2004–2005 Analytical Developments in Secondary Ion Mass Spectrometry

This review of the literature from 2004 and 2005 concerning secondary ion mass spectrometry (SIMS) highlights the contribution the technique has made in the fields of petrology, geochronology, cosmochemistry and material sciences. In petrology, much research was devoted to the measurement of stable isotopes and trace elements by developments in multicollection acquisition, with emphasis on low atomic mass number elements. Elements studied in particular were S (in sulfides), O (in garnets), C (in sedimentary organic matter), Cl (in glasses) and Si. Novel applications of SIMS to geochronology have included the measurement of young zircon grains by the U-Pb and U-Th decay methods. An increasing number of studies have combined U-Pb geochronology with the measurement of trace elements or stable isotopes in zircon.     

长白山锦北雨养泥炭剖面元素富集规律分析

为了揭示长白山锦北泥炭沼泽区泥炭沉积环境和重金属元素的历史变化及其对环境的指示意义,利用荷兰W ardenaar泥炭采样器采取泥炭样品并对样品进行高分辨率切割。用原子吸收分光光度计和等离子体发射光谱仪测定不同深度剖面Ca,Mg,Na,K,A l,Ti,Cu,Zn,Fe,Mn,Pb,Cr,N i和Co的浓度。研究分析了Ca,Mg,Na,K,A l,Ti,Mn,Zn,Cu,Pb,Cr,N i和Co在泥炭剖面的分布趋势并对其进行了相关分析和富集分析,得出Mn,Zn,Cu,Pb,Cr,N i和Co呈显著相关且在泥炭表层明显累积,揭示出泥炭表层重金属元素的大气沉降来源,表明近年来人类重金属消耗量及排放量的增加是大气沉降重金属元素的主要释放源,而且环境中重金属污染有加重的趋势。     

Estimating the minimum in-stream flow requirements via wetted perimeter method based on curvature and slope techniques

Under the assumptions of triangular cross section channel and uniform stable flow, an analytical solution of the minimum ecological in-stream flow requirement (MEIFR) is deduced. Based on the analytical solution, the uncertainty of the wetted perimeter method is analyzed by comparing the two techniques for the determination of the critical point on the relationship curve between wetted perimeter, P and discharge, Q. It is clearly shown that the results of MEIFR based on curvature technique (corresponding to the maximum curvature) and slope technique (slope being 1) are significantly different. On the P-Q curve, the slope of the critical point with the maximum curvature is 0.39 and the MEIFR varied prominently with the change of the slope threshold. This indicates that if a certain value of the slope threshold is not available for slope technique, curvature technique may be a better choice. By applying the analytical solution of MEIFR in the losing rivers of the Western Route South-to-North Water Transfer Project in China, the MEIFR value via curvature technique is 2.5%-23.7% of the multi-year average annual discharge, while that for slope technique is 11%-105.7%. General conclusions would rely on the more detailed research for all kinds of cross-sections.     

Permeability of Hydraulic Fills and Barricade Bricks

Permeability is one of the most important parameters in the design of hydraulic backfilling of mine stopes. A simple and reproducible method was developed for preparing reconstituted hydraulic fill sample in the laboratory, that is representative of the hydraulic fill in the mine stope, replicating the slurry sedimentation process taking place in the mine. Constant head and falling head permeability tests were carried out on the samples, giving consistent results. A brick permeameter was developed to study the flow characteristics of the porous barricade bricks under one-dimensional flow, simulating the flow conditions in the mine. Three different methods were used to determine the permeability of the brick and the results showed very good agreement. This is the first rational attempt to measure the permeability of the porous barricade bricks that are used to close the horizontal access drives in the mines, thus retaining the hydraulic fill. The measurements show that the permeability of the barricade brick is about two to three orders of magnitude greater than that of the hydraulic fill.     

The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.     

江苏省矿山的主要生态环境问题及治理对策

江苏的经济发展较快,对矿产资源的需求量亦大。多年来的无序开采,对生态环境造成很大的破坏和影响,出现了山体植被遭受破坏、土地被占用、环境受污染、诱发地面沉降、地面塌陷等一系列问题,已影响到国民经济的发展。随着省人大和省政府关于限制开山采石和保护环境等政策、法规出台和落实,近几年乱采滥挖现象基本得到了有效的遏制。人们的环保意识得到了加强,不少矿山已逐步开始对环境治理,且初见成效。文章介绍了江苏生态环境现状、存在的主要问题和治理对策,以期引起各级政府和广大民众在对矿产资源开采的同时更要注重环境保护。     

龙永煤田危机矿山资源接替的几种勘探模式

通过龙永煤田现有煤矿状况调查分析发现：许多矿井已步入“花甲之年”，接近矿井服务年限。为了保障我省能源安全，应当采用有效勘探方法，方能使它们“返老还童”。研究发现危机矿山延长服务年限的几种勘探模式是：其一为扩大（延伸）勘探模式；其二为小型井田（块段）勘探模式；其三为资料分析研究模式。经探采对比发现，采用这三种勘探模式后，产生了巨大的经济效益，使一大批老矿井青春再度焕发。     

吾祠煤矿区构造特征及矿井生产布局探讨

通过对漳平市吾祠煤矿区的煤层地质构造特征分析，探讨了复杂构造条件下的矿井生产布局，主要是煤矿区段水平划分、煤炭采区的巷道布置、采煤方法及有关地质硐探等问题，对矿山开发有一定的指导意义。