Compression mechanisms of coesite

 The structure of coesite has been determined at ten pressures up to a maximum of 8.68 GPa by single-crystal X-ray diffraction. The dominant mechanism of compression is the reduction of four of the five independent Si–O–Si angles within the structure. There is no evidence of the fifth linkage, Si1–O1–Si1, deviating from 180°. Some Si–O bond distances also decrease by up to 1.6% over the pressure range studied. The pattern of Si–O–Si angle reduction amounts to a rotation of the Si2 tetrahedron around the [001] direction. This rotation induces significant internal deformation of the Si1 tetrahedron. Comparison of the experimental data with rigid-unit distance least-squares simulations of coesite suggests that this pattern of compression, the anomalous positive values of both s₂₃ and K′′ in the equation of state of coesite, its high elastic anisotropy and the unusual straight Si1–O1–Si1 linkage within the structure are all consequences of the connectivity of the tetrahedral framework. Received: 11 July 2002 / Accepted: 14 January 2003 Acknowledgements The help of Christian Baerlocher of ETH Zurich in providing both the DLS-76 software and advice in its use is gratefully acknowledged, as are discussions with Paul Ribbe of Virginia Tech and the comments of two anonymous reviewers. The data analysis was supported by the National Science Foundation under grant EAR-0105864 to N.L. Ross and R.J. Angel.     

Atomistic simulation of the structure and elastic properties of pyrite (FeS2) as a function of pressure

Interatomic potential parameters have been derived at simulated temperatures of 0 K and 300 K to model pyrite FeS₂. The predicted pyrite structures are within 1% of those determined experimentally, while the calculated bulk modulus is within 7%. The model is also able to simulate the properties of marcasite, even though no data for this phase were included in the fitting procedure. There is almost no difference in results obtained for pyrite using the two potential sets; however, when used to model FeS₂ marcasite, the potential fitted at 0 K performs better. The potentials have also been used to study the high-pressure behaviour of pyrite up to 44 GPa. The calculated equation of state gives good agreement with experiment and shows that the Fe–S bonds shorten more rapidly that the S–S dimer bonds. The behaviour of marcasite at high pressure is found to be similar to that of pyrite.     

止水帷幕在高层建筑深基坑中的应用

某高层建筑基坑西侧紧邻一道河沟,水量较大,采取三重管高压摆喷帷幕止水[1～4],施工完成后通过监测,未发现渗漏、地下水位明显下降和周围建筑物沉降现象。     

京珠高速公路东西湖段软基处理数值分析

采用等效地基固结系数法,对京珠高速公路东西湖段软土地基,进行了比奥固结平面有限元分析。计算值与实测值比较接近。计算结果为选择地基处理措施和确定道面施工时间提供了依据,保证了竣工后该路段的工后沉降满足设计要求。     

塑膜温室油桃休眠期的温度变化

本文详尽分析了冰岛低压和大西洋高压的长期变化规律，发现两者均具有明显的阶段性变化，而且冰岛低压和大西洋高压的强度具有明显的反相关。同时，还分析了大西洋高压和冰岛低压与我国气候的关系，发现大西洋高压与我国冬季气温基本呈正相关，而冰岛低压与我国气温大致呈反相关，但均没有显著影响，所以两者都不是影响我国气候变化的重要天气系统。     

A Comparative Study of the Atmospheric Layers below First Lifting Condensation Level for Instantaneous Pre-Monsoon Thunderstorm Ocurence at Agartala(23°30′N,91°15′E) and Ranchi(23°14′N,85°14′E) of India

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MODELING STUDY ON SEDIMENTATION CONFIGURATION IN FRONT OF THE DAM AND IN THE PRESSURE CONDUIT OF BOTTOM OUTLETS BY FLUME EXPERIMENT

I.INTRODUCTIONReseri,oirsonoverloadedriverswillreachthestateofrelativeequilibriumwithcontinuousdevelopmentofsedimentation.Insuchcase,thereisdePOsitinfrontofthedam.Thereforethesiltpressureonthedambodyisconsiderablylarge.Sedimentationelevationinfrontofthedamisoneofthefactorsofcalculatingthesiltpressure.Inaddition,tokeeplong-termworkingstorageinreservoif,itisnecessarytoinstallbottomoutlets.Asthereisapressureconduitinfrontoftheoperatinggateofthebottomoutlet,thesedimelltenteredtheconduitwill…     

中国和日本梅雨锋区（个例）结构的比较

通过１９８２年梅雨期的个例分析，研究和比较了中国和日本梅雨我的结构。分析表明：１．梅雨锋区系统对流层上部宽广的斜压区和对流层低层较狭窄的弱斜压区共同组成；２．在两个个例中，中国剖面上锋区均呈“椅”型结构。日本剖面上，６月呈均匀倾斜结构，７月略呈“椅型”，涡度场上中国剖面为相当正压结构，日本剖面为斜压结构；３．梅雨锋区系统可民是均匀斜压区在不均匀和加热情况下结构改变结果；４．中国大陆雨区高层大量潜热     

Analysis of DNAPL infiltration in a medium with a low-permeable lens

In this paper we study the infiltration of DNAPL in a porous medium containing a single low-permeable lens. Our aim is to determine whether or not DNAPL infiltrates into the lens. A key role is played by the capillary pressure: DNAPL cannot infiltrate into the lens unless the capillary pressure exceeds the entry pressure of the lens. In the model this is reflected by an interface condition, the extended capillary pressure condition. To derive analytical approximations we first consider a steady-state DNAPL plume in a homogeneous medium. This results in an estimate of the DNAPL plume width as a function of depth, and an asymptotic solution for small saturations. Assuming that the extent of the lens is much larger than the width of the unperturbed DNAPL plume in the homogeneous medium, we derive an explicit criterion for DNAPL infiltration into the lens in terms of a critical inflow rate. A numerical algorithm is presented in which the extended capillary pressure condition is incorporated. The numerical and analytical results show good qualitative agreement. This revised version was published online in August 2006 with corrections to the Cover Date.     

流体在同心环状空间中流动时的压力损失

同心环状空间是工程上较常见到的流体流动空间，在此空间中流体流动情况的分析较复杂。工程上对其流动情况的分析常常是引用流体力学中的分析结果，但往往由于对环状空间结构的条件重视不够，引用时很容易出毛病。经过仔细推导分析，指出其应用条件，并有助于对同心环状空间中流体流动时压力损失的分析与计算