大洋海区海-气CO_2通量单参数遥感算法的适用性检验

利用卫星遥感技术的优势,基于LDEO数据库的全球海表二氧化碳分压（PCO2）及海表温度（SST）等实测数据,初步建立东太平洋海区PCO2与SST的单参数经验算法,并采用相同区域的独立实测数据检验.结果表明,单参数算法在寡营养大洋海区具有良好的适用性,反演值与实测值之间的均方根误差（RMS）为0.51 Pa（1 Pa=9.869μatm）,由此估算出2003年6月该海域CO2通量为-1.4 mmol/（m2.d）,与实测估算的碳通量基本相符,能够很好地反映出海区CO2源汇特征.将该遥感算法运用到西大西洋海域（15°~25°N,60°~75°W）,反演值与实测值之间均方根误差（RMS）为0.69 Pa.检验结果表明,在寡营养大洋海区,单参数遥感算法具有一定的适用性,在受相似因子调控的同纬度海区可以使用同一遥感算法.     

欧氏六线鱼Hexagrammos otakii Jordan & Starks性腺发育的周年变化研究

根据对青岛附近水域欧氏六线鱼（已达性成熟年龄）性腺周年宏观和组织学观察，性腺发育可分为：①重复发育Ⅱ期；②开始成熟期；③接近成熟期；④临产期或产卵期；⑤产后期。按性腺指数变化并结合性腺组织切片确定，欧氏六线鱼性腺发育在青岛海区一年一个周期，繁殖期在１０月下旬至１２月，繁殖盛期是１１月下旬至１２月中旬。     

A preliminary study of carbon system in the East China Sea

In the central part of the East China Sea, the activity of CO₂ in the surface water and total carbonate, pH and alkalinity in the water column were determined in winter and autumn of 1993. The activity of CO₂ in the continental shelf water was about 50 ppm lower than that of surface air. This decrease corresponds to the absorption of about 40 gC/m²/yr of atmospheric CO₂ in the coastal zone or 1 GtC/yr in the global continental shelf, if this rate is applicable to entire coastal seas. The normalized total carbonate contents were higher in the water near the coast and near the bottom. This increase toward the bottom may be due to the organic matter deposited on the bottom. This conclusion is supported by the distribution of pH. The normalized alkalinity distribution also showed higher values in the near-coast water, but in the surface water, indicating the supply of bicarbonate from river water. The residence time of the East China Sea water, including the Yellow Sea water, has been calculated to be about 0.8 yr from the excess alkalinity and the alkalinity input. Using this residence time and the excess carbonate, we can estimate that the amount of dissolved carbonate transported from the coastal zone to the oceanic basin is about 70 gC/m²/yr or 2 GtC/yr/area-of-global-continental-shelf. This also means that the rivers transport carbon to the oceans at a rate of 30 gC/m²/yr of the coastal sea or 0.8 GtC/yr/ area-of-global shelf, the carbon consisting of dissolved inorganic carbonate and terrestrial organic carbon decomposed on the continental shelf.     

大西洋经向翻转环流对岁差响应的气候背景依赖性

大西洋经向翻转环流（Atlantic Meridional Overturning Circulation,AMOC）是气候系统重要的组成部分,其强度变化可直接影响南北半球的热量分配,厘清其变化机理对全球变暖背景下的未来预估至关重要。海洋沉积物记录发现,在晚更新世,AMOC的变化与地球岁差周期有紧密联系,但其物理机理尚不清楚。本文利用海洋−大气耦合气候模型—COSMOS（ECHAM5/JSBACH/MPIOM）模型,通过敏感试验,分析在冰盛期冷期和间冰期暖期气候背景下,AMOC对地球岁差变化的响应机理。结果表明：岁差降低引起的北半球夏季太阳辐射增强,会导致间冰期暖期背景下的AMOC显著减弱,但对冰盛期AMOC的影响并不明显。通过进一步分析发现,在间冰期暖期,夏季太阳辐射增强,造成高低纬大西洋海表的升温,同时促进北大西洋高纬度地区的局地降水,两者导致北大西洋表层海水密度降低,共同削弱大西洋深层水生成。而在冰盛期冷期,大西洋高低纬度地区的响应对AMOC的影响反向—副热带升温触发的海盆尺度低压异常,通过其南侧的西风异常削弱大西洋向太平洋的水汽输送,导致净降水增多,海表盐度下降;同时,高纬度升温造成的海冰减少,促进了海洋热丧失,海表失热变重,有利于大西洋深层水的生成,最终两者的共同作用导致AMOC对岁差变化的响应偏弱。本文系统揭示了不同气候背景下,岁差尺度AMOC变化的控制机理,对理解晚更新世AMOC重建记录中持续存在的岁差周期具有重要启示意义。     

微小卡罗藻溶血活性的生长期特征及其溶血毒素种类分析

研究微小卡罗藻的生长曲线及不同生长期藻细胞提取液和去藻上清液溶血活性的大小,通过乙酸乙酯和Bligh-Dyer两种方法提取溶血毒素,利用柱层析和薄层层析对溶血毒素成分进行初步的分离与分析。结果表明,藻细胞提取液在4个生长阶段中都具有明显的溶血活性,去藻上清液在平稳期和衰亡期具有明显的溶血活性,延滞期及对数生长期溶血活性很低,表明微小卡罗藻的溶血物质是其自身正常生理代谢产物,且在细胞老化过程中可以释放至水体环境中。两种提取方法都可以将溶血毒素提取出来,进一步的色谱分离和生物活性检测发现微小卡罗藻主要含有3种不同性质的溶血毒素,其溶血作用可能与微小卡罗藻较高含量的多不饱和脂肪酸18:5n3和22:6n3有关。     

Benthic nitrate biogeochemistry affected by tidal modulation of Submarine Groundwater Discharge (SGD) through a sandy beach face, Ria Formosa, Southwestern Iberia

To investigate both the role of tides on the timing and magnitude of Submarine Groundwater Discharge (SGD), and the effect on benthic nitrogen biogeochemistry of nitrate-enriched brackish water percolating upwards at the seepage face, we conducted a study of SGD rates measured simultaneously with seepage meters and mini-piezometers, combined with sets (n = 39) of high resolution in-situ porewater profiles describing NH₄⁺, NO₃⁻, Si(OH)₄ and salinity distribution with depth (0–20 cm). Sampling took place during two consecutive spring tidal cycles in four different months (November 2005, March, April and August 2006) at a backbarrier beach face in the Ria Formosa lagoon, southern Portugal. Our results show that the tide is one of the major agents controlling the timing and magnitude of SGD into the Ria Formosa. Intermittent pumping of brackish, nitrate-bearing water at the beach face through surface sediments changed both the magnitudes and depth distributions of porewater NH₄⁺ and NO₃⁻ concentrations. The most significant changes in nitrate and ammonium concentrations were observed in near-surface sediment horizons coinciding with increased fraction of N in benthic organic matter, as shown by the organic C:N ratio. On the basis of mass balance calculations executed on available benthic profiles, providing ratios of net Ammonium Production Rate (APR) to Nitrate Reduction Rate (NRR), coupled to stoichiometric calculations based on the composition of organic matter, potential pathways of nitrogen transformation were speculated upon. Although the seepage face occasionally contributes to reduce the groundwater-borne DIN loading of the lagoon, mass balance analysis suggests that a relatively high proportion of the SGD-borne nitrogen flowing into the lagoon may be enhanced by nitrification at the shallow (1–3 cm) subsurface and modulated by dissimilatory nitrate reduction to ammonium (DNRA).     

Interdecadal Variations of ENSO Signals and Annual Cycles Revealed by Wavelet Analysis

Interdecadal variations of El Niño/Southern Oscillation (ENSO) signals and annual cycles appearing in the sea surface temperature (SST) and zonal wind in the equatorial Pacific during 1950–1997 are studied by wavelet, empirical orthogonal function (EOF) and singular value decomposition (SVD) analyses. The typical timescale of ENSO is estimated to be about 40 months before the late 1970s and 48–52 months after that; the timescale increased by about 10 months. The spatial pattern of the ENSO signal appearing in SST also changed in the 1970s; before that, the area of strong signal spread over the extratropical regions, while it is confined near the equator after that. The center of the strongest signal shifted from the central and eastern equatorial Pacific to the South American coast at that time. These SST fluctuations near the equator are associated with fluctuations of zonal wiond, whose spatial pattern also shifted considerably eastward at that time. In the eastern equatorial Pacific, amplitudes of annual cycles of SST are weak in El Niño years and strong in La Niña years. This relation is not clear, however, in the 1980s and 1990s.     

Improved Method for Calculating Anthropogenic CO2 in the Upper Layer of the North Pacific Subtropical Gyre along 175°E

Seawater samples were collected in the North Pacific along 175°E during a cruise of the Northwest Pacific Carbon Cycle Study (NOPACCS) program in 1994. Many properties related to the carbonate system were analyzed. By using well-known ratios to correct for chemical changes in seawater, the CO₂ concentration at a given depth was back calculated to its initial concentration at the time when the water left the surface in winter. We estimated sea-surface CO₂ and titration alkalinity (TA) in present-day winter, from which we evaluated the degree of air-sea CO₂ disequilibrium in winter was. Using a correction factor for air-sea CO₂ disequilibrium in winter, we reconstructed sea-surface CO₂ in pre-industrial times. The difference between the back-calculated initial CO₂ and sea-surface CO₂ in pre-industrial times should correspond to anthropgenic CO₂ input. Although the mixing of different water masses may cause systematic error in the calculation, we found that the nonlinear effect induced by the mixing of different water masses was negligible in the upper layer of the North Pacific subtropical gyre along 175°E. The results of our improved method of assessing the distribution of anthropogenic CO₂ in that region show marked differences from those obtained using the previous back-calculation method.     

Reproductive biology of Parazoanthus axinellae (Schmidt, 1862) and Savalia savaglia (Bertoloni, 1819) (Cnidaria,Zoantharia) from the NW Mediterranean coast

Despite the wide distribution of zoanthids, little is known about their pattern of reproduction. Here we investigate the reproductive biology of two Mediterranean species, the common Parazoanthus axinellae (Schmidt) and the rare Savalia savaglia (Bertoloni). For both species, samples were collected during an annual cycle, from January to December 2005, in the Western Mediterranean (Ligurian Sea, Italy). Both species are gonochoric. In P. axinellae the sex‐ratio (n colonies = 30) showed a slight predominance of male colonies (M/F = 1.35), whereas in the population of S. savaglia (n colonies = 15) a predominance of females was found (M/F = 0.3). In P. axinellae the first gametocytes were visible in March, whereas in S. savaglia they became visible in May. Both species reproduce at the end of autumn when seawater temperature begins to decrease. Parazoanthus axinellae (10 m depth) spawns eggs and sperms in November, whereas S. savaglia (67 m depth) spawns in December. In P. axinellae sexes were segregated on a rocky wall, with males occurring deeper, whereas male and female colonies of S. savaglia were irregularly dispersed in the population. The maximum number of oocytes differed between the species, being higher in P. axinellae than in S. savaglia.     

Relating petroleum system and play development to basin evolution: West African South Atlantic basins

Sedimentary basins can be classified according to their structural genesis and evolutionary history and the latter can be linked to petroleum system and play development. We propose an approach in which we use the established concepts in a new way: breaking basins down into their natural basin cycle division, then defining the characteristics of each basin cycle (including the type of petroleum systems and plays they may contain) and comparing them with similar basin cycles in other basins, thereby providing a means to learn through a greater population of (perhaps not immediately obvious) analogues. Furthermore, we introduce the use of the trajectory plot as a new tool in such an analysis. This methodology has been applied to the West African South Atlantic marginal basins between Cameroon and Angola, and we demonstrate that the similar tectonostratigraphic evolution of the individual basins along this margin has led to the development of similar types of petroleum systems and play (level)s. Consequently, we can make analogue comparisons among these basins in order to evaluate and predict the presence of potential, yet undiscovered, hydrocarbon accumulations in less well explored parts of the margin.