热水沉积岩及矿物岩石标志

热水沉积物不同于普通沉积物 ,主要与热水流体类型有关。文中把热水流体划分为中高温热水流体与中低温热水流体。中高温热水沉积岩包括钾长石岩、硅质岩、电气石岩、钠长石岩、萤石岩 ;中低温热水沉积岩包括碳酸盐、硫酸盐等岩石。钾长石岩是文中确定的一种标准高温热水沉积岩 ,热水沉积钾长石以冰长石和钡长石为主 ;热水沉积碳酸盐矿物一般为铁、镁、锰、钙碳酸盐 ,碳酸盐的形成与CO2 和H2 O的不混溶温度有关 ,一般在不混溶温度 ,即 2 66℃以下生成 ,或在海水补偿线以上形成。热水沉积岩中有热水交代蚀变岩夹层 ,尤其是在高温热水活动区 ,可以交代泥质、钙泥质沉积物形成热水交代沉积岩 ,包括方柱石黑云母岩、透辉石透闪石岩、夕卡岩、绿泥石岩等。根据对霍各乞铜多金属矿床的研究 ,热水交代透辉石透闪石岩的稀土总量较低 ,表现为轻稀土富集 ,重稀土亏损 ,稀土配分模式表现为正Eu异常     

桐庐杂岩体中共存的两种碱性长石研究

桐庐同熔型火山－侵入杂岩中出现两种碱性长石，一种为无色透明，另一种为微红色，本文利用X射线衍射仪，电子探针，透射电镜对其结构态，成分及出溶微结构进行了对比研究。结果表明，两者成分差别不大，而结构差别较大，无色透明的为透长石，出溶叶片发育；微红色的为正长石或低透长石，出溶结构不发育。而且随着冷却速率的变慢，无色透明碱性长石的Al/Si有序度增大，微红色碱性长石的有序度降低，分析后认为这种共存现象是岩浆混和造成的，从而为桐庐杂岩体的岩浆混合成因提供了有力的证据。     

pH值对长石溶解度及次生孔隙发育的影响

本文从长石溶解反应的机理及各离子形态在溶液中分布的热力学角度出发 ,论述了pH值对三个长石端员及高岭石在流体中溶解度的影响。在此基础上 ,进一步探讨了流体酸碱度对长石向高岭石转化和次生孔隙发育程度的制约 ,并提出了衡量次生孔隙发育程度的参数———转化系数D。     

遥感在新疆淖毛湖戈壁找矿中的应用

根据不同地质体在不同波段上的光谱特征，选择不同波段的TM数据进行假彩色合成，主成分分析，匹配滤波及多种处理方法，对淖毛湖戈壁琼河坝地区的线环构造特征，赋矿岩层，矿化蚀变等示矿要素进行增强处理和特征提取，取得较好效果，为在戈壁地区快速追踪找矿信息，指导成矿预测提供了重要的基本资料。     

Plagioclase dissolution related to biodegradation of oil in Brent Group sandstones (Middle Jurassic) of Gullfaks Field, northern North Sea

Brent Group sandstones from the north side of the Gullfaks Oilfield contain mostly 5–8% albitic plagioclase, whereas plagioclase is almost absent in the same strata in the southern part of the field. Absence of plagioclase throughout the entire vertical extent of the Brent Group in the southern wells seems to rule out provenance as the principal explanation for differing plagioclase content, which is therefore interpreted as the result of diagenesis. Hypotheses for the nature of the inferred leaching event include epigenetic meteoric diagenesis and mesogenetic release of acid components from clay minerals or kerogen, but these explanations are unable to account for the observed spatial distribution of the plagioclase-bearing and plagioclase-free sandstone intervals. However, overall correspondence between the area lacking plagioclase and oil compositions having both anomalously high CO₂ and organic geochemical indications of advanced biodegradation suggest a link between plagioclase dissolution and biodegradation of the present oil column. It is, therefore, proposed that acid components from biodegradation selectively reacted with albitic plagioclase to form kaolin, releasing sodium bicarbonate into the residual water. The plagioclase-free sandstones contain more kaolin than the plagioclase-bearing sandstones, as would be expected due to aluminium conservation. However, the wide and overlapping ranges of kaolin content in both groups suggest that most of the kaolin originated from processes other than biodegradation-driven plagioclase alteration, potentially including both epigenetic and mesogenetic dissolution, as well as deposition of detrital kaolin and kaolin precursors.     

Application of short-wave infrared spectroscopy to define alteration zones associated with the Elura zinc–lead–silver deposit, NSW, Australia

Short-wave infrared reflectance spectra obtained from a Portable Infrared Mineral Analyser (PIMA) have been used to define alteration zones adjacent to base metal sulfide ore bodies at the Elura Mine, Cobar, Australia. The spectroscopic work identified white mica (sericite), chlorite and carbonates of hydrothermal origin in the alteration zones associated with the ore bodies. Weathering, alteration and ore zones can be discriminated by variations in the intensity and wavelength of relevant absorption features. Hydrothermal alteration is classified into four principal types, namely sericitic, silicic, chloritic and carbonate alteration. The first three types comprise overprinting hydrothermal assemblages of quartz, sericite, chlorite, ankerite, siderite, calcite and sulfides developed in strongly altered metasiltstone and slate of Early Devonian age, adjacent to the zinc–lead–silver mineralisation. An extensive zone of carbonate alteration, manifested as porphyroblasts of siderite in the host metasediments, is recognised beyond the zones of strong alteration. Spectral analysis is consistent with the mineralogical data obtained from XRD and XRF analyses and defines the limits of the alteration zones to distances of about 80 m around the ore bodies. The study demonstrates the potential for spectral analysis to assist with drill hole logging and the identification of alteration zones as part of mineral exploration and development programs.     

新疆尉犁县蛭石矿床成因及矿床模式探讨

本文通过新疆尉犁县蛭石矿床的研究指出,与蛭石成矿密切相关的云母岩是碱性超基性岩经同源高温气液多次反复交代所形成之蚀变岩。并证实,在热液阶段,不能直接形成蛭石矿,只有在风化作用阶段,金(黑)云母经水化之后才铲最终成矿。在搞清成矿地质背景、成矿机制、成矿过程的基础上,确定该蛭石矿床成因类型为:与碱性超基性岩有关的气化—高温热液交代—风化壳型蛭石矿床,并初步构想了该蛭石矿床之成矿模式。     

赣北主要内生金矿床的形成条件

赣北地区的金矿床,可分为含金韧性剪切带型、硅化破碎带型、隐爆角砾岩型和微细粒浸染型等4个类型,其原始成矿物质来源于上地幔,通过火山喷发—沉积作用,形成含金沉积建造和含金火山岩建造.钠、钾质两个系列的花岗质岩石都可以形成金矿床.矿化富集主要通过韧、脆性变形和岩浆隐蔽爆破,产生多次破碎,多期蚀变矿化.在中—低温热液阶段,含矿热液体系的HS~-、Cl~-离子减少,还原介质增加的条件下沉淀富集,形成不同类型的金矿床.     

Geochemical Aspects of Hypogene Hydrothermal Alteration Zones in the Chol-qeshlaghi Area, NW Iran: Constrains on REEs

Chol-qeshlaghi altered area lies in the northwestern part of the post-collisional Urumieh-Dokhtar magmatic arc, NW Iran. Pervasive silicic, argillic, phyllic and propylitic altered zones appears to be intimately affiliated to the fluids derivative of upper Oligocene Khankandi granodiorite. This paper is dedicated to the identification of geochemical characteristics of hydrothermal alterations, focusing on the determination of the mass gains and losses of REEs, to gain significant insights regarding the chemical exchanges prevailed between the host rocks and hydrothermal fluids. The low pH and high activity of SO_4~(-2) ligands in silicic alteration fluids, resulting in depletion of entire REEs. Decreasing of LREEs appeared in argillic zone may attributed to reduce in adsorption ability of clay minerals in low pH; whereas HREEs enrichment in phyllic zone was inclined to put it down to the abundance of sericite(± Fe oxides). A significant reduction of Eu/Eu* ratio in silicic zone can be attributed to negligible sulfides and clay minerals as some effective agents in adsorption of released Eu~(+2). Factors such as changes in pH, the abundance of absorptive neomorph mineral phases, activity of ligands play an important role in controlling the distribution and concentration of REEs in Chol-qeshlaghi alteration system.