动面的位置和形态,较好地解决了滑动面搜索的难题。将该法应用于广州科学城某人工高边坡稳定性的研究,在三维数值模拟过程中,将强度参数大幅度折减,计算后获得各剖面的剪应变增量图,从这些图中可获得潜在滑动面。这与人们通常将此类边坡的中风化面作为滑动面存在较大差别。将该滑动面运用极限平衡法进行计算,计算结果显示各剖面的安全系数基本都大于1.2,边坡稳定但仍需要加固处理,与三维数值模拟结果相一致。由此认为用这种分析法确定出的潜在滑动面合理、计算结果可靠,可作为搜索边坡潜在滑动面并计算安全系数的方法之一。     

西藏扎布耶盐田盐渍土的改性配比试验

根据盐渍土的物理化学性质,采用掺入不同比例石灰或水泥的方法进行改性处理。经击实、抗剪和抗压强度试验结果表明,盐渍土掺入石灰或水泥改性后,混合料的最大干密度、最优含水率、强度指标等均有增加,特别是内聚力迅速增长。研究表明,盐渍土混合料的性状得到了明显改善,改性后的混合料可用于修建盐田埝堤类相关工程。