冀西北坝上地区石墨矿成矿模式及找矿模型

通过分析冀西北坝上地区石墨矿地质背景、含矿带、矿体、含矿建造、变质变形及混合岩化特征,总结得出该区石墨矿的成矿特征。通过对比区域典型石墨矿床与同一成矿带相邻石墨矿床的地质特征,结合区域大地构造演化规律,总结了石墨矿的成矿模式。按照“三位一体”找矿理论,总结了石墨矿的成矿地质体及构造特征,构建了石墨矿综合找矿模型。该区石墨矿呈似层状赋存于红旗营子岩群含石墨变粒岩中,矿带分布受大型复式褶皱控制,含矿建造的沉积时代为古元古代早期,变质成矿时代为古元古代中期,变质程度为角闪岩相,成因类型为区域变质型。该区为浅覆盖区,“低阻-高极化”物探异常是重要的地球物理找矿标志,地质-物探-钻探相结合是石墨找矿快速、有效的手段。     

中国石墨供应风险评价

石墨是战略性矿产,是支撑未来战略性新兴产业发展的重要资源。通过收集石墨储、产、消、贸、价等方面的数据资料,构建了资源安全、贸易安全和市场安全三维供应风险评价体系,通过计算资源保障程度、自给率、进口份额占比、进口国家风险、进口国家集中度、进口价格波动指数、价格波动指数7个指标对石墨资源供应风险进行评价,结果显示市场安全对石墨供应风险影响最大。建议建立大鳞片石墨资源储备制度,实施石墨出口配额制度,以石墨烯技术辐射带动整个石墨产业,打破石墨提纯及深加工技术垄断,引领中国石墨产业发展,促进中国由石墨资源大国向石墨资源强国迈进。     

高频红外法测定石墨样品中的固定碳

采用硝酸酸化处理,低温焙烧氧化除去无机碳及有机碳,样品于高频红外碳硫分析仪测定固定碳质量分数,经国家标准物质验证,测定值与标准值相符,方法精密度RSD%为0.71,检出限为0.02%,满足石墨低品位固定碳质量分数分析质量要求。     

在线液-液萃取微型万用分相器的设计和应用 Ⅰ.连续流动萃取石墨炉原子吸收测环境水中镉和不同价态的铬

计了一种用于液＿液萃取，可与各种检测器配合并适用于比重大于或小于水的有机溶剂的微型万用分相器及相应的流路系统。用于与石墨炉原子吸收分光计联用测定环境水中镉和铬，检出限分别为５８ｎｇ／Ｌ和０１７μｇ／Ｌ，精密度（ＲＳＤ，ｎ＝９）分别为５４％和６７％，加标回收率为９２％～１０８％，样品测定速率为３０／ｈ。     

Internal structure of Longmenshan fault zone at Hongkou outcrop,Sichuan,China,that caused the 2008 Wenchuan earthquake

This paper reports the internal structures of the Beichuan fault zone of Longmenshan fault system that caused the 2008 Wenchuan earthquake,at an outcrop in Hongkou,Sichuan province,China.Present work is a part of comprehensive project of Institute of Geology,China Earthquake Administration,trying to understand deformation processes in Longmenshan fault zones and eventually to reproduce Wenchuan earthquake by modeling based on measured mechanical and transport properties.Outcrop studies could be integrate...     

石墨炉原子吸收法测定钛铁矿中的微量镉

研究了石墨炉原子吸收测定钛铁矿中微量元素Cd的方法,探索了在高含量的Fe,Ti基体干扰下以NH4H2PO4-H2NCSNH2-EDTA为混合基体改进剂的最佳仪器工作条件。在取样0.200 0g,定容25mL的条件下,方法检出限为0.006μg/g,用国家标准物质验证,其准确度(RE%)10%,12次测定精密度(RSD%)10%,加标回收率90%~110%之间,符合国家相关要求。     

Internal structure of Longmenshan fault zone at Hongkou outcrop,Sichuan, China,that caused the 2008 Wenchuan earthquake

This paper reports the internal structures of the Beichuan fault zone of Longmenshan fault system that caused the 2008 Wenchuan earthquake, at an outcrop in Hongkou, Sichuan province, China. Present work is a part of comprehensive project of Institute of Geology, China Earthquake Administration, trying to understand deformation processes in Longmenshan fault zones and eventually to reproduce Wenchuan earthquake by modeling based on measured mechanical and transport properties. Outcrop studies could be integrated with those performed on samples recovered from fault zone drilling, during the Wenchuan Earthquake Fault Scientific Drilling (WFSD) Project, to understand along-fault and depth variation of fault zone properties. The hanging wall side of the fault zone consists of weakly-foliated, clayey fault gouge of about 1 m in width and of several fault breccia zones of 30–40 m in total width. We could not find any pseudotachylite at this outcrop. Displacement during the Wenchuan earthquake is highly localized within the fault gouge layer along narrower slipping-zones of about 10 to 20 mm in width. This is an important constraint for analyzing thermal pressurization, an important dynamic weakening mechanism of faults. Overlapping patterns of striations on slickenside surface suggest that seismic slip at a given time occurred in even narrower zone of a few to several millimeters, so that localization of deformation must have occurred within a slipping zone during coseismic fault motion. Fault breccia zones are bounded by thin black gouge layers containing amorphous carbon. Fault gouge contains illite and chlorite minerals, but not smectite. Clayey fault gouge next to coseismic slipping zone also contains amorphous carbon and small amounts of graphite. The structural observations and mineralogical data obtained from outcrop exposures of the fault zone of the Wenchuan earthquake can be compared with those obtained from the WFSD-1 and WFSD-2 boreholes, which have been drilled very close to the Hongkou outcrop. The presence of carbon and graphite, observed next to the slipping-zone, may affect the mechanical properties of the fault and also provide useful information about coseismic chemical changes.     

原子荧光法测定高纯石墨粉中的砷、锑

提出以硫脲-抗坏血酸-硼氢化钾反应体系,利用氢化物发生原子荧光法测定高纯石墨粉中的砷、锑含量。讨论了试剂纯度的影响、硫脲一抗坏血酸预还原时间的选择、干扰试验、硼氢化钾溶液的用量等影响。实验结果表明,该方法对高纯石墨粉中的砷、锑含量分析准确、快速、简便,在试验条件下,砷的检出限为0．02mg／kg、锑的检出限为0．007mg／kg;砷的回收率为94％～108％、锑的回收率为96％～108％。采用该方法能满足电池行业用石墨规定的指标。     

湖南鲁塘石墨矿Re-Os同位素研究

石墨具有较高的Re、Os含量,可望成为理想的Re-Os同位素测年对象,但迄今国内外研究较少,尤其在煤层经变质作用形成石墨过程中,其中Re-Os同位素体系的变化还有待研究。湖南鲁塘石墨矿是我国典型的隐晶质石墨矿床之一,矿体产于二叠系龙潭组煤系地层中。本文采用Carius管逆王水溶解样品,直接蒸馏、微蒸馏分离纯化Os,丙酮萃取法分离富集Re,热表面电离质谱法对鲁塘矿区石墨样品以及外围原煤进行了Re-Os同位素分析。结果表明:鲁塘石墨的Re含量为0.901~9.794 ng/g,Os含量为7.3~189.5 pg/g,Re-Os同位素等时线年龄为155.6±3.6 Ma,该年龄与鲁塘石墨矿东侧骑田岭岩体第二阶段中粒黑云母花岗岩锆石U-Pb年龄153~157 Ma一致,表明了龙潭组煤层受到骑田岭岩体"烘烤"作用,发生热接触变质作用,使得靠近骑田岭岩体原煤变质为石墨,形成石墨矿床。通过对比石墨、原煤和骑田岭岩体Re、Os含量及比值,发现石墨中的Re、Os主要来源于原煤,并根据石墨Re-Os等时线初始(187Os/188Os)i值(0.686±0.032),推测骑田岭岩体在侵入煤系地层过程中,有少量具有较低187Os/188Os值的Os被碳质吸附。     

石墨炉原子吸收光谱法测定水质中的锂

采用石墨炉原子吸收光谱法,以4％NH4NO3消除干扰。测定水样中的锂。试验了影响测定的主要因素。在优化实验条件下,方法的检出限为0．27μg／l,特征量为4．2pg,锂的质量浓度为0μg／l～30μg／l时,工作曲线线性关系良好。对于ρ(Li)=20．0μg／l样品的测定相对标准偏差(RSD,n=12)为3．03％。