Dissolved trace elements and heavy metals in the Danjiangkou Reservoir,China

Concentrations of trace elements and heavy metals (Al, As, Ba, Cd, Co, Cr, Cu, Fe, Hg, Mn, Ni, Pb, Sb, Se, Sr, V and Zn) in the Danjiangkou Reservoir, the water source area of the Middle Route of China’s interbasin South to North Water Transfer Project, were analyzed using an Inductively Coupled Plasma Atomic Emission Spectrometer (ICP-AES) and compared with the national and international standards for drinking water. The results indicated that concentrations of As, Pb, Sb and Se in the Reservoir exceeded the standards and they would pose health risk for residents in the region and the water receiving areas of the interbasin water transfer project. Spatial and temporal variability of the trace elements and heavy metals in the Reservoir implies their mixed sources of natural processing and anthropogenic activities in the upper drainage of the Reservoir. The research results would help develop water resource management and conservation strategy for the interbasin water transfer project.     

Raman spectroscopic study of K-lingunite at various pressures and temperatures

K-lingunite is a high-pressure modification of K-feldspar that possesses the tetragonal hollandite structure. Variations of the Raman spectra of K-lingunite were studied up to ~31.5 GPa at room temperature, and in the range 79–823 K at atmospheric pressure. The Raman frequencies of all bands were observed to increase with increasing pressure, and decrease with increasing temperature for K-lingunite. This behavior is in line with those observed for most of other materials. New sharp Raman bands appear at pressures greater than 13–15 GPa, suggesting a phase transition in K-lingunite with increasing pressure. The transition is reversible when pressure was released. The appearance of these new Raman bands may correspond to the phase transition revealed earlier at around 20 GPa by X-ray diffraction studies. Instead of transforming back to its stable minerals, such as orthoclase, microcline or sanidine, K-lingunite became amorphous in the temperature range 803–823 K at atmospheric pressure.     

长沙黄花国际机场水源地的水文地质条件

长（沙）－平（江）白垩系红层盆地，公认为贫水地区。我院在机场附近找到了单井日产水量〉５３００ｍ＾３的优质地下水，一举解决了长沙黄花国际机场的供水问题。这项勘察成果，不仅解决了机场的水源地，而且对长－平红层盆地的水文地质研究、勘查和找水建井等，均具有现实意义。     

Metamorphic evolution of garnet-bearing ultramafic rocks from the Gongen area, Sanbagawa belt, Japan

Garnet‐bearing ultramafic rocks including clinopyroxenite, wehrlite and websterite locally crop out in the Higashi‐akaishi peridotite of the Besshi region in the Cretaceous Sanbagawa metamorphic belt. These rock types occur within dunite as lenses, boudins or layers with a thickness ranging from a few centimetres to 1 metre. The wide and systematic variation of bulk‐rock composition and the overall layered structure imply that the ultramafic complex originated as a cumulate sequence. Garnet and other major silicates contain rare inclusions of edenitic amphibole, chlorite and magnetite, implying equilibrium at relatively low P–T conditions during prograde metamorphism. Orthopyroxene coexisting with garnet shows bell‐shaped Al zoning with a continuous decrease of Al from the core towards the rim, consistent with rims recording peak metamorphic conditions. Estimated P–T conditions using core and rim compositions of orthopyroxene are 1.5–2.4 GPa/700–800 °C and 2.9–3.8 GPa/700–810 °C, respectively, implying a high P/T gradient (> 3.1 GPa/100 °C) during prograde metamorphism. The presence of relatively low P–T conditions at an early stage of metamorphism and the steep P/T gradient together trace a concave upwards P–T path that shows increasing P/T with higher T, similar to P–T paths reported from other UHP metamorphic terranes. These results suggest either (1) down dragging of hydrated mantle cumulate parallel to the slab–wedge interface in the subduction zone by mechanical coupling with the subducting slab or (2) ocean floor metamorphism and/or serpentinization at early stage of subduction of oceanic lithosphere and ensuing HP–UHP prograde metamorphism.     

中国大陆科学钻探主孔自然放射性测井及其解释

为了认识江苏东海超高压变质带上地壳岩石自然放射性的垂向分布特征, 榴辉岩退变质程度对放射性元素浓度的影响, 以及放射性产热率对地温梯度的影响, 利用中国大陆科学钻探(CCSD) 主孔100~5000m自然放射性测井(自然伽马和自然伽马能谱) 资料统计了CCSD主孔各类岩石的自然放射性强度和铀、钍、钾元素的浓度, 计算出产热率曲线.自然伽马, 铀、钍、钾浓度和产热率从蛇纹岩到榴辉岩、角闪岩、副片麻岩、正片麻岩依次增大.随着榴辉岩退变质程度的增强, 其铀、钍、钾元素的浓度值逐渐增大.CCSD主孔自然放射性的垂向分布特征主要受岩性控制, 自然放射性随深度增加有增强趋势.产热率与自然伽马测井值之间有很好的线性关系, 在高放射性岩层的上部, 地温梯度会出现较强扰动和低值异常.      

高温高压岩石流变仪的围压标定方法

高温高压岩石流变仪围压标定的主要方法为氯化盐类的部分熔融法和矿物相变法。利用氯化盐类进行压力标定时,不仅可以利用单一盐类,也可以使用多种盐类的混合物;常用的压力标定矿物相变及其适用温压范围如下:石英-柯石英,500~1200℃、2.5~3.2GPa;钠长石-硬玉+石英,600~1200℃、1.6~3.2GPa;铁橄榄石+石英-铁辉石,600~1200℃、1~1.7GPa;磷镁石-Mg3(PO4)2-Ⅱ,565~825℃、0.6~0.9GPa;方解石-文石,600~1200℃、0.5~2.5GPa。不同的标定方法具有不同的特征,文中将进行详细介绍。     

从地温场特征探讨兰州断陷盆地地热资源前景

根据祁连造山带东段地温梯度、大地热流场、温泉和地热异常孔空间分布 ,以华家岭—武山近SN向隐伏深断裂为界 ,东边地温场高、温泉多 ,为隆起断裂型中低温地热田 ,其西地温场低于东部 ,地热异常孔为沉降盆地型地热异常指示 ,可为地热田开发提供信息特征。并对兰州断陷盆地的地热资源前景和开发前期工程进行探讨。     

沉水植物黑藻对上覆水中各形态磷浓度的影响

室内模拟研究了沉水植物黑藻对上覆水中不同形态磷浓度的影响及其季节性变化,并从沉水植物生长、间隙水和碱性磷酸酶活性(APA)三方面进行了讨论,进一步揭示磷在浅水湖泊水-沉积物界面的交换机理。结果表明,在本研究条件下,上覆水中各形态磷以溶解性总磷(DTP)为主,其他形态磷浓度变异较大,黑藻降低了上覆水中总磷(TP)、溶解性活性磷(SRP)和DTP浓度,也降低了DTP和SRP占总磷的比例,从而使颗粒态总磷(PP)和溶解性有机磷(DOP)占总磷比例升高。黑藻主要通过吸收上覆水中的磷和抑止沉积物、上覆水中APA使上覆水中各形态磷浓度保持较低水平,其中对SRP和DTP浓度的影响更明显。上覆水中各形态磷浓度呈现明显的季节性变化。在7～8月,TP、SRP和DTP浓度呈下降趋势,并在8月达到最低值;9～10月间有所升高,但仍然维持在较低水平,不同采样时间存在波动。     

Relationship between the variation of water quality in rivers and the characteristics of watershed at Miyun,Beijing, China

Based on the characteristics of land use and drainage network of the upper watershed of the Miyun Res-ervoir, Beijing, 26 monitoring and sampling sites were selected in different sub-catchments. Temporal and spatial variations in nutrient loss were dealt with in this paper in terms of the monitoring data on the water quality of the main tributaries flowing into the Miyun Reservoir. In combination with the monitoring data on water quality, the impacts of watershed characteristics including land-use type, landscape pattern, and drainage density were assessed, The concentrations of nutrients in the rainy season are higher than those in other seasons, and the concentrations of NO3--N are linearly related to those of total N which is the main form of nitrogen present in the fiver water. The concentrations of nitrogen become higher toward the reservoir along the main rivers. The seasonal variation of ni-trogen in the watershed affected by intensive human activities is very obvious; in the watershed with steady or low water flow, the seasonal variation of nitrogen is less obvious. Forest land and grassland can trap and filter nitrogen effectively. Land-use pattern also has important impacts on the loss of nitrogen. The concentrations of nitrogen and phosphorus in the water bodies show great temporal and spatial variations. On a temporal scale, the concentrations of TN and TP in the rainy reason are higher than those in other seasons. On a spatial scale, the concentrations of TN and NO3--N in the Qingshui River and Chaohe River are highest all the time. The spatial variation of TP is distinct, being obvious at sampling sites near villages. The form of nitrogen and phosphorus loss varies in different hydrological seasons. Dissolved nitrogen and phosphorus are the main forms in streams in non-rainy seasons, the dissolved nitro-gen and total nitrogen decrease in percentage in the rainy season. Particulate nitrogen and phosphorus are the main forms in some rivers. The concentrations of TN and NO3--N from orchards and villages are high whereas those from forest land are lowest. Land-use pattern has impacts on TN and NO3--N losses, at the sampling sites near the source landscape, the concentrations are higher than those at the sampling sites near the sink landscape. Water quality of the rivers which flow into the Miyuan Reservior is influenced by the composition of adjacent soils.     

两城水源地喀斯特水资源评价

两城水源地具有较丰富的喀斯特水，根据长期观测资料，充分考虑水资源的各种补给和开采条件，应用水均衡原理，对其水资源量进行定量评价，获得允许可开采量，为工农业供水提供可靠依据。