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Ti separation was achieved by ion-exchange chromatography using Bio-Rad AG 1-X8 anion-exchange and DGA resins. For high-Fe/Ti and high-Mg/Ti igneous samples, a three-column procedure was required, whereas a two-column procedure was used for low-Fe/Ti and low-Mg/Ti igneous samples. The Ti isotopes were analysed by MC-ICP-MS, and instrumental mass bias was corrected using a 47Ti-49Ti double-spike technique. The 47Ti-49Ti double-spike and SRM 3162a were calibrated using SRM 979-Cr, certificated value 53Cr/52Crtrue = 0.11339. Isobaric interference was evaluated by analysing Alfa-Ti doped with Na, Mg, Ca, and Mo, and results indicate that high concentrations of Na and Mg have no significant effect on Ti isotope analyses; however, Ca and Mo interferences lead to erroneous δ49/47Ti values when Ca/Ti and Mo/Ti ratios exceed 0.01 and 0.1, respectively. Titanium isotopic compositions were determined for 12 igneous reference materials, BCR-2, BHVO-2, GBW07105, AGV-1, AGV-2, W-2, GBW07123, GBW07126, GBW07127, GBW07101, JP-1, and DTS-2b. Samples yield δ49/47Ti (‰) of ?0.035 ± 0.022, ?0.038 ± 0.031, 0.031 ± 0.022, 0.059 ± 0.038, 0.044 ± 0.037, 0.000 ± 0.015, 0.154 ± 0.044, ?0.044 ± 0.018, 0.010 ± 0.022, 0.064 ± 0.043, 0.169 ± 0.034, and ?0.047 ± 0.025 (relative to OL-Ti, ±2SD), respectively; of which isotopic compositions of DTS-2b, JP-1, GBW07101, GBW07105, GBW07123, GBW07126, and GBW07127 are reported for the first time. Standard Alfa-Ti was analysed repeatedly over a ten-month period, indicating a reproducibility of ±0.047 (2SD) for δ49/47Ti, similar to the precisions obtained for geochemical reference materials. 相似文献
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为适应生态地质调查和评价工作对成土母质研究的要求,以四川大凉山区为例,提出基于地质建造的成土母质分类方案,即以地质构造演化和地质建造环境为依据,结合残坡积物的成因类型对成土母质进行分类。大凉山区的成土母质可划分为第四纪冲洪积物、新近纪—第四纪砂泥岩类残坡积物、侏罗纪—白垩纪泥质岩类残坡积物、三叠纪砂泥岩类残坡积物、中生代中酸性岩类残坡积物、二叠纪基性—超基性岩类残坡积物、震旦纪—三叠纪砂泥岩类残坡积物、震旦纪—三叠纪碳酸盐岩类残坡积物、元古宙中酸性岩类残坡积物、元古宙火山碎屑岩类残坡积物、元古宙基性—超基性岩类残坡积物、元古宙变质岩类残坡积物等12类。研究表明,大凉山区成土母质和土壤存在差异性,但同一成土母质上的不同土壤类型具有一定相似的地球化学特征,不同成土母质形成的同一种土壤类型存在较大的地球化学差异。因此,基于地质建造的成土母质分类方案既能有效反映不同构造背景和成岩环境下的成土母质差异,又能有效表征成土母质与其上土壤的内在联系。 相似文献
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The mathematical base of the double porosity concept, consisting of the continuity and equilibrium equation respectively, is briefly reviewed. A quasi-steady-state transfer function, the so-called leakage term, is used. Important aspects of the developed code, based on the double porosity theory, are presented together with two hypothetical example problems. The resulting trend of the settlements are compared to those from previous work and was found to be significantly different. However, the implications are that the present study exhibits a more realistic prediction for the settlement. 相似文献
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红层软岩边坡生态防护技术探讨 总被引:1,自引:0,他引:1
红层软岩边坡,土质贫瘠,浅层稳定性差,生态防护失效的现象比较突出。为提高西部红层软岩边坡生态防护的可靠性,在对西部红层软岩地区铁路、公路边坡生态防护状况进行调研和分析的基础上,总结红层软岩边坡生态防护失败的原因,吸取经验教训,提出适于红层软岩边坡的生态防护方法和适合该区栽植的草木品种及配置方法。 相似文献
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Marine plastic debris has been a pervasive issue since the last century, and research on its sources and fates plays a vital role in the establishment of mitigation measures. However, data on the quantity of plastic waste that enters the sea on a certain timescale remain largely unavailable in China. Here, we established a model using material flow analysis method based on life cycle assessment to follow plastic product from primary plastic to plastic waste with statistical data and monitoring data from accurate sources. This model can be used to estimate and forecast the annual input of plastic waste into the sea from China until 2020. In 2011, 0.547 3–0.751 5 million tons of plastic waste entered the seas in China, with a growth rate of 4.55% per year until 2017. And the amount will decrease to0.257 1 to 0.353 1 million tons in 2020 under the influence of governmental management. The amount of plastic waste discharged from coastal areas calculated in this study was much larger than that from river, thus it is suggested to strengthen the governance and control of plastic waste in coastal fishery activities in China in order to reduce the amount of marine plastic waste input. 相似文献