Rare Earth, Major and Trace Elements in the Kunimiyama Ferromanganese Deposit in the Northern Chichibu Belt, Central Shikoku, Japan

Abstract. Rare earth, major and trace element geochemistry is reported for the Kunimiyama stratiform ferromanganese deposit in the Northern Chichibu Belt, central Shikoku, Japan. The deposit immediately overlies greenstones of mid-ocean ridge basalt (MORB) origin and underlies red chert. The ferromanganese ores exhibit remarkable enrichments in Fe, Mn, P, V, Co, Ni, Zn, Y and rare earth elements (excepting Ce) relative to continental crustal abundance. These enriched elements/ Fe ratios and Post-Archean Average Australian Shale-normalized REE patterns of the ferromanganese ores are generally analogous to those of modern hydrothermal ferromanganese plume fall-out precipitates deposited on MOR flanks. However in more detail, Mn and Ti enrichments in the ferromanganese ores are more striking than the modern counterpart, suggesting a significant contribution of hydrogenetic component in the Kunimiyama ores. Our results are consistent with the interpretation that the Kunimiyama ores were umber deposits that primarily formed by hydrothermal plume fall-out precipitation in the Panthalassa Ocean during the Early Permian and then accreted onto the proto-Japanese island arc during the Middle Jurassic. The presence of strong negative Ce anomaly in the Kunimiyama ores may indicate that the Early Permian Panthalassa seawater had a more striking negative Ce anomaly due to a more oxidizing oceanic condition than today.     

古尔班通古特沙漠生物结皮的分布特征

新疆古尔班通古特沙漠是我国最大的固定和半固定沙漠，其间广泛发育着以地衣植物为主的生物结皮，是除种子植物以外的固定沙面的重要生物因子。研究表明，选择适当的时段，应用遥感技术并结合地面调查来研究沙漠生物结皮的空间分布格局是可行的，遥感制图与地面调查的结果基本一致。该沙漠南部是生物结皮最为丰富的区域，各种类型的生物结皮均有充分发育，呈连续分布，但其分布模式向北、向西和向东变得破碎。通过统计生物结皮像元的面积，得到生物结皮覆盖率超过33％的像元面积占研究区总面积的28．7％。生物结皮的分布对地貌部位有较强的选择性，生物结皮的不同发育阶段种类组成亦有较大的差别。     

Contrasting hydrological response of coastal and desert biocrusts

Biocrusts abound in southern Israel, covering the Hallamish dune field near Nizzana (NIZ) in the Negev (mean annual precipitation of 95 mm) and the coast of Nizzanim (NIM) near Ashdod (mean annual precipitation of 500 mm). While the hydrological response of the NIZ crust to natural rain events was thoroughly investigated, no data is available on the hydrological response of the NIM crust. Runoff was monitored in runoff plots during the years 2005–2008, and in addition, sprinkling experiments were carried out on NIM and NIZ crusts. For the evaluation of the possible factors that may control runoff initiation, fine content of the parent material, crust thickness, compressional strength, hydrophobicity, surface microrelief, organic matter, biomass (chlorophyll a and total carbohydrates) and the crust's species composition of NIM were studied and compared to that of NIZ. The data showed that in comparison to the NIZ crust that readily generated runoff, no runoff was produced by the NIM crust. This was so despite the fact that (1) Microculeus vaginatus predominated in both crusts, (2) the substantially higher rain intensities in NIM, (3) the greater thickness and higher chlorophyll content and (4) the lower microrelief at NIM in comparison to NIZ. The lack of runoff in NIM was explained by its low amounts of exopolysaccharides that did not suffice to affectively clog the surface and in turn to facilitate runoff initiation. The absence of runoff and its consequences on the NIM ecosystem are discussed. Copyright © 2012 John Wiley & Sons, Ltd.     

The effect of conservation practices in sloped croplands on soil hydraulic properties and root‐zone moisture dynamics

Rain‐induced erosion and short‐term drought are the two factors that limit the productivity of croplands in the red soil region of subtropical China. The objective of this study was to estimate the effects of conservation practices on hydraulic properties and root‐zone water dynamics of the soil. A 3‐year experiment was performed on a slope at Xianning. Four treatments were evaluated for their ability to reduce soil erosion and improve soil water conditions. Compared with no practices (CK) and living grass strips (GS), the application of polyacrylamide (PAM) significantly reduced soil crust formation during intense rainfall, whereas rice straw mulching (SM) completely abolished soil crust formation. The SM and PAM treatments improved soil water‐stable aggregates, with a redistribution of micro‐aggregates into macro‐aggregates. PAM and SM significantly increased the soil water‐holding capacity. These practices mitigated the degradation of the soil saturated hydraulic conductivity (Ks) during intense rainfalls. These methods increased soil water storage but with limited effects during heavy rainfalls in the wet period. In contrast, during the dry period, SM had the highest soil water storage, followed by PAM and CK. Grass strips had the lowest soil water storage because of the water uptake during the vigorous grass growth. A slight decline in the soil moisture resulted in a significant decrease in the unsaturated hydraulic conductivity (Ku) of the topsoil. Therefore, the hydraulic conductivity in the field is governed by soil moisture, and the remaining soil moisture is more important than improving soil properties to resist short‐term droughts. As a result, SM is the most effective management practice when compared with PAM and GS, although they all protect the soil hydraulic properties during wet periods. These results suggest that mulching is the best strategy for water management in erosion‐threatened and drought‐threatened red soils. Copyright © 2014 John Wiley & Sons, Ltd.     

Seasonal variations in infiltrability of moss‐dominated biocrusts on aeolian sand and loess soil in the Chinese Loess Plateau

Biocrust effects on soil infiltration have attracted increasing attention in dryland ecosystems, but their seasonal variations in infiltrability have not yet been well understood. On the Chinese Loess Plateau, soil infiltrability indicated by saturated hydraulic conductivity (K_s) of biocrusts and bare soil, both on aeolian sand and loess soil, was determined by disc infiltrometer in late spring (SPR), midsummer (SUM), and early fall (FAL). Then their correlations with soil biological and physiochemical properties and water repellency index (RI) were analysed. The results showed that the biocrusts significantly decreased K_s both on sand during SPR, SUM, and FAL (by 43%, 66%, and 35%, respectively; P < .05) and on loess (by 42%, 92%, and 10%, respectively; P <.05). As compared with the bare soil, the decreased K_s in the biocrusted surfaces was mostly attributed to the microorganism biomass and also to the increasing content of fine particles and organic matter. Most importantly, both the biocrusts and bare soil exhibited significant (F ≥ 11.89, P ≤ .003) seasonal variations in K_s, but their patterns were quite different. Specifically, the K_s of bare soil gradually decreased from SPR to SUM (32% and 42% for sand and loess, respectively) and FAL (29% and 39%); the K_s of biocrusts also decreased from SPR to SUM (59% and 92%) but then increased in FAL (36% and 588%). Whereas the seasonal variations in K_s of the biocrusts were closely correlated with the seasonal variations in RI, the RI values were not high enough to point at hydrophobicity. Instead of that, the seasonal variations of K_s were principally explained by the changes in the crust biomass and possibly by the microbial exopolysaccharides. We conclude that the biocrusts significantly decreased soil infiltrability and exhibited a different seasonal variation pattern, which should be carefully considered in future analyses of hydropedological processes.     

Supraglacial weathering crust dynamics inferred from cryoconite hole hydrology

Water levels in cryoconite holes were monitored at high resolution over a 3‐week period on Austre Brøggerbreen (Svalbard). These data were combined with melt and energy balance modelling, providing insights into the evolution of the glacier's near‐surface hydrology and confirming that the hydrology of the near‐surface, porous ice known as the ‘weathering crust’ is dynamic and analogous to a shallow‐perched aquifer. A positive correlation between radiative forcing of melt and drainage efficiency was found within the weathering crust. This likely resulted from diurnal contraction and dilation of interstitial pore spaces driven by variations in radiative and turbulent fluxes in the surface energy balance, occasionally causing ‘sudden drainage events’. A linear decrease in water levels in cryoconite holes was also observed and attributed to cumulative increases in near‐surface ice porosity over the measurement period. The transport of particulate matter and microbes between cryoconite holes through the porous weathering crust is shown to be dependent upon weathering crust hydraulics and particle size. Cryoconite holes therefore yield an indication of the hydrological dynamics of the weathering crust and provide long‐term storage loci for cryoconite at the glacier surface. This study highlights the importance of the weathering crust as a crucial component of the hydrology, ecology and biogeochemistry of the glacier ecosystem and glacierized regions and demonstrates the utility of cryoconite holes as natural piezometers on glacier surfaces. Copyright © 2015 John Wiley & Sons, Ltd.