含水矿物在真空下的释Ar机制:Ar-Ar热年代学面临的新问题

地质体的实际情况、激光显微探针束研究、XRD和SEM观测以及真空加热下Ar的释放特征都表明体积扩散不是含水矿物在真空加热中释放Ar的唯一机制。在低温下 ,Ar的释放主要受由缺陷引起的短程扩散和体积扩散共同作用的多途径扩散机制制约 ;而在高温下 ,由于含水矿物在真空中不够稳定 ,Ar的释放受到脱羟基、脱氢、氧化反应、分层作用等造成的晶体结构改变的强烈影响。含水矿物在高温下的氧化分解会导致矿物中原始Ar浓度梯度的均一化 ,因而无法得到真实的Ar分布剖面 ,也无法据此计算矿物的封闭温度 ,并进而可能影响到ArAr年龄坪的地质意义。     

Pressure effect on Ti- or P-rich accessory mineral saturation in evolved granitic melts with differing K2O/Na2O ratios

The solubility of Ti- and P-rich accessory minerals has been examined as a function of pressure and K₂O/Na₂O ratio in two series of highly evolved silicate systems. These systems correspond to (a) alkaline, varying from alkaline to peralkaline with increasing K₂O/Na₂O ratio; and (b) strongly metaluminous (essentially trondhjemitic at the lowest K₂O/Na₂O ratio) and remaining metaluminous with increasing K₂O/Na₂O ratio (to 3). The experiments were conducted at a fixed temperature of 1000 °C, with water contents varying from 5 wt.% at low pressure (0.5 GPa), increasing through 5–10 wt.% at 1.5–2.5 GPa to 10 wt.% at 3.5 GPa. Pressure was extended outside the normal crustal range, so that the results may also be applied to derivation of hydrous silicic melts from subducted oceanic crust.

For the alkaline composition series, the TiO₂ content of the melt at Ti-rich mineral saturation decreases with increasing pressure but is unchanged with increasing K content (at fixed pressure). The P₂O₅ content of the alkaline melts at apatite saturation increases with increased pressure at 3.5 GPa only, but decreases with increasing K content (and peralkalinity). For the metaluminous composition series (termed as “trondhjemite-based series” (T series)), the TiO₂ content of the melt at Ti-rich mineral saturation decreases with increasing pressure and with increasing K content (at fixed pressure). The P₂O₅ content of the T series melts at apatite saturation is unchanged with increasing pressure, but decreases with increasing K content. The contrasting results for P and Ti saturation levels, as a function of pressure in both compositions, point to contrasting behaviour of Ti and P in the structure of evolved silicate melts. Ti content at Ti-rich mineral saturation is lower in the alkaline compared with the T series at 0.5 GPa, but is similar at higher pressures, whereas P content at apatite saturation is lower in the T series at all pressures studied. The results have application to A-type granite suites that are alkaline to peralkaline, and to I-type metaluminous suites that frequently exhibit differing K₂O/Na₂O ratios from one suite to another.     

多孔结构矿物（岩石）及其环境修复材料的实用性

具有多孔结构的矿物(岩石)作为一类特殊的工业原材料，在环境修复领域的应用前景正在成为研究热点。本文从微孔的尺度、结构、形态、成分等表面固体特征出发，概括性地论述了凹凸棒石、海泡石、蒙脱石、沸石、硅藻土等十几种多孔结构矿物(岩石)在环境修复工程中用作过滤材料、吸附剂、离子交换剂和催化剂等材料时的基本特征和使用时应注意的问题。     

柯树背岩体的副矿物特征及地质意义

本文详细研究了柯树背岩体的岩石学及副矿物学特征，研究发现F9大断裂以西部分(西体)与F9大断裂以东部分(东体)在岩性、矿物组成、副矿物特征、锆石群型特征上存在很大差别，副矿物特征、锆石群型特征指示东体与寨背岩体类似，为同熔系列花岗岩；西体为重熔再生岩浆成因的改造型花岗岩。这一认识对于该区的铀金找矿具有一定的指导意义。     

粘粒含量对南京粉细砂液化影响的试验研究

南京粉细砂是一种以片状颗粒成分为主的粉细砂，与通常的圆形颗粒石英砂有一定区别，片状颗粒成分使得南京粉细砂具有各向异性的性质。通过对不同粘粒含量的南京粉细砂进行液化试验，分析其试验结果发现：对于粘粒含量ρc＝5％、10％和15％三种情况，在均压固结情况下，当南京粉细砂达到初始液化时，采用变形标准和孔压标准是一致的；而偏压固结时，只能采用变形标准作为南京粉细砂达到初始液化的标准，此时振动孔压仅达到围压的50％-70％。粘粒含量对南京粉细砂的抗液化强度影响很大，随粘粒含量增加，在不同固结比时，其抗液化强度并不是单调变化，而是在粘粒含量ρc＝10％左右处于一个低谷，其抗液化强度最低。     

Flotation of oxidized minerals of copper using a new synthetic chelating reagent as collector

A new synthetic reagent containing a mixed aliphatic-aromatic structure, with a hydrocarbon chain and an aminothiophenol chelating group, has proven to be an effective collector for the flotation of chrysocolla minerals. The flotation is optimum in the narrow pH range of 5.5 to 6, falls sharply at pH 5, and is moderate in the pH range 7 to 11. Infrared spectra indicate that copper aminothiophenolate chelates are formed on the surface of the chrysocolla under the conditions of maximum flotation.     

矿物O同位素地球化学理论

应用增量方法不仅能够从理论上准确计算所有固体矿物的O同位素分馏系数，而且能够定量预测；（1）热力学平衡条件下共生矿物之间的18O富集顺序；（2）岩石化学成分与O同位素组成之间的关系；（3）矿物结构变化对O同位素组成的影响；（4）同质多相转变和矿物反应中的氧同位素继承性。本文对这些规律性预测进行了概要性介绍，并给出实例予以说明。     

南极长城站地区粘土矿物的空间分布规律与成因探讨

对南极长城站地区粘土矿物的空间分布与某些元素的地球化学行为之间的相关关系给予了较为详细的研究，并从地球化学方面探讨了粘土矿物的成因。研究表明，Ｃａ和Ｍｇ元素是高岭石生成的主要控制因子，高岭石的空间分布是两者共同作用的结果。Ｓｉ、Ｃａ、Ｍｇ和Ｆｅ元素的地球化学行为与蒙脱石在空间上的含量变化有明显的相关关系。Ｓｉ元素对蒙脱石的生成起到了较大的作用。     

四川盆地西部富钾卤水水文地球化学特征及其成因意义探讨

四川盆地西部宫钾卤水以深层卤水形式赋存于地下４０００余ｍ的中三叠统雷口坡组四段（Ｔ２ｌ４）盐系的碳酸盐岩储层中。富钾卤水与海水不同浓缩阶段相比，其中含Ｋ＋含量异常高，构成液态钾矿资源；Ｂｒ－、Ｉ－、Ｂ（３＋）、Ｌｉ＋等稀有组分也远超过综合利用工业品位，为优质化工原料水。富钾卤水为沉积变质和钾盐溶滤的复合成因，具有固夜态找钾的指示意义。本文为四川盆地固液态找钾提供了有价值的线索。