CNO燃烧核反应的研究

本文利用势垒穿透模型计算重离子融合反应截面,我们发现理论计算结果同现有的实验数据符合得相当好。在此基础上,对~(12)C+~(12)C,~(12)C+~(14)N,~(12)C+~(16)O,~(14)N+~(14)N,~(14)N+~(16)O和~(16)O+~(16)O六种融合反应,在T_9=-0.1—5.0温度范内数值计算了这些热核反应率,并给出了它们随温度变化的近似解析表达式.对~(12)C+~(12)C,~(12)C+~(16)O和~(16)O+~(16)O这三种热核反应率,我们的新结果明显地低于Caughlan等人在1985年的列表值,特别是~(16)O+~(16)O的热核反应率比文[21中值低7—20倍,这将对整个大质量恒星的演化、超新星爆发以及核合成带来较大的影响,本文简略地讨论了这些影响.     

Origin of Pyroxenite-Peridotite Veined Mantle by Refertilization Reactions: Evidence from the Ronda Peridotite (Southern Spain)

The Ronda orogenic peridotite (southern Spain) contains a varietyof pyroxene-rich rocks ranging from high-pressure garnet granulitesand pyroxenites to low-pressure plagioclase–spinel websterites.The ‘asthenospherized’ part of the Ronda peridotitecontains abundant layered websterites (‘group C’pyroxenites), without significant deformation, that occur asswarms of layers showing gradual modal transitions towards theirhost peridotites. Previous studies have suggested that theselayered pyroxenites formed by the replacement of refractoryspinel peridotites. Here, we present a major- and trace-element,and numerical modelling study of a layered outcrop of groupC pyroxenite near the locality of Tolox aimed at constrainingthe origin of these pyroxenites after host peridotites by pervasivepyroxene-producing, refertilization melt–rock reactions.Mg-number [= Mg/(Mg + Fe) cationic ratio] numerical modellingshows that decreasing Mg-number with increasing pyroxene proportion,characteristic of Ronda group C pyroxenites, can be accountedfor by a melt-consuming reaction resulting in the formationof mildly evolved, relatively low Mg-number melts (0·65)provided that the melt fraction during reaction and the time-integratedmelt/rock ratio are high enough (>0·1 and > 1,respectively) to balance Mg–Fe buffering by peridotiteminerals. This implies strong melt focusing caused by melt channellingin high-porosity domains resulting from compaction processesin a partial melted lithospheric domain below a solidus isothermrepresented by the Ronda peridotite recrystallization front.The chondrite-normalized rare earth element (REE) patterns ofgroup C whole-rocks and clinopyroxenes are convex-upward. Numericalmodeling of REE variations in clinopyroxene produced by a pyroxene-forming,melt-consuming reaction results in curved trajectories in the(Ce/Nd)_N vs (Sm/Yb)_N diagram (where N indicates chondrite normalized).Based on (Ce/Nd)_N values, two transient, enriched domains betweenthe light REE (LREE)-depleted composition of the initial peridotiteand that of the infiltrated melt may be distinguished in thereaction column: (1) a lower domain characterized by convex-upwardREE patterns similar to those observed in Ronda group C pyroxenite–peridotite;(2) an upper domain characterized by melts with strongly LREE-enrichedcompositions. The latter are probably volatile-rich, small-volumemelt fractions residual after the refertilization reactionsthat generated group C pyroxenites, which migrated throughoutthe massif—including the unmelted lithospheric spinel-tectonitedomain. The Ronda mantle domains affected by pyroxenite- anddunite- or harzburgite-forming reactions (the ‘layeredgranular’ subdomain and ‘plagioclase-tectonite’domain) are on average more fertile than the residual, ‘coarsegranular’ subdomain at the recrystallization front. Thisindicates that refertilization traces the moving boundariesof receding cooling of a thinned and partially melted subcontinentallithosphere. This refertilization process may be widespreadduring transient thinning and melting of depleted subcontinentallithospheric mantle above upwelling asthenospheric mantle. KEY WORDS: subcontinental mantle; refertilization; pyroxenite; peridotite; websterite; melt–rock reaction; plagioclase; trace elements     

Sensitivity of a Titan ionospheric model to the ion-molecule reaction parameters

Various aspects of ion-molecule reactions for Titan ionospheric chemistry modeling are reviewed in this work: temperature/collision energy effects on reaction rates and, more importantly, on products distributions; differential reactivity of isomers of ions; reactivity of excited states of ions; pathways to the building of complex ions. We evaluate here the extent to which these points affect model predictions. We find that the present limiting factors to model predictivity are the model incompleteness for heavy ion production pathways; the differential reactivity of isomers; and, to a lesser degree, the temperature effects on the branching ratios of ion-molecule reactions. Extensive experimental studies are required to fill these gaps in ion-molecule reactivity knowledge.     

考虑桩周土竖向作用大直径楔形桩纵向振动特性

将桩土系统划分为数量足够多的微元段,相邻微元桩段接触面处的环形凸面与土的相互作用采用单个Voigt体模拟,求得Voigt体的弹簧和黏壶系数。结合相邻微元桩段接触面上的应力平衡条件和位移连续条件,得到修正的阻抗函数递推法,桩身采用Rayleigh杆考虑桩身的横向惯性效应。结合桩底的边界条件,运用拉普拉斯变换和修正的阻抗函数递推法求得了平面应变条件下成层土中考虑桩周土竖向作用时大直径楔形桩桩顶复阻抗的解析解。通过与已有解对比,研究了桩周土竖向作用对桩顶复刚度和桩顶在瞬态激振下的速度响应的影响,并在低频域内详细分析了桩周土的竖向作用与桩土系统参数对桩顶复刚度的影响的耦合作用。     

基于Pt/SAPO-11和Pt/ZSM-22催化剂的溶剂脱蜡油加氢异构反应

采用常规水热法合成SAPO-11和ZSM-22分子筛,制备分别含有分子筛的催化剂,借助XRD、SEM和NH3-TPD表征2种催化剂的结构和酸性,并以加氢预精制溶剂脱蜡油为原料,采用固定床反应器研究Pt/SAPO-11和Pt/ZSM-22催化剂的加氢异构反应性能.结果表明:催化剂的反应活性和选择性主要取决于催化剂的酸量和酸强度,相对而言,由于SAPO-11分子筛催化剂弱酸含量较高,具有更佳的异构化选择性.利用1HNMR和13CNMR核磁共振研究加氢异构反应前后基础油的化学结构变化,Pt/SAPO-11催化剂有较高的加氢异构选择性.     

黄土高原小流域重力侵蚀稳定可靠度分析

在应用有限差分FLAC3D软件对黄土高原小流域概化模型塑性屈服区分布规律进行数值模拟的基础上,采用基于FLAC3D的有限元强度折减法和简化一次二阶矩法相结合的方法研究了小流域概化模型重力侵蚀稳定可靠度和破坏概率。结果表明：小流域剪切塑性区域主要分布于坡面和沟坡大部分区域,张拉塑性区域主要分布于梁峁顶和梁峁坡上部;小流域边坡整体破坏概率达到28.6%,高于1%,表明流域重力侵蚀处于高破坏概率范畴之内,处于不可接受的风险水平,需采取适当的工程措施以提高其稳定性;采用安全系数法和可靠度相结合的二元指标评价体系分析和评价边坡稳定性,能获得更为合理、可靠的分析结果。相关数值模拟和稳定可靠度分析结果可应用于流域重力侵蚀研究中,为推动流域侵蚀产沙时空规律研究的深入发展和小流域水土流失综合治理提供科学依据。     

凡纳滨对虾遗传多样性研究中AFLP体系的建立

凡纳滨对虾是当今世界公认的重要对虾养殖品种之一,然而良种选育研究仍相对落后,亟需采用分子遗传学手段加以解决.本文以凡纳滨对虾为材料,对预扩增体系、选择性扩增体系中的稀释倍数、dNTP浓度、Taq浓度、Mg2+浓度、引物浓度进行比较,结果表明,300 ng基因组DNA采用5U PstI和5UMseI双酶切4 h,16℃连接过夜,连接产物稀释10倍进行预扩增,预扩增产物稀释50倍进行选择性扩增,能够得到稳定丰富的条带,最终建立了适用于凡纳滨对虾的AFLP反应体系.本研究又进一步应用优化后的AFLP反应体系,从64对选择性扩增引物组合中筛选出12对多态性高的引物组合,便于对凡纳滨对虾基因多态性位点进行分析,从而为凡纳滨对虾的遗传多样性研究奠定基础.     

求解反应扩散方程的紧致隐积分因子方法

积分因子(IF)方法是近年来提出的求解刚性常微分方程组的一种有效的数值方法。本文应用改进的紧致隐积分因子(cIIF)方法求解二维反应扩散方程。在空间离散上采用二阶中心差分方法。数值模拟得到各种斑图结构与所引文献结果相当一致。     

位场向下延拓的导数迭代法

针对向下延拓的不适定问题,提出了一种新的位场向下延拓方法-导数迭代法。从位场垂向一阶导数的定义出发,将观测面和向上延拓、向下延拓同等高度平面上的位场值近似联系起来,采用迭代法进行逐次逼近,推导出空间域位场向下延拓的导数迭代法的递推公式。考虑到空间域向上延拓积分方程实现的复杂性,对递推公式进行快速傅里叶变换,整理得到波数域中的导数迭代公式,同时证明了该方法的收敛性。模型检验和实例分析均表明迭代法相对直接FFT法具有稳定性强和下延深度大的优点。     

复杂地基反力模式下高承台嵌岩灌注桩的屈曲稳定分析

为探讨桩侧地基土反力对高承台嵌岩灌注桩桩身屈曲稳定的影响,假定地基反力系数呈更为复杂的幂分布,基于弹性地基梁理论建立桩土体系总势能方程,采用最小势能原理,导出了桩身屈曲临界荷载与稳定计算长度的解析解,并据此获得了地基反力系数分布模式、桩身自重及桩侧摩阻力等对桩身屈曲稳定的影响规律。工程应用分析结果表明,考虑地基反力系数为一般幂分布时,桩身屈曲分析结果更趋合理。