基于灰色算子的尾矿坝浸润线混沌研究

对于尾矿坝浸润线时间序列，通过建立一个灰色算子，来弱化坝体高度、库内水位等因素所带来的确定性影响，突出混沌特性，形成新的时间序列，对该序列进行相空间重构后，求取关联维。德兴铜矿2#尾矿坝浸润线观测数据的分析结果表明，灰色算子能较好地处理混沌问题，浸润线时间序列存在着非整数维，是一个混沌系统：对于尾矿坝安全不能进行长期预测，而需要长期监测。     

Dissolved inorganic carbon evolution in neutral discharge from mine tailings piles

We measured the concentrations of dissolved inorganic carbon (DIC) and major ions and the stable carbon isotope ratios of DIC (δ¹³C_DIC) in two creeks discharging from carbonate‐rich sulphide‐containing mine tailings piles. Our aim was to assess downstream carbon evolution of the tailings discharge as it interacted with the atmosphere. The discharge had pH of 6.5–8.1 and was saturated with respect to carbonates. Over the reach of one creek, the DIC concentrations decreased by 1.1 mmol C/l and δ¹³C_DIC increased by ~4.0‰ 200 m from the seep source. The decrease in the DIC concentrations was concomitant with decreases in the partial pressure of CO_2(aq) because of the loss of excess CO_2(aq) from the discharge. The corresponding enrichment in the δ¹³C_DIC is because of kinetic isotope fractionation accompanying the loss of CO_2(g). Over the reach of the other creek, there was no significant decrease in the DIC concentrations or notable changes in the δ¹³C_DIC. The insignificant change in the DIC concentrations and the δ¹³C_DIC is because the first water sample was collected 160 m away from the discharge seep, not accessible during this research. In this case, most of the excess CO_2(aq) was lost before our first sampling station. Our results indicate that neutral discharges from tailings piles quickly lose excess CO_2(aq) to the atmosphere and the DIC becomes enrich in ¹³C. We suggest that a significant amount of carbon cycling in neutral discharges from tailings piles occur close to the locations where the discharge seeps to the surface. Copyright © 2015 John Wiley & Sons, Ltd.     

我国尾矿综合利用研究现状及建议

尾矿资源综合利用问题已受到世界各国的重视,其对策已由消极的废物处理转向物质再回收,尾矿资源化的发展趋势越来越清晰。但是,我国尾矿综合利用率和发达国家相比还存在较大的差距。大量的尾矿积存,对矿山周边地区环境、土地利用造成了严重的影响。开展典型尾矿资源综合利用技术研究和推广尾矿资源产业化利用技术研究与推广,不但可使原来资源枯竭或资源不足的矿山焕发青春,而且还能够重新成为新的资源基地,以开辟新的材料科技领域,推动科技进步,同时也可以解决环境污染、改善生态环境和整治国土,具有巨大社会、经济和环境效益。因此尾矿的综合利用要做到国家重視、立法保障、评价先行、技术支撑、全部利用,才能真正解决尾矿污染等问题。     

Water-rock-tailings interactions and sources of sulfur and metals in the subtropical mining region of Taxco,Guerrero (southern Mexico): A multi-isotopic approach

Multi-isotope (H, O, S, Sr, Pb) systems coupled with conventional (major and trace element) hydrogeochemical analysis were applied to determine the origin of water, to model water-rock-tailings interactions and for source apportionment of sulfur and associated toxic metals in the mining region of Taxco, Guerrero in southern Mexico. Oxygen and H isotopes indicate that meteoric water in the zone is rainwater undergoing varying degrees of isotopic fractionation by atmospheric evaporation whereas Sr isotopes trace the interaction of pristine water from volcanics of the regional recharge zone and subsequently flowing through sandstone and shale to spring points. Leachates form from two distinctive sources (spring water and surface water) having differential interactions with bedrocks prior to entering the tailings. Compared to pristine water, leachates are enriched in sulfate, metals (e.g. Fe, Mn, Pb and Zn) and metalloids (e.g. As). The sulfur isotopic composition of ore-sulfides, leachates, secondary precipitates, regional surface water and hypogenic sulfates is described in terms of a two-component mixing model with shale of Mexcala and limestone of Morelos formations representing the light and heavy end-members, respectively, whereas Sr isotopic composition is bracketed combining three lithogenic (Mexcala/Morelos, Tilzapotla and Taxco Schist) sources. Finally, leachates have a mixture of lead from ore-sulfides and Taxco Schist Formation (Family I) or from ore-sulfides alone (Family II). The application of multiple environmental isotopic techniques is an outstanding tool for elucidating complex interactions of water with bedrocks and tailings and for determining the source of sulfur and toxic metal from mining and other metal polluted environments.     

Sequestration of molybdate during transformation of 2-line ferrihydrite under alkaline conditions

Hematite is a thermodynamically stable iron oxide under the aerobic conditions present in most natural surface soils and sediments. Most studies to date have focused on the capacity of hematite to adsorb trace metals and metalloids, but structural incorporation of trace metals within hematite is less recognized. This study assessed the incorporation of molybdenum within the structure of hematite during the phase transformation of 2-line ferrihydrite under alkaline conditions (pH ∼10). Extended X-ray absorption fine structure analyses show molybdenum incorporated into hematite, with two Mo-O shells having a coordination number (CN) of 3 and average bond distances of 1.78 ± 0.01 and 2.08 ± 0.02 Å, respectively, as well as two Mo-Fe shells with a CN of 3 and average bond distances of 3.10 ± 0.02 Å and 3.44 ± 0.02 Å, respectively. This observation suggests the tetrahedrally-coordinated Mo in the molybdate that adsorbs onto the 2-line ferrihydrite changes to an octahedrally-coordinated Mo within the hematite with Mo possibly substituting for Fe in the hematite structure. Our findings suggest that molybdenum partitioning (low concentrations) to iron oxides in the environment can occur due to structural incorporation as well as adsorption.     

辐射井技术在尾矿库降排水工程中的应用

尾矿库是我国重大危险源之一,而尾矿库内的浸润线又是坝体安全的重要指标之一,为有效排出尾矿中的水,降低尾矿库内浸润线,本文通过辐射井技术在尾矿库降排水工程中应用的多个成功工程实例,归纳、总结并提出该技术在尾矿库应用过程中的设计思路、施工要点及工艺方法等。     

杨林坳钨矿尾矿资源勘查及综合回收利用工艺浅析

通过对湖南省衡南县川口乡杨林坳钨矿尾矿库尾砂的勘查、试验分析、前期综合利用科研工作情况介绍,分析了今后综合回收尾矿中有价金属、非金属及充分消耗尾砂的工艺思路,以达到充分利用、消耗尾砂,提高循环经济利用率,大大降低尾砂对环境污染和尾矿库存在的隐患。     

江西德兴铜矿区水系的Cu同位素地球化学特征及其地质意义

江西德兴铜矿水系样的δ65Cu值具有极大的变化范围(-5.8‰~+24.4‰),是迄今为止已报道发现的最大的Cu同位素分馏值。水体中铜的来源可分为黄铜矿源和黄铁矿源,二者具有明显不同的Cu同位素特征。根据水体的Cu同位素值分布特征,圈出了流经矿体(矿体上方)水、矿体外围水和尾矿库水3个源区。水体中的Cu主要以离子态和微粒态存在,二者具有明显不同的65Cu特征,尾矿库中黄铁矿65Cu对水体的Cu同位素组成具有较大的影响作用。Cu同位素在示踪找矿及地质环境监测方面具有良好的应用潜力。     

典型矿区尾矿库特征污染物识别研究

通过对典型尾矿库土壤样品分析,利用重金属超标率、植物体BCF、污染因子的权重值筛选等通进行典型污染物识别,为开展尾矿库污染治理工作提供依据。     

Isolation of protein from Chlorella sorokiniana CY1 using liquid biphasic flotation assisted with sonication through sugaring-out effect

Microalgae,a sustainable source of multi beneficial components has been discovered and could be utilised in pharmaceutical,bioenergy and food applications.This study aims to investigate the sugaring-out effect on the recovery of protein from wet green microalga,Chlorella sorokiniana CY1 which was assisted with sonication.A comparison of monosaccharides and disaccharides as one of the phaseforming constituents shows that the monosaccharides,glucose was the most suitable sugar in forming the phases with acetonitrile to enhance the production of protein(52% of protein).The protein productivity of microalgae was found to be significantly influenced by the volume ratio of both phases,as the yield of protein increased to 77%.The interval time between the sonication as well as the sonication modes were influencing the protein productivity as well.The optimum protein productivity was obtained with 10s of resting time in between sonication.Pulse mode of sonication was suitable to break down the cell wall of microalgae compared to continuous mode as a lower protein yield was obtained with the application of continuous mode.The optimum condition for protein extraction were found as followed:200g/L glucose as bottom phase with volume ratio of 1:1.25,10s of resting time for ultrasonication,5s of ultrasonication in pulse mode and 0.25g of biomass weight.The high yield of protein about 81% could be obtained from microalgae which demonstrates the potential of this source and expected to play an important role in the future.