水平荷载下导管架平台桩基础的非线性有限元分析

导管架平台桩基础的控制荷载主要为风荷载、波浪荷载、地震荷载等水平荷载,为研究水平荷载下导管架平台桩基础的承载特性,采用非线性有限元分析方法对水平荷载下桩-土之间的相互作用进行研究,提出了有效模拟桩基水平承载特性的有限元模型,分析了模型桩的刚度、直径、土质参数中水平土压力系数、剪胀角对桩基承载特性的影响及水平荷载下群桩承载特性,并将有限元计算结果与API规范及模型试验结果进行对比。研究结果表明,非线性有限元分析方法分析水平荷载下桩-土相互作用是可行的,计算结果可为导管架平台的桩基设计提供参考。     

河北某斑岩型钼矿提高选矿指标试验研究

河北省某钼矿为单一斑岩型钼矿,主要金属矿物为辉钼矿。为了进一步提高钼精矿的品位和回收率,试验采用混合捕收剂(煤油∶2号油=2∶1)和新型捕收剂PE-100相结合的方法,粗选时可使粗精矿的回收率提高2个百分点,品位也略有提高。为节约生产成本,试验采用阶段磨矿阶段选别的选矿工艺,即原矿磨矿(-0.074mm占60%)后,经一次粗选,一次扫选,粗精矿再磨(-0.038mm占85%)后再进行5次精选,最终获得钼精矿品位w(Mo)=50.007%,回收率为89.90%的较好指标。     

注入CO2提高煤层气产能的可行性研究

根据煤储层吸附一解吸机理,首次采用“解吸一注气一解吸”的实验方法,分别进行CH4,CO2的吸附一解吸和CO2注入置换煤层CH4实验,模拟了煤层气井“排采一注气一排采”的增产途径和效果。结果表明：在CH4和CO2二元体系的竞争吸附中,CO2组分的吸附速率是先快后慢,而CH4组分的吸附速率先慢后快,解吸时则相反,反映出CO2在竞争吸附中占据优势;注入CO2气体的数量越大和相对浓度越高,单位压降CH4解吸率和CO2吸附率就越高。实验结论对工业规模的煤层气开发试验具有指导意义。     

Gold recovery from a refractory pyrrhotite ore by biooxidation

The aim of the present investigation was to study the biooxidation of a refractory gold-bearing pyrrhotite, in order to increase the gold recovery during the subsequent conventional cyanidation.Bacterial cultures utilised in the biological test consisted predominantly of Thiobacillus genus. Tests were conducted at laboratory scale. The gold content of the ore sample, coming from Bolivia, was of 10 g t⁻¹ Au.After 24 h leaching time by direct cyanidation, low gold recovery was obtained (<20% Au), with a high reagent consumption. On the other hand, a high gold recovery was achieved for the biooxidated samples: after 24 h cyanidation gold dissolution reached about 91% Au.Experimental results have shown the technical feasibility of the biooxidative pretreatment prior to conventional leaching and a complete circuit of treatment, on laboratory scale, has been developed considering also the subsequent gold recovery by carbon adsorption/desorption and electrowinning.A gold extraction yield of about 86% was determined in the whole process for gold extraction from pyrrhotite (biooxidation, solid–liquid separation, cyanidation, adsorption, desorption, electrowinning).     

Simulation of groundwater level recovery in abandoned mines,Fengfeng coalfield,China

Abandoned mines are of high potential risk as they could be a large underground storage of pollutants(heavy metals and organic wastes, etc.). Various physical, chemical and biological reactions would take place when groundwater flows into underground spaces, which makes abandoned mine a huge potential hazard to groundwater environment. The recovery of groundwater level is one of the key elements controlling the reactions and causing such hazards. This paper simulated groundwater level recovery processes in the abandoned mines, Fengfeng coalfield by using the computer program FEFLOW. The paper integrated the pipe flow model, "three zones" model and groundwater inrush(discharge) model in the simulation of groundwater in the complex laneway-aquifer system. Groundwater flow in the laneway systems was considered pipe flow and described in Bernoulli equation. The water-bearing medium(coal seam roof) overlying the laneway systems was divided into "three zones" composed of the caving zone, fissure zone and bending zone based on the disruption degrees of previous mining. Groundwater in the Ordovician limestone aquifer(bottom of coal seam) flowing into laneway systems was considered a major inrush/recharge source, and its flow rate was calculated by an inrush(discharge) model which was newly developed in this study and incorporated into FEFLOW. The results showed that it would take approximately 95 days for groundwater in abandoned mines to recover to regional groundwater level elevation, and the total amount of water filling up would be about 1.41195×10~7 m~3, which is consistent with the actual data. The study could be of theoretical and practical significance to mitigate abandoned mines' hazards and improve mine groundwater utilization.     

Isothermal annealing of partially metamict zircon: evidence for a three-stage recovery process

 Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict zircons (2.6 and 4.8 × 10¹⁸ α-decays g⁻¹) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages, each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized (recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures, where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize. The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 10¹⁸ α-decays g⁻¹), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation under ambient temperatures. Received: 6 September 2001 / Accepted: 25 February 2002     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

无隔水管泥浆回收钻井技术控制系统功能设计

无隔水管泥浆回收钻井技术（RMR）作为双梯度钻井工艺之一,具有绿色环保、井身结构简易、工程成本低和安全程度高等优点。但是RMR作为新兴钻井工艺,虽然国外应用较为成熟,但国内目前尚无工程应用,缺乏相关使用经验。最关键的是RMR控制系统功能复杂,对可靠性、准确性及灵敏性等要求高,面对复杂工况时,要求控制系统能够及时准确的做出应对处理。因此,为发展国内无隔水管泥浆回收钻井技术（RMR）,拉近甚至超越国外钻井工艺水平,迫切需要对控制系统做出相对完善的设计。本文针对无隔水管泥浆回收钻井过程中的几类典型工况,分析不同工况下控制系统所具备的功能,设计控制功能具体的实现形式。通过对无隔水管泥浆回收钻井技术控制系统的功能设计与实现的研究,以期为今后同类研究提供有益的借鉴。     

汶川地震灾后农田和森林植被恢复遥感监测

2008年汶川8.0级特大地震对当地的生态系统造成了极大的破坏,为了评估5年来灾区农田和森林植被的恢复情况,利用逐年机载高分辨率遥感影像,结合星载遥感数据和地面调查数据,开展了灾区农林植被恢复状况监测。在农田恢复监测方面,结合2008年地震发生后以及2013年5月中旬的机载高分辨率遥感数据,采用目视解译的方式对汶川地震中受损农田的恢复状况进行监测与评估,同时利用GVG(GPS、Video和GIS)农情采样系统的作物种植成数调查结果,分析了灾后作物种植结构的变化。结果表明,灾区1592 ha受损农田,5年后仅有约17.5%得到了恢复和耕种使用。就耕地利用强度而言,重灾区耕地利用率较高,作物种植结构没有发生重大变化。在森林恢复状况监测方面,对典型区(岷江干旱河谷区和盆周山地区的3个重点区域)采用目视解译方式识别出森林变化,并结合大区域尺度规一化植被指数(NDVI)时间序列变化分析,对整个灾区的森林损毁和恢复情况做出评价。监测结果显示,汶川县、什邡市和绵竹市的森林植被恢复情况总体较好,但是一些坡度较大的损毁区、次生灾害频发区的森林尚未恢复,大区域尺度的统计结果显示,地震重灾区的46381 ha重度损毁森林植被和177025 ha中度损毁森林植被区域,完全恢复的区域占13.52%和25.84%,部分恢复的区域都占到50%。在自然恢复较为困难的区域,如汶川县中部和东北部、都江堰市北部、彭州市北部、什邡市北部、绵竹市北部、安县北部及北川县南部等,需要加强人工干预。遥感监测方法既适用于震后的农田和森林恢复状况动态监测,也适用于其他自然灾害发生时对灾区农田和森林植被破坏状况进行应急监测,具有实际应用价值和良好的发展前景。     

加标回收在水质分析中的应用及回收率计算方法

阐述了水质分析中加标回收分析的方法步骤、条件控制及计算方法。当加标体积影响试样在加标水样中的浓度时,直接使用回收率理论计算公式的计算值,均较其真实的回收率偏低,且其偏低值随加标体积的增加而增大。根据加标回收分析的定义,分别以加标前后被测组分质量浓度(mg/L)的变化或含量(μg)的变化为依据,导出两个计算加标回收率的实用公式。采用该公式,加标体积可以不受严格控制,其计算结果与真实的回收率一致,适用于日常水质分析工作。