Hot contacts of garnet peridotites in middle/upper crustal levels: new constraints on the nature of the late Variscan high-T/low-P event in the Moldanubian (Central Vosges/NE France)

P–T  paths based on parageneses in the immediate vicinity of former high-temperature contact zones between mantle peridotites and granulitic country rocks of the Central Vosges (NE France) were derived by applying several conventional thermometers and thermobarometric calculations with an internally consistent dataset. The results indicate that former garnet peridotites and garnet–spinel peridotites were welded together with crustal rocks at depths corresponding to 1–1.2 GPa. The temperature of the crustal rocks was about 650–700 °C at this stage, whereas values of 1100 °C (garnet peridotites) and 800–900 °C (garnet–spinel peridotites) were calculated for the ultramafic rocks. After emplacement of the mantle rocks, exhumation of the lower crust took place to a depth corresponding to 0.2–0.3 GPa. The temperatures of the incorporated peridotite slices were still high (900–1000 °C) at this stage. This is indicated by the presence of high- T  /low- P parageneses ( c . 800 °C, 0.2–0.3 GPa) in a small (1–10 m) contact aureole around a former garnet peridotite. Crustal rocks distant to the peridotites equilibrated in the same pressure range at lower temperature (650–700 °C). High cooling rates (10²–10³ °C Ma⁻¹) were calculated for a garnet–biotite rock inclusion in the peridotites and for the crustal rocks at the contact by applying garnet–biotite diffusion modelling. Minimum rates of 0.75–7.5 cm a⁻¹ are required for vertical ascent of rock units (30 km vertical distance) derived from the crust–mantle boundary, resulting in a late Variscan (340 Ma) high- T  /low- P event.     

Opx–Cpx exsolution textures in lherzolites of the Cretaceous Purang Ophiolite (S. Tibet,China), and the deep mantle origin of Neotethyan abyssal peridotites

ABSTRACT

We investigated lherzolitic peridotites in the Cretaceous Purang ophiolite along the Yarlung Zhangbo suture zone (YZSZ) in SW Tibet to constrain their mantle–melt evolution history. Coarse-grained Purang lherzolites contain orthopyroxene (Opx) and olivine (Ol) porphyroclasts with embayments filled by small olivine (Ol) neoblasts. Both clinopyroxene (Cpx) and Opx display exsolution textures represented by lamellae structures. Opx exsolution (Opx1) in clinopyroxene (Cpx1) is made of enstatite, whose compositions (Al₂O₃ = 3.85–4.90 wt%, CaO = <3.77 wt%, Cr₂O₃ = 0.85–3.82 wt%) are characteristic of abyssal peridotites. Host clinopyroxenes (Cpx1) have higher Mg#s and Na₂O, with lower TiO₂ and Al₂O₃ contents than Cpx2 exsolution lamellae in Opx, and show variable LREE patterns. Pyroxene compositions of the lherzolites indicate 10–15% partial melting of a fertile mantle protolith. P–T estimates (1.3–2.3 GPa, 745–1067°C) and the trace element chemistry of pyroxenes with exsolution textures suggest crystallization depths of ~75 km in the upper mantle, where the original pyroxenes became decomposed, forming exsolved structures. Further upwelling of lherzolites into shallow depths in the mantle resulted in crystal–plastic deformation of the exsolved pyroxenes. Combined with the occurrence of microdiamond and ultrahigh-pressure (UHP) mineral inclusions in chromites of the Purang peridotites, the pyroxene exsolution textures reported here confirm a multi-stage partial melting history of the Purang lherzolites and at least three discrete stages of P-T conditions in the course of their upwelling through the mantle during their intra-oceanic evolution.     

西藏雅鲁藏布江缝合带普兰地幔橄榄岩铬尖晶石成因研究

普兰蛇绿岩位于雅鲁藏布江缝合带西段,其中地幔橄榄岩由方辉橄榄岩、含单斜辉石方辉橄榄岩以及少量二辉橄榄岩及纯橄岩组成。尖晶石是地幔橄榄岩中常见的副矿物,可以作为重要的岩石学成因指示剂。在野外地质调查基础上,通过岩相观察、电子探针、尖晶石成分面分析、电子背反射衍射分析,可将普兰地幔橄榄岩铬尖晶石分为三类:第一类铬尖晶石呈自形,粒径较小(<100μm),或包裹于斜方辉石中,或杂乱分布于橄榄石和辉石之间,具有高Cr^#(>0.6)、低Mg^#(0.43~0.57)的特征,为部分熔融+玻安质熔体交代成因;第二类铬尖晶石呈半自形-他形,粒径较大(>100μm),常含有橄榄石、辉石包裹体,具有中Cr^#(0.17~0.42)、高Mg^#(0.63~0.77)的特点,主要受部分熔融作用影响;第三类铬尖晶石呈他形蠕虫状与辉石交生在一起构成后成合晶结构,粒径变化较大,具有低Cr#(0.17~0.28)、高Mg^#(0.67~0.77)的特点。EBSD分析结果显示尖晶石、辉石的结晶学优选方位(CPO)较为相似,表明为同一矿物分解而来,单斜辉石与大陆岩石圈地幔捕掳体中石榴子石的稀土元素对比表明构成后成合晶结构的辉石和铬尖晶石为具有大陆岩石圈地幔属性的高压石榴子石退变分解而成。综合分析表明:普兰蛇绿岩的地幔橄榄岩体在从石榴子石相深度上升过程中发生了石榴子石退变、岩石部分熔融及熔体渗透作用,岩体经历了威尔逊旋回初期的大陆裂谷阶段,主体经历了中-低程度的部分熔融,类似大洋中脊环境,局部受到了富硅、富镁玻安质熔体的影响。     

伊豆-小笠原前弧地区Hahajima海山蛇纹石化橄榄岩岩石学和地球化学研究

Serpentinites, which contain up to 13 wt% of water, are important reservoirs for chemical recycling in subduction zones. In the past two decades, forearc mantle serpentinites were identified in different locations around the world. Here, we present petrology and whole rock chemistry of ultramafic and mafic rocks dredged from the Hahajima Seamount, which is located 24–40 km west to the junction of the Izu-Bonin Trench and the Mariana Trench. Nearly all the collected samples are extensively hydrated, and olivine grains in ultramafic rocks are replaced by serpentine minerals, with only one sample preserving remaining trace of orthopyroxene. Our new results show that the Hahajima serpentinized peridotite samples are all MgO-rich(～42 wt%), but have low contents in Al_2O_3, CaO, rare earth and high field strength elements, which is consistent with the overall depleted character of their mantle protoliths. Model calculations indicate that these Hahajima peridotite samples were derived from 10%–25% partial melting of the presumed fertile mantle source, which is generally lower than those of peridotites from Torishima Forearc Seamount, Conical Seamount and South Chamorro Seamount(mostly25%). All the serpentinites from these four forearc seamounts show strong enrichment in fluid-mobile and lithophile elements(Li, Sr, Pb and U). In details, Hahajima Seamount serpentinites do not have obvious enrichment in Cs and Rb, and display remarkably high abundances of U. These observations indicate that the serpentinization of Hahajima peridotites occurred by addition of seawater or low temperature seawater-derived hydrothermal fluid, without or with little contribution from slab-derived fluids. The geochemical signature of serpentinites from Hahajima Seamount could be interpreted as the result of the combination of extensive partial melting and subsequent percolation of seawater through the mantle wedge.     

Estimating and simulating the degree of serpentinization of peridotites using hyperspectral remotely sensed imagery

The mineral products resulting from the process of serpentinization, by which primary magnesium silicate minerals in peridotites are replaced by hydrous serpentine-group minerals, are of economic importance since Alpine-type peridotites are the host rocks for virtually all large asbestos deposits, which may be attributed mainly to the serpentine-group mineral chrysotile. Conventional field mapping of the distribution of highly serpentinized areas is time consuming and requires detailed sampling and laboratory analysis. In 0.4- to 2.5-m reflectance spectra of serpentinized peridotites, serpentinization is responsible for a decrease in contrast of olivine-pyroxene iron absorption features and an appearance and increase in OH^– absorption features near 1.4 m and 2.3 m associated with serpentine minerals. The degree of serpentinization is positively correlated with the depth of the 1.4-m and 2.3-m absorption features for samples containing more than 55 weight percent serpentine minerals. Small amounts of magnetite in a sample obscure the spectral contrast and decrease the overall brightness of weakly serpentinized samples. A methodology is used for mapping serpentine minerals in ultrabasic rocks from imaging spectrometer data, which includes (1) vegetation masking, (2) calculating the absorption band depth of the 2.3-m absorption feature in unmasked pixels, (3) translating this value into percent serpentine minerals using an empirical linear model, and (4) estimating the degree of serpentinization at the remaining locations using conditional simulation techniques or ordinary block kriging. From the results of this study, it can be concluded that mapping the degree of serpentinization from high-spectral resolution imagery is possible within marginal statistical fluctuations. Conditional simulation reproduces the spatial and statistical variability of the data set; however, it sacrifices the local accuracy. Direct estimation using ordinary kriging provides a better local estimate but does not honor the statistics and spatial dispersion of the original data.The spectral analyses presented in this publication were carried out at the Jet Propulsion Laboratory in Pasadena, California. The author would like to thank Mrs. Cindy Grove for her help in processing the samples. Dr. Harold Lang is thanked for advice in interpreting the spectra. The article benefitted from critical comments by Dr. Roger Clark and Dr. John Mustard, and various discussions with Prof. Salemon Kroonenberg and Prof. Andrea Fabbri. The Spectral Image Processing System (SIPS) developed at the Center for the Study of Earth from Space (CSES) of the University of Colorado, Boulder, was used for the GERIS data calibration. This article benefitted from a critical review by Dr. Daniel H. Knepper, Jr.     

Mantle–crust interactions during Variscan subduction in the Eastern Alps (Nonsberg–Ulten zone): geochronology and new petrological constraints

We have analyzed the Sm–Nd and Rb–Sr whole-rock and mineral isotope systematics of garnet peridotites and associated eclogites and migmatitic gneisses from the Nonsberg–Ulten zone of the Eastern Alps. The garnet peridotites include coarse-grained varieties, characterized by well-preserved to slightly modified mantle geochemical signatures, and finer-grained varieties enriched in amphibole and LILE. Hydration of some of the most strongly deformed, fine-grained peridotites by crustal fluids caused isotopic disequilibrium between the peridotite minerals, preventing accurate age determinations. The coarse-grained peridotites, the eclogites and the country migmatitic gneisses yield garnet–whole-rock and garnet–clinopyroxene Sm–Nd ages that indicate for all rock types an isotopic homogenization event at ca. 330 Ma. The similar ages suggest that all rock types shared a common history since the incorporation of the peridotites in the crust, and constrain the garnet-facies metamorphism of the peridotites, as well as partial melting of the crust, to an episode of crustal subduction at the end of the Variscan orogenic cycle.     

亲铁元素异常——后增薄层模型

地幔中铂族元素丰度是基于地球形成理论所得计算值的两三百倍，无论是地幔中还是球粒陨石中，铂族元素之间的比值是相近的；对于这一现象有很多解释，其中被普遍接受的是：地核形成后(核幔分异完成后)，大约占现在地球质量0．5％-1％的球粒陨石物质加入地幔，即可造成现在地幔中的铂族元素在丰度与比值方面的特征，这就是后增薄层模型(Late-veneer model)。但是，这一模型受到很多地幔样品铂族元素具非球粒陨石比值和高压下Co、Ni亲铁性测定结果的挑战。最近的地幔橄榄岩各相铂族元素精确测定、高压下Pt、Pd金属相与硅酸盐分配系数的测定，以及Re-Os同位素的研究都支持后增薄层模型。     

Palaeomagnetic study of the Ronda peridotites (Betic Cordillera, southern Spain)

A palaeomagnetic study of the Ronda peridotites (southern Spain) has been carried out on 301 samples from 20 sites, spread along the three main outcrops of the ultrabasic complex: Ronda, Ojén and Carratraca massifs. Different lithologies and outcrops with different degrees of serpentinization have been sampled and analysed. Rock magnetic experiments have been carried out on a representative set of samples. These measurements include: Curie curves, hysteresis cycles, isothermal remanent magnetization (IRM) acquisition curves, thermal demagnetization of IRM imparted along three orthogonal axes and magnetic bulk susceptibility. Results indicate that magnetite is the main magnetic mineral present in the samples. Stepwise thermal and alternating field (AF) demagnetization of the natural remanent magnetization (NRM) reveals the presence of a characteristic remanent magnetization (ChRM) carried by magnetite, and in some sepentinized samples, a northward component with variable unblocking temperatures up to 250–575 °C. The appearance and the relative intensity of this northward component are strongly related to serpentinization degree. Taking into account the geological history of the peridotites, the ChRM has been considered as a thermo-chemical remanent magnetization acquired during the first serpentinization phase associated to the post-metamorphic cooling of this unit. On the basis of radiometric and fission track analysis, the ChRM is proposed to have been acquired between 20 and 17–18 Ma. The inclination of the mean direction of the ChRM statistically coincides with the expected inclination for stable Iberia during the Oligocene–Miocene. The declination of the ChRM differs from the expected declination, indicating clockwise block rotations of 41±12° about vertical axes since the cooling of the peridotites. When applying a compositional layering correction, the ChRM directions fail to pass this kind of fold test, thus, the compositional layering was not a palaeohorizontal during ChRM acquisition time. Normal and reversed polarities of the ChRM are reported, showing that at least one reversal of the Earth's magnetic field took place during ChRM acquisition process. A tentative polarity zonation within the peridotitic outcrops is also suggested. No evidence is found from these data for the previously proposed simultaneity between post-metamorphic cooling and rotation of the peridotites.     

The Composition of Near-solidus Partial Melts of Fertile Peridotite at 1 and 1{middle dot}5 GPa: Implications for the Petrogenesis of MORB

We have determined the near-solidus melt compositions for peridotiteMM-3, a suitable composition for the production of mid-oceanridge basalt (MORB) by decompression partial melting, at 1 and1·5 GPa. At 1 GPa the MM-3 composition has a subsolidusplagioclase-bearing spinel lherzolite assemblage, and a solidusat 1270°C. At only 5°C above the solidus, 4% meltis present as a result of almost complete melting of plagioclase.This melting behaviour in plagioclase lherzolite is predictedfrom simple systems and previous experimental work. The persistenceof plagioclase to > 0·8 GPa is strongly dependenton bulk-rock CaO/Na₂O and normative plagioclase content in theperidotite. At 1·5 GPa the MM-3 composition has a subsolidusspinel lherzolite assemblage, and a solidus at 1350°C.We have determined a near-solidus melt composition at 2% meltingwithin 10°C of the solidus. Near-solidus melts at both 1and 1·5 GPa are nepheline normative, and have low normativediopside contents; also they have the highest TiO₂, Al₂O₃ andNa₂O, and the lowest FeO and Cr₂O₃ contents compared with higherdegree partial melts. Comparison of these near-solidus meltswith primitive MORB glasses, which lie in the olivine-only fieldof crystallization at low pressure, indicate that petrogeneticmodels involving aggregation of near-fractional melts formedduring melting at pressures of 1·5 GPa or less are unlikelyto be correct. In this study we use an experimental approachthat utilizes sintered oxide mix starting materials and peridotitereaction experiments. We also examine some recent studies usingan alternative approach of melt migration into, and entrapmentwithin ‘melt traps’ (olivine, diamond, vitreouscarbon) and discuss optimal procedures for this method. KEY WORDS: experimental petrology; mantle melting; near-solidus; fertile peridotite; MORB     

New constraints on the evolution of the Gibraltar Arc from palaeomagnetic data of the Ceuta and Beni Bousera peridotites (Rif,northern Africa)

The Betic Cordillera and the Moroccan Rif together form one of the smallest and tightest orogenic arcs on Earth and almost completely close the Mediterranean to the west. For the explanation of the geodynamic evolution of the mountain belt, palaeomagnetic data that generally found clockwise block rotations in the Iberian and anticlockwise rotations in the Moroccan part of the mountain belt, have played a key role in recent works. This palaeomagnetic study has found new constraints on the rotations and timing of the peridotitic bodies outcropping in the key position at the westernmost margin of the mountain belt, in Ceuta and Beni Bousera (Rif, northern Africa).Detailed thermal demagnetization of 115 individually oriented samples from 14 sites was combined with rock magnetic and scanning electron microscopic experiments to analyze the magnetic mineralogy responsible for the remanences and the mechanisms and relative times of their acquisition. In Ceuta, up to three magnetic components, and in Beni Bousera, up to two magnetic components have been found, that are all to be interpreted as chemical remanent magnetizations (CRM). The data suggests the following succession of geodynamic events affecting the peridotites until recent times: (1) after their exhumation and subsequent cooling about 20 Ma ago, they recorded a characteristic remanent magnetization of both normal and reversed polarities, carried by (pseudo-)single-domain magnetite grains; (2) after their dismembering, the Ceuta peridotites were tilted southward by 22–34° about a horizontal or tilted axis (up to plunge 50°) with an azimuth of 72–145° and the Beni Bousera peridotites were rotated anticlockwise by 72.3 ± 12.1° about a vertical axis and (3) both recorded another magnetic signal of normal polarity only, carried by multi-domain magnetite grains; and finally (4) the Ceuta peridotites rotated anticlockwise by 19.7 ± 5.9° about a vertical axis.This study provides the first palaeomagnetic data for the Ceuta peridotites that, with their tilt and recent small net rotation, had a distinct geodynamic evolution from the large net rotations about vertical axes in Beni Bousera and Ronda (Betic Cordillera). Moreover, earlier palaemagnetic data for Beni Bousera is improved, as mixed polarities have been found in the older of the remanences for the first time, and its interpretation as a CRM changes the rotation timing that was proposed previously. The sequence of events exposed in this work are important constraints that need to be incorporated in any geodynamic model of the evolution of the Betic–Rifean mountain belt.