甲醛对Nessler法和次氯酸酚盐法测定养殖水体总氨氮的影响

水体中含一定浓度的甲醛 ,用 Nessler法测得的总氨氮 (TAN)浓度远远高于实际浓度 ,差异百分数最高达 4 5 0 .0 6 % ;用次氯酸酚盐法测得的总氨氮 (TAN)浓度则明显低于实际浓度 ,差异百分数最高可达 84 .77%。甲醛浓度范围为 10～ 4 0 mg/ L、TAN浓度为 1～ 10 mg/ L,通过双因素有重复观察值的交叉实验 ,得到如下矫正式 :(1)用 Nessler法测 TAN时 ,Y=4 .0 5 2 9- 0 .0 72 4 x1+ 0 .2 0 6 4x2 ,标准误差为 1.3381;(2 )用次氯酸酚盐法测 TAN时 ,Y=0 .1196 + 0 .0 345 x1+ 1.0 0 2 2 x2 ,标准误差为 0 .4 6 2 7。 Y为 TAN实际浓度 (mg/ L) ,x1为甲醛浓度 (mg/ L) ,x2 为测得的 TAN浓度(mg/ L )。比较含氨氮水体与不含氨氮水体中的甲醛浓度 ,方差分析结果表明 ,没有显著差异。     

环境演变研究时间序列的建立方法评述

对环境演变时间序列建立的几种主要方法的纪年原理、应用状况及应用的优点、范围、局限性进行了阐述和比较，包括长寿命宇宙成因核素在内的同位素纪年方法主要判别第四纪以来大时间尺主的沉积物的地质年龄，且能很好地应用于全球变化的研究，但百余年来沉积物的年龄及侵蚀历史变化的研究只能通过^210Pbex、^137Cs等半衰期相对较短的核素来进行；指出^210Pbex可望在现代流域侵蚀环境演变以及其效应评价的研究中获得新的突破。     

Correction method for full-depth current velocity with lowered acoustic Doppler current profiler (LADCP)

A new method is presented to process and correct full-depth current velocity data obtained from a lowered acoustic Doppler current profiler (LADCP). The analysis shows that, except near the surface, the echo intensity of a reflected sound pulse is closely correlated with the magnitude of the difference in vertical shear of velocity between downcast and upcast, indicating an error in velocity shear. The present method features the use of echo intensity for the correction of velocity shear. The correction values are determined as to fit LADCP velocity to shipboard ADCP (SADCP) and LADCP bottom-tracked velocities. The method is as follows. Initially, a profile of velocity relative to the sea surface is obtained by integrating vertical shears of velocity after low-quality data are rejected. Second, the relative velocity is fitted to the velocity at 100–800 dbar measured by SADCP to obtain an “absolute” velocity profile. Third, the velocity shear is corrected using the relationship between the errors in velocity shears and echo intensity, in order to adjust the velocity at sea bottom to the bottom-tracked velocity measured by LADCP. Finally, the velocity profile is obtained from the SADCP-fitted velocity at depths less than 800 dbar and the corrected velocity shear at depths greater than 800 dbar. This method is valid for a full-depth LADCP cast throughout which the echo intensity is relatively high (greater than 75 dB in the present analysis). Although the processed velocity may include errors of 1–2 cm s⁻¹, this method produced qualitatively good current structures in the Northeast Pacific Basin that were consistent with the deep current structures inferred from silicate distribution, and the averaged velocities were significantly different from those calculated by the Visbeck (2002) method.     

金属电极在含油模拟海水中电化学行为的研究

采用电化学阻抗和恒电位阶跃技术研究了金属铂和镍电极在含油氯化钠溶液中的电化学行为特征,测量了不同含油量体系中电化学信号的变化,并建立了相应的等效电路.实验结果表明,同样条件下多孔电极比平面电极的电化学信号响应显著,泡沫镍电极与铂黑电极相比对含油量的响应则更为明显.     

无居民海岛开发适宜性评价指标体系的构建和在厦门海域的应用

无居民海岛开发适宜程度取决于对其生态重要性与开发可行性的综合评价.本研究从表征生态重要性的物种、生境和自然历史文化遗迹,以及反映开发可行性的自然、资源和社会经济条件构建无居民海岛开发适宜性评价指标体系;采用专家咨询法和层次分析法确定指标权重,在评价指标量化与标准化处理的基础上,建立生态重要性-开发可行性互斥矩阵确定无居民海岛的开发适宜程度.对厦门海域的实际应用研究结果表明,其18个无居民海岛的开发适宜性总体偏低,中度适宜开发的海岛共有7个,低适宜开发的海岛有8个,不适宜开发的海岛有3个,评价结果与国家海洋局2011年发布的可供开发利用无居民海岛名录中厦门海域部分基本吻合.作者建议对厦门海域中度适宜开发的无居民海岛可据其资源特征进行适度开发;对低适宜开发的无居民海岛应优先保护海岛生态,维护海岛自然属性;对不适宜开发的无居民海岛应重点加强海岛生态保护,必要时进行生境的重建和修复.     

西北冰洋表层沉积物中重金属的赋存形态研究

用连续提取法对选自西北冰洋的32个表层沉积物进行分析,测定了Cr、Cu、Pb在全样中及其在P1-2、P3、P4、P5中的含量.结果表明随着离岸距离增加,水深加深,Cr、Cu、Pb含量呈增高的趋势.研究区陆架沉积物中Cr、Cu、Pb含量分别为60.66、14.77、16.65μg/g;深海沉积物中Cr、Cu、Pb的含量分别为80.40、41.70、25.62μg/g.元素赋存形态分析表明,Cr、Cu、Pb主要赋存在残渣态,残渣态中三元素的含量平均值分别为64.97、19.67、17.56μg/g,占元素总量的比例分别为93.58%、75.02%和83.76%.三元素在各赋存形态中的含量分布是:Cu为残渣态>有机质和硫化物态>铁锰氧化态>可交换及碳酸盐态;Pb和Cr则为残渣态>铁锰氧化物态>有机质硫化物态>可交换态及碳酸盐态.研究区重金属元素在不同赋存形态中的含量分布与北太平洋深海沉积物中类似.     

杭州湾中部实测波浪特性分析

利用杭州湾中部一年实测波浪资料,分析该地区的波参数统计变化特性,采用最小二乘法拟合得出相关参数之间的关系式,并统计分析了频谱特性。结果表明:杭州湾中部以小浪和轻浪为主,在各月分布较为均匀,年平均周期为2.97 s;最大一次波浪过程为冷空气影响所致,影响强度大于台风莫拉克;常浪向分布在东北至东南向,其中又以小浪出现较多,对应的波周期以2~4 s为主;强浪向主要分布在西北和东北方向,对应的波周期主要分布在3~5 s;多数特征波参数之间相关关系较好;由谱分析得知风浪占多数,且以单峰为主。研究结果可为相关工程和理论研究提供基础资料。     

用于海洋环境科学的一种新方法--影响因子分析法

用影响因子法对象山港海域叶绿素a与海水理化因子之间关系分析,结果表明：水温、溶解氧(DO)、气温、盐度、化学耗氧量(COD)因子为叶绿素a浓度变化的重要有效影响因子,其中水温、溶解氧因子占主导地位。由于该海域的富营养化,N、P和Si营养盐已经不再是影响浮游植物生长的有效因子。在特定海域资料有限的情况下,影响因子法比普通的相关和灰色系统分析更具有透明性,能够有效剔除无效因子,定量表达各理化因子对叶绿素a的影响程度。用影响因子法可以明确地判断出特定海域各海水理化因子对叶绿素a影响的主次程度及其有效性,从而定量确定出影响叶绿素a浓度的主要因子。     

Numerical simulation of random wave slamming on structures in the splash zone

The numerical investigation of random wave slamming on superstructures of marine structures in the splash zone is presented in this paper. The impact pressures on the underside of the structure are computed based on the improved volume of fluid method (VOF). The governing equations are Reynolds time-averaged equations and the two equation k– model. The third order upwind difference scheme is applied to the convection term to reduce the effect of numerical viscosity. The numerical wave flume with random wave-maker suitable for VOF is established. Appropriate moving contact-line boundary conditions are introduced to the model wave in contact with and separated from the underside of structure. Parametric studies have been carried out for different incident waves, structure dimensions and structure clearance. The numerical results are verified by the experimental results.