Oxygen Isotope Exchange Kinetics Between Coexisting Minerals and Water in the Aral Granite Pliiton of the Altay Mountains,Northern Xinjiang

Abstract Coexisting quartz, feldspar and biotite vary widely in their δ¹⁸O values and display a remarkable ¹⁸O / ¹⁶O disequilibrium relation; especially, a quartz–feldspar reversal (Δ ¹⁸O_{Quartz?feldspar}<0) exsists in the Aral granite pluton of the Altay Mountains, northern Xinjiang. The ¹⁸O / ¹⁶O exchange reaction definitely occurred between granite and water. Initial δ¹⁸O values of the granite and exotic fluid are evaluated by the mass balance consideration. The conventional method of discrimination between various magma derivations simply with δ¹⁸O values of either whole rock or separate minerals is misleading and unreliable. Experiments carried out by the authors show that the ¹⁸O / ¹⁶O exchange reaction is not accompanied by what geologists describe as petrological and mineralogical alteration effect. This decoupling relation implies that exchange reaction occurs at a relatively high temperature during subsolidus–postmagmatic cooling of magmas. The exchange mechanism is mainly diffusion–controlled. It is demonstrated through quantitative modelling that the hydrothermal system associated with the Aral pluton is long–lived (0.8—6 Ma), with a relatively high fluid flow rate (3 x 10^?14 mol. s^?1) and high W/ R ratio (0.79-6.14). This means that an intense flow and convection may exist at the midcrustal level of orogenic magmatic arcs.     

流体输运,化学反应与交代作用

在成矿及变质作用过程中， 体运移促使热量发生传输及周围岩石发生化学反应和交代作用。流体输过一化学反应耦合动力学方程能定量评价热液系统组分浓度、温度和流量函数的人演化，对于区域变质和交代韧性断裂带等变质系统，还可通过流体运称方向和时间积分流体能量来定量描述流体输运一化学反应耦合客观变持地体中水力破裂的形成与流体运移和失挥发分反应耦合过程有关。     

热液系统流体输运－化学反应耦合动力学综述

输运－反应模式通过连续质量守恒方程进行描述，它表示为主要组分的Ｎ＋Ｍ个耦合的非线性偏微分方程。这些方程可以通过有限差分或有限元等数值方法进行求解。利用准静态近似法，涉及平流、分子扩散和水动力弥散作用的地球化学系统的演化在时间上通过一系列静止状态模拟出来。模拟实际地质系统的动力学实验对输运－反应耦合动力学的应用具有十分重要的影响。     

Growth of monodisperse,submicron aerosol particles exposed to SO2, H2O2, and NH3

The growth of monodisperse particles (0.07 to 0.5 µm) exposed to SO₂ (0–860 ppb), H₂O₂ (0–150 ppb) and sometimes NH₃ (0–550 ppb) in purified air at 22 °C at relative humidities ranging from 25 to 75% were measured using the Tandem Differential Mobility Analyzer technique. The experiments were performed in a flow reactor with aqueous (NH₄)₂SO₄ and Na₂SO₄ droplets. For (NH₄)₂SO₄ droplets the fractional diameter growth was independent of size above 0.3 µm but decreased with decreasing size below that. When NH₃ was added the fractional growth increased with decreasing size. Measurements were compared with predictions of a model that accounts for solubility of the reactive gases, the liquid phase oxidation of SO₂ by H₂O₂, and ionic equilibria. Agreement between measured and predicted droplet growth is reasonable when the ionic strength effects are included. Theory and experiments suggest that NH₃ evaporation is responsible for the decrease in relative growth rates for small aqueous ammonium sulfate particles. The observed droplet growth rates are too slow to explain observed growth rates of secondary atmospheric sulfate particles.     

造影剂在CT动态扫描中应用与副反应的对照研究

本文分析及总结了ＣＴ动态２增强扫描中使用的６０％泛影葡胺造影剂的最优化剂量，以减少病人副反应发生发生率。根据泛影葡胺的理化特性及反应发生机理及注入体内不同组织时间的一密度曲线，经２００例分组实验和１５００例临床应用证明ＣＴ动态增强扫描注入造影剂的最优化剂量为６０ｍｌ／次，从而取代过去的１００ｍｌ／次。     

Evaluation of the processes affecting vertical water chemistry in an alluvial aquifer of Mankyeong Watershed, Korea, using multivariate statistical analyses

Vertical variations of redox chemistry and groundwater quality were investigated in an alluvial aquifer beneath an agricultural area, in which deep groundwaters are free of NO₃, Fe, and Mn problems that are frequently encountered during the development of alluvial groundwaters. This study was performed to identify and evaluate vertical chemical processes attenuating these chemical species in the study area. For this study, the processes affecting groundwater chemistry were identified by factor analysis (FA) and the groundwater samples collected from six multilevel samplers were hierarchically classified into three different redox zones by cluster analysis (CA) based on the similarity of geochemical features. FA results indicated three major factors affecting the overall water chemistry: agricultural activities (factor 1), redox reactions (factor 2), and remnant seawater (factor 3). The groundwater quality in the study area was revealed to be controlled by a series of different redox reactions, resulting in different redox zones as a function of depth. It was also revealed that the low Fe and Mn levels in the groundwater of the deeper part are associated with sulfate reduction, which led to precipitation of Fe as iron sulfide and adsorption of Mn on it.     

Calcite Dissolution in Deionized Water from 50°C to 250°C at 10 MPa: Rate Equation and Reaction Order

Carbonate minerals and water （or geofluids） reactions are important for modeling of geochemical processes and have received considerable attention over the past decades. The calcite dissolution rates from 50℃ to 250℃ at 10 MPa in deionized water with a flow rate varying from 0.2 to 5 mL/min were experimentally measured in a continuous flow column pressure vessel reactor. The dissolution began near the equilibrium with c/ceq 〉 0.3 and finally reached the equilibrium at 100℃-250℃, so the corresponding solubility was also determined as 1.87, 2.02, 2.02 and 1.88×10^-4.mol/L at 100℃, 150℃, 200℃ and 250℃ respectively, which was first increasing and then switching to decreasing with temperature and the maximum value might occur between 150℃ and 200℃. The experimental dissolution rate not only increased with temperature, but also had a rapid increase between 150℃ and 200℃ at a constant flow rate of 4 mL/min. The measured dissolution rates can be described using rate equations of R = k（1-c/ceq）n or R = kc-n. In these equations the reaction order n changed with temperature, which indicates that n was a variable rather than a constant, and the activation energy was 13.4 kJ/mol calculated with R = k（1-c/ceq）n or 18.0 kJ/mol with R = kc^-n, which is a little lower than the surface controlled values. The varied reaction order and lower activation energy indicates that calcite dissolution in this study is a complex interplay of diffusion controlled and surface controlled processes.     

A New Index Developed for Fast Diagnosis of Meteorological Roles in Ground-Level Ozone Variations

China experienced worsening ground-level ozone(O₂) pollution from 2013 to 2019. In this study, meteorological parameters, including surface temperature(T₂), solar radiation(SW), and wind speed(WS), were classified into two aspects,(1) Photochemical Reaction Condition(PRC = T₂× SW) and(2) Physical Dispersion Capacity(PDC = WS). In this way, a Meteorology Synthetic Index(MSI = PRC/PDC) was developed for the quantification of meteorology-induced ground-level O₂pollution. The positive linear relationship between the 90 th percentile of MDA8(maximum daily 8-h average) O₂concentration and MSI determined that the contribution of meteorological changes to ground-level O-3 varied on a latitudinal gradient, decreasing from ~40% in southern China to 10%–20% in northern China. Favorable photochemical reaction conditions were more important for ground-level O₂pollution. This study proposes a universally applicable index for fast diagnosis of meteorological roles in ground-level O₂variability, which enables the assessment of the observed effects of precursor emissions reductions that can be used for designing future control policies.     

熊本牡蛎(Crassostrea sikamea)多嵴和无嵴品系子二代生长性状的选择效应

为了进一步检查熊本牡蛎(Crassostrea sikamea)多嵴品系及无嵴品系的连续选择反应能力,以两个品系子一代上选组为材料,以壳高为指标,按照10%选择强度,开展了两个品系子二代混合上选研究,评估了两个品系子二代选择反应、现实遗传力,计算了两个品系的遗传改进量。结果表明:两个品系仍具有较高的现实遗传力,多嵴品系遗传参数均大于无嵴品系,表现出较好的遗传改良效果。多嵴和无嵴品系幼虫期的选择反应分别为0.47、0.34,稚贝期为0.65、0.40,养成期为0.82、0.56;幼虫期的现实遗传力分别为0.27、0.19,稚贝期为0.37、0.23,养成期为0.47、0.32;幼虫期的遗传改进量分别为4.83%、3.61%,稚贝期为7.55%、5.76%,养成期为9.95%、6.47%。经过一周年的养成,多嵴品系壳高显著大于无嵴品系,两个品系现实遗传力分别为0.50、0.35,遗传改进量分别为10.13%、6.61%。由此可见,多嵴品系具有较快的生长速度,遗传改良潜力较大。本研究为熊本牡蛎遗传改良和新品系培育奠定了坚实的基础。     

表生环境中镁同位素的地球化学循环

近些年表生环境中镁同位素分馏取得了一系列重要研究进展,这些新认识为深入理解表生环境中镁同位素地球化学循环奠定了基础。表生环境中镁同位素的地球化学循环主要涉及风化、河流搬运、碳酸盐沉淀、水岩反应等重要地质过程。风化过程中镁同位素发生显著分馏,硅酸盐风化产物中富集重的镁同位素,轻的镁同位素易进入水体。河流搬运过程中,镁同位素不发生分馏,但外源输入可能影响水体的镁同位素组成。河水汇入海洋后,碳酸盐沉淀过程可导致轻的镁同位素以碳酸盐的形式从海水中移出。在海底高温水岩反应过程中,海水中绝大多数的镁(80%~87%)都进入岩石,循环后的热液可能富集轻的镁同位素。海底低温水岩反应过程中海水的镁可以进入岩石并形成次生矿物,此过程的镁同位素分馏主要与次生矿物的形成有关。此外,海水中的镁易与黏土矿物发生交换反应,此过程黏土矿物倾向于吸附轻的镁同位素。总之,在表生环境中上地壳的镁(δ26Mg约为-0.22‰)经历风化作用、河流搬运、海洋贮存,最终以碳酸盐岩(δ26Mg一般小于-1‰)或与玄武岩发生反应的形式重新回到岩石圈。