利用U—1000型激光拉曼探针测定流体包裹体气体成分的研究

本文利用U－1000型激光拉曼探针成功地测量出单个流体包裹体中H2S、CH4、CO2气体成分，并讨论了包裹体中这些气体的拉曼谱峰位移与包裹体内压的关系，分析了影响激光拉曼探针定量测定包裹体气相成分的取面积和拉曼定量因子因素。     

西藏羊八井地热田水热蚀变

本文对羊八井地热田钻扎ZK-201、ZK-301和ZK-308的岩心进行了较系统的蚀变矿物学、岩石学和流体包体研究。划分出6个蚀变矿物共生组合及蚀变分带,讨论了蚀变过程中岩石化学变化的特点,并推测了蚀变的温度和酸碱度条件。研究表明,热田曾处于极度的活动状态,最高温度达220-240℃,由于冷水的入侵,热田在目前钻探所及范围已冷却了50-70℃。蚀变矿物分布模式表明,目前热田流体主通道位于北部,热田进一步的开发应以寻找北部深部高温流体为主。     

The fractal geometry of flow paths in natural fractures in rock and the approach to percolation

The distributions of contact areas in single, natural fractures in quartz monzonite (Stripa granite) are found to have fractal dimensions which decrease fromD=2.00 to values nearD=1.96 as stress normal to the fractures is increased from 3 MPa up to 85 MPa. The effect of stress on fluid flow is studied in the same samples. Fluid transport through a fracture depends on two properties of the fracture void space geometry. the void aperture; and the tortuosity of the flow paths, determined through the distribution of contact area. Each of these quantities change under stress and contribute to changes observed in the flow rate. A general flow law is presented which separates these different effects. The effects of tortuosity on flow are largely governed by the proximity of the flow path distribution to a percolation threshold. A fractal model of correlated continuum percolation is presented which quantitatively reproduces the flow path geometries. The fractal dimension in this model is fit to the measured fractal dimensions of the flow systems to determine how far the flow systems are above the percolation threshold.     

The Partitioning of Tungsten bwtween Aqueous Fluids and Silicate Melts

An experimental study has been carried out to determine the partition coefficients of tungsten between aqueous fluids and granitic melts at 800 °C and 1.5 kb with natural granite as the starting material. The effects of the solutions on the partition coefficients of tungsten show a sequence of P > CO ₃ ²⁻ > B > H₂O. The effects are limited (generallyK _D < 0.3) and the tungsten shows a preferential trend toward the melt over the aqueous fluid. The value ofK _D increases with increasing concentration of phosphorus; theK _D increases first and then reduces with the concentration of CO ₃ ²⁻ when temperature decreases, theK _D between the solution of CO ₃ ²⁻ and the silicate melt increases, and that between the solution of B₄O ₇ ²⁻ and the silicate melt decreases. The partition coefficients of phosphorus and sodium between fluids and silicate melts have been calculated from the concentrations of the elements in the melts. TheK _D value for phosphorus is 0.38 and that for sodium is 0.56. Evidence shows that the elements tend to become richer and richer in the melts.     

江汉盆地T油田新沟嘴组成岩流体及流体／矿物反应热力学

对江汉盆地Ｔ油田主要的工业储层－下第三系新光沟嘴组沉积岩石的成岩流体进行了热力学研究。实测的成岩矿物流体包裹体的均一温度为１１０－１３９℃，属于该区中成岩阶段的温度范围（６７－１５５℃）。成岩流体的压力为１０．２－５６ＭＰａ。成岩流体中阳离子的活度出现Ｃａ＾２＋＞Ｍｇ＾２＋＞Ｎａ＾＋＞Ｋ＾＋＞Ｆｅ＾３＋＞Ｆｅ＾２＋；阴离子的活离出现ＨＣＯ３＾－＞ＳＯ４＾２－＞Ｆ＾－＞Ｃｌ＾－＞ＣＯ３＾２－；气相成     

On the significance of CO2 inclusions in plagioclase microphenocrysts in tholeiite from Moeraki,New Zealand

Liquid plus vapour inclusions of CO₂ are widespread in plagioclase microphenocrysts in small tholeiitic intrusions and tephra of the Moeraki and adjacent areas of northeast Otago, New Zealand. They imply the presence of immiscible CO₂ droplets in the magma at depths of about 7–14 km. Their presence within 5 μm of the edges of microphenocrysts as little as 35 μm thick and 118 μm long indicates minimal feldspar crystal growth during the final ascent and quenching of the magma. Delicate branching clusters of lath-like microphenocrysts escaped disruption during this ascent. Such CO₂ inclusions are a potential source of ‘excess argon’ perturbing K-Ar age determinations. Received March 24, 1993/Accepted September 10, 1993     

旋转流体物理实验中见到的大气环流特征

在合适的实验参数下(热力Rossby数R_(OT)=0.1,Taylor数T_a=2.2 ×10~7),在旋转斜压流中,大尺度地形强迫造成低频振荡以及大气环流中的“阻塞”流型。这是由于地形强迫造成的准静止波与行进波的相互作用及共振引起的。地形把波数单一的流动变成多波数的流动。地形强迫使波数减少。     

中国东部地洼阶段应力场与锡成矿

中国东部地壳地洼阶段的热塑性变形应力场有利于锡成矿。构造应力场对锡成矿的控制作用,表现为对成矿域的矿液运移势和能量场的控制。推导获得矿液运移势的计算公式:Vi=-(a·K_0/u)·[exp(σ_1-σ_2)]·(σ_1+σ_2),表明地壳构造应力场对成矿域矿液的运移和成矿部位的选择提供了有利的动力学条件。     

四川威远气田烃流体包裹体的研究

通过烃流体包裹体的类型、均一化温度、气相及液相成分、盐度以及同位素的研究,可以认为威远气田的天然气主要是由白云岩中有机质形成。由于从80～160℃到200～240℃的热解作用,有机物质已演化到过成热阶段。这一过程可由白云岩中存在液态烃及含沥青烃流体包裹体得到证明。威远气田的特征是:震旦系白云岩中天然气的自产自储,以CH_4为主;油田水为古海水,盐度(4.3～17.2)wt%NaCl,pH>8,(CO+CH_4)/CO_2比值指示还原条件。在基底花岗岩石英中发现有气态烃包裹体,其成分及δ~(13)C‰与花岗岩储气层中产出的天然气一致,为部分天然气可能来自深部地壳或地幔提供了新的证据。因而,威远气田天然气的成因主要由有机物质形成,部分甲烷气可能经基底断裂来自地球深处。