Radiative association in Li+H revisited: the role of quasi-bound states

The role in radiative association of narrow resonances arising from quasi-bound levels is examined. For the rate coefficient the contribution from such levels is readily calculated in terms of the Einstein A -coefficient from bound rovibrational levels generated using a suitable alternative boundary condition. By locating systematically all the quasi-bound levels, an enhancement by more than an order of magnitude of the rate coefficient for Li(2s) + H(1s) association above about 600 K is obtained. The effect on the LiH abundance in the early Universe is no more than an increase of a factor of 3 for limited ranges of values of the redshift. For the Li(2p) state the effect of narrow resonances appears to have been taken into account in previous calculations.     

Deuterated hydrogen molecule and search for early structure-formation signatures in the Universe

Possible detection of signatures of structure formation at the end of the 'dark age' epoch  ( z ∼ 40–20)  is examined. We discuss the spectral–spatial fluctuations in the cosmic microwave background radiation (CMBR) temperature produced by elastic resonant scattering of CMBR photons on deuterated hydrogen (HD) molecules located in protostructures moving with peculiar velocity. Detailed chemical kinematic evolution of HD molecules in the expanding homogeneous medium is calculated. Then, the HD abundances are linked to protostructures at their maximum expansion, whose properties are estimated by using the top-hat spherical approach and the Λ cold dark matter (ΛCDM) cosmology. We find that the optical depths in the HD three lowest pure rotational lines for high-peak protohaloes at their maximum expansion are much higher than those in LiH molecule. The corresponding spectral–spatial fluctuation amplitudes, however, are probably too weak to be detected by current and forthcoming millimetre telescope facilities. We extend our estimates of spectral–spatial fluctuations to gas clouds inside collapsed CDM haloes by using results from a crude model of HD production in these clouds. The fluctuations for the highest peak CDM haloes at redshifts ∼20–30 could be detected in the future. Observations will be important to test model predictions of early structure formation in the Universe.     

On the influence of magnetic fields on level populations

The influence of magnetic fields on the energy level populations of atoms is firstly studied by analysing the Stokes profiles of Fe  i 6302.5 forming in the solar magnetized atmosphere, with the aid of a departure factor defined to evaluate the deviation from the normal Boltzmann distribution without a magnetic field. This factor is directly related to the ratio of line-source function to the continuum one. The relationship between the departure and the magnetic field reveals an effect that the magnetic field induces an exponential increase in the level population of the lower level of Fe  i 6302.5 (Landé factor   g = 2.5  ) with the field strength. This indicates that the magnetic field can cause the redistribution of populations of those levels whose Landé factors are non-zero. Therefore, this effect should be included in the calculation of the statistical equilibrium. Secondly, an experiment utilizing the Hg5461 line in the laboratory on the Earth is carried out to reveal that the exponential relation is independent of variations in temperature, and the excitation is completely magneto-induced. Finally, the exponential relation is explained by taking account of the magnetic energy in the Boltzmann distribution.     

Measurement of radiative lifetimes and determination of transition probabilities of astrophysical interest in Ho iii

Lifetimes of six levels belonging to the 4f¹⁰6p configuration of Ho  iii have been measured for the first time using the time-resolved laser-induced fluorescence method. They are compared with multiconfigurational pseudo-relativistic Hartree–Fock calculations. A very good agreement is found. Using the experimental lifetimes and theoretical branching fractions, a first set of transition probabilities of astrophysical interest has been obtained for this ion.     

Application of stress release models to historical earthquakes from North China

Univariate and multivariate stress release models are fitted to historical earthquake data from North China. It is shown that a better fit is obtained by treating separately the Eastern part of the region, including the North China Plain and Bohai Sea, and the Western part of the region, including the Ordos Plateau and its Eastern boundary. Further improvement is obtained by fitting the large events (M7.6) and smaller events in the Western region by different stress release models. The comparisons are made by computing the likelihoods of the fitted models and discounting the number of parameters used by Akaike's AIC criterion. The models are used to develop long-term risk scenarios for the East and West regions.     

Impact of land use covers upon karst processes in a typical Fengcong depression system of Nongla, Guangxi, China

The direction and intensity of karst processes can be deeply affected by soil physical and chemical variations which were resulted from land use. Taking Nongla Fengcong depression area, Mashan County, Guangxi as an example, authors discussed the impact of land use on karst processes based on the data of field limestone tablet. The results showed that the corrosional rates at varied soil depth are quite different. Corrosional rate in woodland and orchard is mostly bigger than 20 mg/a, which is much higher than that in tilled land and shrub. Generally, corrosional rate decreased from orchard, woodland, tilled land, fallow land and shrub successively, in which soil organic matter (OM) and soil pH are two major controlling factors: corrosion process is controlled remarkably by soil OM in woodland and orchard. The higher the organic matter content is and the less the pH value is, the higher the corrosional rate is. Owing to lower organic matter content, the corrosional rate is mainly affected by soil CO₂ in tilled land and shrub.     

An experimental study of the grain-scale processes of peridotite melting: implications for major and trace element distribution during equilibrium and disequilibrium melting

The grain-scale processes of peridotite melting were examined at 1,340°C and 1.5 GPa using reaction couples formed by juxtaposing pre-synthesized clinopyroxenite against pre-synthesized orthopyroxenite or harzburgite in graphite and platinum-lined molybdenum capsules. Reaction between the clinopyroxene and orthopyroxene-rich aggregates produces a melt-enriched, orthopyroxene-free, olivine + clinopyroxene reactive boundary layer. Major and trace element abundance in clinopyroxene vary systematically across the reactive boundary layer with compositional trends similar to the published clinopyroxene core-to-rim compositional variations in the bulk lherzolite partial melting studies conducted at similar P–T conditions. The growth of the reactive boundary layer takes place at the expense of the orthopyroxenite or harzburgite and is consistent with grain-scale processes that involve dissolution, precipitation, reprecipitation, and diffusive exchange between the interstitial melt and surrounding crystals. An important consequence of dissolution–reprecipitation during crystal-melt interaction is the dramatic decrease in diffusive reequilibration time between coexisting minerals and melt. This effect is especially important for high charged, slow diffusing cations during peridotite melting and melt-rock reaction. Apparent clinopyroxene-melt partition coefficients for REE, Sr, Y, Ti, and Zr, measured from reprecipitated clinopyroxene and coexisting melt in the reactive boundary layer, approach their equilibrium values reported in the literature. Disequilibrium melting models based on volume diffusion in solid limited mechanism are likely to significantly underestimate the rates at which major and trace elements in residual minerals reequilibrate with their surrounding melt. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Influence of Wind on Dynamics and Flushing of Shallow Estuaries

Observations of two small estuaries in Cape Cod, U.S.A. indicate large variations in salinity structure that are forced by variations in along-estuary wind stress. During onshore winds, the estuarine circulation is reduced, and the along-estuary salinity gradient increases as freshwater accumulates. During offshore winds, the surface outflow is enhanced, freshwater is flushed out of the estuary, and the along-estuary salinity gradient becomes weak. Constrictions block the wind-induced flushing, resulting in strong salinity fronts across the constrictions. The residence time of one of the estuaries varies by more than a factor of three in response to variations in wind-induced flushing. The other estuary has little variation of flushing associated with winds, due to a constriction at the mouth that inhibits the wind-induced exchange. The strong influence of winds on the flushing of these estuaries is due in part to their shallow depths, which accentuates the influence of wind stress relative to the effects of the horizontal density gradient. In addition, the residence times of the estuaries are comparable to the time scale of wind forcing, allowing large changes in water properties during wind events.