Bohai crude oil identification by gas chromatogram fingerprinting quantitative analysis coupled with cluster analysis

1 IntroductionWith the development of industry, more andmore petroleum energy sources are needed. The ex-ploitation of, especially benthal, develops quickly.The spilled oil accidents occur inevitably during oilexploitation and transportation. For example, in theBohai Sea, there are more than 1 000 oil wells andthe spilled oil accidents occur almost every year. Allkinds of dissension arose since the accidents couldnot be dealt with effectively in time. The key stepwhich affects the accidents …     

Allocation of commingled pipeline oils to field production

This paper presents a case study of using oil fingerprinting technology to correctly back allocate commingled pipeline crude to production from six contributing fields in an offshore southeast Asia basin. A large number of oil and pipeline samples were collected over time and analyzed by gas chromatography for their oil fingerprints. In this case, production from each field pipeline could easily be distinguished by their whole-oil fingerprints that changed little with time. However, oils collected from the commingled pipelines showed significant chromatographic variation with time, indicating production contribution from the different fields to the pipelines varied with time. Quantitative results were attained using a proprietary computer program which mathematically calculates relative contributions (±3%) of oil mixes based on a best-fit least-squares regression of selected chromatographic peak ratios. This allocation method assisted operations to more accurately determine production for each field or a group of fields in the basin. The technique, which provides a new approach to supplement and cross-check production metering necessary for defining tax liability, has helped save significant tax dollars for field operation units.     

Application of light hydrocarbons (C4–C13) to oil/source rock correlations:: a study of the light hydrocarbon compositions of source rocks and test fluids from offshore Mid-Norway

Relatively little work has been published on the correlation between the light hydrocarbon distributions in reservoir fluids and their proposed source rocks [Philippi, G. T. (1981)]. The aim of our work was to study this relationship in detail for samples from Mid-Norway. The main source rocks offshore Mid-Norway are the marine shales of the Late Jurassic Spekk Formation and the coals and paralic shales of the Early Jurassic Åre Formation. Reliable light hydrocarbon (C₄–C₁₃) data for source rock samples were acquired by thermal extraction-GC of the source rocks. Of these, notably the hydrocarbons in the C₆–C₈ range (routinely measured in test fluids) were used to discriminate between the Spekk and Åre Formation samples. A total of twenty-six samples from the Spekk Formation and twenty-four samples from the Åre Formation at different maturity levels and facies were analyzed. In general, the two source rock types differ in their light hydrocarbon composition by the presence of relatively more aromatics and cyclohexanes in the Åre samples, while the Spekk samples are richer in cyclopentanes and acyclic hydrocarbons. We show that source rock facies is a more important indicator of light hydrocarbon composition than maturity variation. Differences in the chemical composition, which can be used to discriminate between the two source rocks, were supported by differences in the carbon isotope composition of individual components of the same fraction, as determined by GHM-IR-MS analysis of eleven samples. Further, the light hydrocarbon compositions of reservoir fluids (oils and condensates) were compared with those for the source rock(s). Sixty-six gas chromatograms of oils and condensates, representing most of the known petroleum accumulations in Mid-Norway, were collected. Of these, five oil samples were selected for detailed isotopic analysis of individual components (GC-IR-MS). When using a classification scheme based on data from sediment samples, data for the light hydrocarbon fraction of oils and condensates indicate that the Spekk Formation is the dominant source for most of the fields from Mid-Norway, with a significant contribution from the Åre Formation being detected principally in one field. Differences in the chemical composition of the C₆–C₈ fractions were supported by differences in the carbon isotope composition of individual components, which also discriminate between the oils. Although the classification diagrams used in this study are based on source rock data from Mid-Norway, the method can be applied to other areas, providing that the diagrams are calibrated with source rock data from the area of interest.     

Sediment delivery from agricultural land to rivers via subsurface drainage

Diffuse sources of sediment and sediment‐associated nutrients are of increasing environmental concern because of their impacts on receiving water courses. The aim of the research reported here was to monitor the outflow from four field (land) drains at two farms in the English Midlands in order to estimate the quantity of sediment delivered to the local rivers and the most likely sources and processes involved. A multiparameter sediment unmixing model was employed, using environmental magnetic, geochemical and radionuclide tracers in order to determine the most likely origin of sediments transported through the drains. Results demonstrated that there was a generally linear relationship between drainflow sediment loss and drainflow volume and that the majority (>70%) of the sediment exported from the drains was derived from topsoil. Macropore flow through heavily cracked soils is supported by the data to be the most likely means of sediment delivery to the drains. In one catchment, drains contributed over 50% of the annual sediment budget. Spatial and temporal variations in the sources of sediment reaching one drain outlet were investigated in detail. A link between soil moisture deficit (SMD) and the frequency of high‐intensity rainfall events was used to explain the appearance and persistence of a new sediment source in this drain after October 1998. It is concluded that field drains have the potential to be significant conduits of sediment and agrochemicals in a wide variety of environments in the UK. It is also suggested that this potential may increase if projected climate change leads to more intense rainfall events and increases in SMD across a greater area of the UK. Copyright © 2005 John Wiley & Sons, Ltd.     

Temporal variability of suspended sediment sources in an alpine catchment combining river/rainfall monitoring and sediment fingerprinting

Influence of the rainfall regime on erosion and transfer of suspended sediment in a 905‐km² mountainous catchment of the southern French Alps was investigated by combining sediment monitoring, rainfall data, and sediment fingerprinting (based on geochemistry and radionuclide concentrations). Suspended sediment yields were monitored between October 2007 and December 2009 in four subcatchments (22–713 km²). Automatic sediment sampling was triggered during floods to trace the sediment origin in the catchment. Sediment exports at the river catchment outlet (330 ± 100 t km^‐2 yr^‐1) were mainly driven (80%) by widespread rainfall events (long duration, low intensities). In contrast, heavy, local and short duration storms, generated high peak discharges and suspended sediment concentrations in small upstream torrents. However, these upstream floods had generally not the capacity to transfer the sediment down to the catchment outlet and the bulk of this fine sediment deposited along downstream sections of the river. This study also confirmed the important contribution of black marls (up to 70%) to sediment transported in rivers, although this substrate only occupies c. 10% of the total catchment surface. Sediment exports generated by local convective storms varied significantly at both intra‐ and inter‐flood scales, because of spatial heterogeneity of rainfall. However, black marls/marly limestones contribution remained systematically high. In contrast, widespread flood events that generate the bulk of annual sediment supply at the outlet were characterized by a more stable lithologic composition and by a larger contribution of limestones/marls, Quaternary deposits and conglomerates, which corroborates the results of a previous sediment fingerprinting study conducted on riverbed sediment. Copyright © 2012 John Wiley & Sons, Ltd.     

Identifying remains of extinct kangaroos in Late Pleistocene deposits using collagen fingerprinting

Our knowledge of past animal populations, including the geographical ranges of extinct species, has largely been derived from morphological analyses of skeletal fossil remains. However, a major barrier to the identification of the remains of extinct megafaunal species in archaeological and palaeontological sites is the highly fragmented nature of the material, which often precludes confident taxonomic identifications based on morphology. Biomolecular techniques are able to go beyond these limitations and are increasingly being used to make such identifications. Protein analysis offers a promising alternative to DNA techniques because they can be much cheaper, more amenable to high‐throughput processing and work on much older specimens. Here we demonstrate the potential of collagen fingerprinting in an Australian context by extracting collagen from 50‐ka kangaroo fossils from two caves in Tasmania, and identify several species including the extinct short‐faced kangaroo Simosthenurus occidentalis . Importantly, of the five fossil bones sampled that had hitherto been ascribed morphology‐based identifications below the family level, three had been incorrectly identified during an initial assessment of photographs taken in the field. Our results highlight the utility of using protein‐based methods for making genus‐level identification of marsupial bone, especially those that may form a basis for broader arguments such as that of late‐surviving megafaunal species.