Surface complexation at hydrous fluorapatite

The adsorption of H⁺, OH^– and ARS (Alizarin Red S) onto hydrous fluorapatite surfaces and Ca²⁺—ARS complexation in solution were studied by means of combined potentiometric and spectrophotometric titrations, as well as zeta potential and FT-IR measurements. Corresponding equilibrium constants of surface and solution reactions are determined. The application in flotation processes is discussed.     

Dynamic stress concentration and scattering of SH-wave by interface elliptic cylindrical cavity

In this paper, the dynamic stress concentration and scattering of SH-waves by bi-naterial structures that possess an interface elliptic cavity are investigated. First, by using the complex function method, the Green‘s function is constructed. This yields the solution of the displacement field for an elastic half space with a semi-elliptic canyon impacted by an anti-plane harmonic line source loading on the horizontal surface. Then, the problem is divided into an upper and lower half space along the horizontal interface, regarded as a harmony model. In order to satisfythe integral continuity condition,the unknown anti-plane forces are applied to the interface. The integral equations with unknown forces can be established through the continuity condition, and after transformation, the algebraic equations are solved numerically. Finally, the distribution of the dynamic stress concentration factor (DSCF) around the elliptic cavity is given and the effect of different parameters on DSCF is discussed.     

La prévision du climat : de l'échelle saisonnière à l'échelle décennale

The atmosphere and the ocean are subject to many dynamical instabilities, which limit the time during which their behaviour can be deterministically forecasted. At longer timescales, the atmosphere can be predicted at best using statistical methods, as a response to external forcing linked to sea- and land-surface anomalies. Climate being defined as the mean of atmospheric states, it appears that it can be predicted up to a few months in advance, which is the characteristic time of the so-called slow components of the climate system. Forecasting can sometimes be extended to longer time ranges, especially when the coupled ocean–atmosphere system exhibits internal variability modes, with characteristic times of a few years. Seasonal climate forecasting is most often based upon Monte-Carlo simulations, where the various realisations correspond to slightly different initial conditions. The present sate-of-the-art in Europe (ECMWF) and/or in the USA (IRI) allows to forecast such major phenomena, as El Niño, up to six months in advance. Finally, some parameters may exhibit predictability at still longer time-ranges (inter-annual to decadal), but only for certain regions. The example of electricity production is used to underline the potentially large economical benefit of seasonal climate forecasting. To cite this article: J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.

Résumé

L'atmosphère et l'océan sont le siège d'instabilités dynamiques, qui limitent la durée pendant laquelle il est possible d'en prévoir l'évolution de façon déterministe. Au-delà, l'atmosphère n'est plus prévisible, au mieux, que de façon statistique, en fonction du forçage externe qu'exerce(nt) sur elle l'océan et/ou la surface des continents. Le climat (au sens d'une moyenne des états atmosphériques) se révèle ainsi prévisible jusqu'à des échéances temporelles de quelques mois, échelle de temps caractéristique des composantes dites « lentes » du système climatique. La prévision peut s'étendre à des échéances parfois plus longues, dans le cas où le système couplé océan–atmosphère posséderait des modes de variabilité temporelle de périodes caractéristiques de quelques années. La prévision climatique saisonnière est très souvent construite à partir de simulations de type Monte-Carlo, avec des ensembles de réalisations utilisant des conditions initiales légèrement différentes. Dans l'état actuel de ces prévisions, qu'elles soient réalisées en Europe (CEPMMT) ou aux États-Unis (IRI), il est possible de prévoir environ six mois à l'avance un certain nombre de phénomènes climatiques, en particulier ceux liés aux épisodes dits « El Niño », pour lesquels l'amplitude des variations est suffisamment importante. Il existe, par ailleurs, une prévisibilité à encore plus longue échéance (inter-annuelle à décennale), mais seulement pour certains paramètres et certaines régions. L'exemple de la production d'électricité montre l'importance économique potentielle très grande de la prévision climatique saisonnière. Pour citer cet article : J.-C. André et al., C. R. Geoscience 334 (2002) 1115–1127.     

Une dépression piézométrique naturelle en hausse au Sahel (Sud-Ouest du Niger)A rising piezometric depression in the Sahel (southwestern Niger)

In southwest Niger, the Continental Terminal water table displays a natural hollow shape about 10 m in depth over an area of 4000 km². A 10-year survey of this hollow aquifer has shown that current recharge is above $\text{20 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. The water table has risen continuously since the 1950–1960s as a result of land clearance. This shows a disequilibrium in the aquifer balance. The long-term recharge rate is estimated by radioisotopes to be around $\text{1 }\text{mm}\text{yr}{}^{\mathrm{?1}}$. This figure fits with the only possible origin of the piezometric depression, i.e. evapotranspiration losses in its centre. To cite this article: G. Favreau et al., C. R. Geoscience 334 (2002) 395–401.     

Analytical solutions for water flow passing over a vegetal area

This study is aimed at investigating the vertical velocity profile of flow passing over a vegetal area by an analytical approach. The soil ground is considered as pervious and thus non-zero velocity at the ground surface can be estimated. The soil and vegetation layers are regarded as homogeneous and isotropic porous media. Therefore the solution of the flow can be obtained by applying the theory of turbulent flow and Biot’s theory of poroelasticity after dividing the flow field into three layers: homogenous water, vegetation and pervious soil. The velocity distribution is compared with the experimental data of [Rowiński PM, Kubrak J. A mixing-length model for predicting vertical velocity distribution on flows through emergent vegetation. J Hydrol Sci 2002;47(6):893–904] to show its validity. In addition, five dimensionless parameters denoting the variation of slope, permeability of soil, Reynolds stress, density of vegetation, and relative height of vegetation are proposed to reveal their effects on the surface water flow. The analytical solutions of flow velocity can also be simplified into simpler expressions to describe the flow passing over a non-vegetated area.     

Research on Autonomous Orbit Determination of Navigation Satellite Based on Crosslink Range and Orientation Parameters Constraining

Introduction Thepotentialvulnerabilityofsatellitenaviga tionsystemthatreliesongroundstationsisthat thesystemwouldbreakdownifgroundstations weredestroyed,whichcannotmeettherequire mentofnavigationwarfare[1].Withthedevelop mentofsuchspace basedsystemsasgrou…     

Seismic quantification of the explosions that destroyed the dome of Volcán de Colima, Mexico, in July–August 2003

In July–August 2003, the andesitic lava dome at Volcán de Colima, México, was destroyed by a sequence of explosions that replaced the 2×10⁶ m³ dome with a crater 200 m across and 30 m deep. The two strongest explosions occurred on July 17 and August 28. The initial low-frequency impulses that they produced, which were recorded on broadband seismic records, allowed an estimation of the counter forces of the initiating process as being equal to 0.3×10¹¹ N and 1×10¹¹ N for the July and August events, respectively. The seismic characteristics follow the Nishimura-Hamaguchi scaling law for volcanic explosions, reflecting self-similarity in the processes initiating explosive events. The results also show that counter forces can discriminate between the sizes of explosive eruptions that are assigned the same magnitude by conventional methods of classification such as the Volcanic Explosivity Index. The increasing use of broadband seismometers may therefore provide the basis for using counter forces to determine the magnitude of explosive eruptions.     

Axial poloidal electromagnetic core-mantle coupling torque: A re-examination for different conductivity and satellite supported geomagnetic field models

We investigate the temporal behaviour of the axial component of the electromagnetic core-mantle coupling torque that is associated with the poloidal part of the geomagnetic field observable at the Earth surface. For its computation, we use different models of the geomagnetic field, expanded into spherical harmonics (Wardinski and Holme, 2006; Sabaka et al., 2004), and the mantle conductivity. The geomagnetic field, which we have to know at the core-mantle boundary for the associated computations, will be inferred from the field at the Earth surface by the non-harmonic field continuation through a conducting mantle shell. The aims of this investigation are (i) to check how sensitive is the computation of the torque with respect to the different geomagnetic field models, (ii) to check its dependence on the spherical harmonic degree n, and (iii) to determine the difference between the mechanical torque derived from the observed length-of-day variations (atmospheric influence subtracted) and the poloidal electromagnetic torque in dependence on the assumed conductivity. To use the non-harmonic field continuation for the torque calculation and to obtain an insight into the influence of the different geomagnetic field models on the EM torques are the major aspects of this paper. grm@gfz-potsdam.de     

Pits,rifts and slumps: the summit structure of Piton de la Fournaise

A clear model of structures and associated stress fields of a volcano can provide a framework in which to study and monitor activity. We propose a volcano-tectonic model for the dynamics of the summit of Piton de la Fournaise (La Reunion Island, Indian Ocean). The summit contains two main pit crater structures (Dolomieu and Bory), two active rift zones, and a slumping eastern sector, all of which contribute to the actual fracture system. Dolomieu has developed over 100 years by sudden large collapse events and subsequent smaller drops that include terrace formation. Small intra-pit collapse scars and eruptive fissures are located along the southern floor of Dolomieu. The western pit wall of Dolomieu has a superficial inward dipping normal fault boundary connected to a deeper ring fault system. Outside Dolomieu, an oval extension zone containing sub-parallel pit-related fractures extends to a maximum distance of 225 m from the pit. At the summit the main trend for eruptive fissures is N80°, normal to the north–south rift zone. The terraced structure of Dolomieu has been reproduced by analogue models with a roof to width ratio of approximately 1, suggesting an original magma chamber depth of about 1 km. Such a chamber may continue to act as a storage location today. The east flank has a convex–concave profile and is bounded by strike-slip fractures that define a gravity slump. This zone is bound to the north by strike-slip fractures that may delineate a shear zone. The southern reciprocal shear zone is probably marked by an alignment of large scoria cones and is hidden by recent aa lavas. The slump head intersects Dolomieu pit and may slide on a hydrothermally altered layer known to be located at a depth of around 300 m. Our model has the summit activity controlled by the pit crater collapse structure, not the rifts. The rifts become important on the mid-flanks of the cone, away from pit-related fractures. On the east flank the superficial structures are controlled by the slump. We suggest that during pit subsidence intra-pit eruptions may occur. During tumescence, however, the pit system may become blocked and a flank eruption is more likely. Intrusions along the rift may cause deformation that subsequently increases the slump’s potential to deform. Conversely, slumping may influence the east flank stress distribution and locally control intrusion direction. These predictions can be tested with monitoring data to validate the model and, eventually, improve monitoring.     

Spatio-temporal changes in the abundance of the populations of the gastrotrich community in a shallow lake of tropical Africa

Studies on the biodiversity and population dynamics of freshwater planktonic Gastrotricha have been carried out in conjunction with a physical–chemical analysis of the water in the Yaounde Municipal Lake (Cameroon, Central Africa) over a 14 months period (November 1996–December 1997). The results obtained allow to consider the Yaounde Municipal Lake as an eutrophic lake. It harbours eight species of Gastrotricha belonging to four genera (Chaetonotus, Dasydytes, Neogossea and Polymerurus) of the order Chaetonotida. This community was characterized by high abundances of populations, and was dominated by the genus Neogossea and Chaetonotusreaching up to 2000 ind. L⁻¹. Polymerurus was mostly abundant at the almost anoxic bottom layers. The highest abundances were found mostly during the rainy season, when there is an important sedimentation process of organic matter, and were influenced by several different environmental factors such as dissolved oxygen, temperature and pH of the water.

Finally this community which may play an important role in the water bodies, is a potential water quality indicator.