秦岭巴山地区高陵─达县重磁剖面初步解释

高陵－达县剖面位于秦岭中段，斜跨中朝准地台、秦岭褶皱系、扬子准地台三大构造单元。在研究剖面实磁场特征的基础上，综合地质、物性、省内及邻省深部物探资料，建立了剖面地质－地球物理模型，依此对剖面通过地段的地壳结构、断裂带深部特征、三大构造单元的深部格架进行了解释推断。     

茅台酒酿酒高梁的地质环境研究

茅台酒对酿酒高梁有严格要求，适于茅台酒传统酿造工艺的高梁只产于仁怀县的某些地区，主要是受地质环境的控制。仁怀高梁对某些常量和微量元素有着鲜明的选择性，对磷和钼表现出强烈的吸收作用。岩－土剖面元素的迁聚，对磷和铝的供应是确定仁怀高梁品质和产量的关键。侏罗系砂泥岩、二叠系煤系地层的岩－土剖面，元素淋溶微弱，总量丰富，有效态含量高，组合良好，能正常进行岩－土－高梁系统的物质转化与元素迁移，能充分供应高梁生长所需的磷和钼等元素，是茅台酒酿酒高梁的最宜种植区。     

航空物探平剖图自动绘制的可视化处理

简要介绍了航空物探平面剖面图的自动绘制方法,给出了绘制中对一些问题的处理方法;重点介绍了彩色渐变填充着色、彩色渐变渲染着色等几种可视化处理方法,并提出了着色中渐变度、透明度概念及应用方法。     

Distribution of trace metals in the Odra River system: Water–suspended matter–sediments

Extensive investigations of trace metals concentrations in water, suspended particulate matter (SPM) and bottom sediments of the whole Odra River system were carried out over the years 1997–2000. The vertical distribution of selected metals and their mobility were also studied in the sediment cores from upper and middle river sections. Significant levels of metal contamination were found. Median concentrations (Cd, Pb, Cu, Zn and As) in the SPM and sediments were (mg kg⁻¹) 7.1 and 8.9 Cd, 128 and 146 Pb, 81 and 119 Cu, 1198 and 1204 Zn, 48 and 54 As, respectively. The highest metal pollution of the Odra River solids was found with cadmium, zinc, lead and arsenic, showing high similarity in their frequency distributions in both SPM and sediments. Cd, Zn and As appear to be of particular concern because of the high levels, that appear to be bioavailable, and their high mobility. The exchangeable and carbonate chemical forms of Cd and Zn reached up to 50% of their total amount. Besides the determination of total metal concentration, the metal chemical forms in river solids were investigated. The results of very wide studies of the Odra River system through 4 years suggest that metal pollution decreased, especially for Zn, Pb and Cu. Among all metals studied in the Odra River sediments, substantial reductions of Cd contamination were observed neither in the period after ’97 flood, nor if compared with the earlier results obtained before ’97. No essential differences of the metal contents were observed among the samples for the same river compartment, from the same locality, taken within the five sampling campaigns. The pattern of spatial and vertical metal distributions in the river solids indicates that a variety of sources might be responsible for the contamination; very intensive, historical and current mining and smelting activities probably are the most important ones.     

利用海洋温度剖面与海表盐度反演盐度剖面方法研究

为解决海洋中大量观测数据只含有温度剖面而缺乏盐度观测的问题, 基于历史观测的温盐剖面资料, 考虑到盐度卫星数据的发展, 采用回归分析方法, 在孟加拉湾建立了盐度与温度、经纬度、表层盐度的关系, 并对不同反演方法的反演结果进行检验评估。结果发现, 在不引入海表盐度(sea surface salinity, SSS)时, 最佳反演模型是温度、温度的二次项与经纬度确定的回归模型, 而SSS的引入则可以进一步优化反演结果。将反演结果与观测结果进行对比, 显示用反演的盐度剖面计算的比容海面高度误差超过2cm, 而引入SSS后的误差低于1.5cm。SSS的引入能够较为真实地反映海洋盐度场的垂直结构和内部变化特征, 既能够捕捉到对上混合层有重要影响的SSS信号, 又能够反映盐度在跃层上的季节内变化以及盐度障碍层的季节变化。水团分析显示, 与气候态相比, 盐度反演结果可以更好地表征海洋上层水团的变化特征。     

稳定同位素分馏蒸汽压效应的计算方法

稳定同位素分馏的蒸汽压效应（vaporpressureisotopeeffects,简称VPIE）,在地球化学和天体化学上有着非常重要的研究意义。大部分情况下,由于轻重同位素体具有不同的蒸汽压,在经历挥发和蒸发过程时,含有重同位素的物种挥发得慢,轻同位素物种挥发得快,最终结果导致凝聚相富集重同位素,气相含有较多的轻同位素。在地球化学上,VPIE直接同非常重要的地学参数——同位素平衡分馏系数仅联系在一起。本文应用Bigeleisen提出的方法,直接将VPIE和约化配分函数比（RPFR）相联系,只需要通过理论计算获得两种物质的简谐振动频率,就能够得到非高压情况下该物质的VPIE。本文以水和硫镉矿（CdS）为例,详细介绍了如何计算蒸发和气化过程VPIE的方法,并指出了其在天体化学和矿床学中的一些潜在应用。     

加标回收在水质分析中的应用及回收率计算方法

阐述了水质分析中加标回收分析的方法步骤、条件控制及计算方法。当加标体积影响试样在加标水样中的浓度时,直接使用回收率理论计算公式的计算值,均较其真实的回收率偏低,且其偏低值随加标体积的增加而增大。根据加标回收分析的定义,分别以加标前后被测组分质量浓度(mg/L)的变化或含量(μg)的变化为依据,导出两个计算加标回收率的实用公式。采用该公式,加标体积可以不受严格控制,其计算结果与真实的回收率一致,适用于日常水质分析工作。     

Isothermal annealing of partially metamict zircon: evidence for a three-stage recovery process

 Raman spectroscopy and the powder diffraction technique have been used to monitor the recovery process of two partially metamict zircons (2.6 and 4.8 × 10¹⁸ α-decays g⁻¹) from Sri Lanka during a series of isothermal annealing experiments in the temperature range from 870 to 1622 K. These experiments show for the first time that structural recovery in partially metamict zircon proceeds via three distinct recovery stages, each of which occurs within a distinct time-temperature regime. Whereas the first two stages have previously been recognized (recovery of damaged crystalline remnants and epitaxial recrystallization), the third stage has not yet been identified as a single activated process. It is suggested that anisotropic defect annealing during the first stage at low temperatures, where the structure recovers preferentially along the a(b) plane, produces a geometrical situation where large structural rearrangements are necessary to remove the remaining defects inside the crystalline material. This situation is approximately reached when the amorphous domains start to recrystallize. The reason for anisotropic annealing can be found in a different connectivity between polyhedral linkages in both directions of the zircon lattice. High apparent activation energies, in the range of 6.4 to 7.9 eV, were determined for the third recovery stage from the Raman data, which are interpreted to reflect large structural rearrangements (i.e. polyhedral tilting) associated with the final recovery of the c axis. This explains the occurrence of a distinct recrystallization stage without defect annealing. Finally, it should be mentioned that the first recovery stage is not necessarily expected to occur in less damaged zircon crystals (<∼2 × 10¹⁸ α-decays g⁻¹), since less stable defects along the basal plane might have already been self-annealed during radiation damage accumulation under ambient temperatures. Received: 6 September 2001 / Accepted: 25 February 2002     

Valency Study of Vanadium in Stone Coal Ash of Jiangxi Province

Vanadium-bearing stone coal is a new vanadium resource;recovery ofV_2O_5 from the coal has been investigated.It has been found that a satisfactoryextraction of V_2O_5 depends on both the oxidation of V and its reaction with so-dium salt.V in the coal ash of Yushan mainly exists in two oxidation states:98％V(Ⅲ)and2％V(Ⅳ).The distribution of valency of V shows that organicmatter determines V valency at low temperatures,at about470℃,V(Ⅲ)iscompletely oxidized to V(Ⅳ);above500℃,the temperature is the most impor-tant factor for the oxidation of V .At higher temperatures no more V is oxidizedto V(Ⅴ);an equilibrium is established after92％of V is oxidized to V(Ⅴ).The roles of NaCl in the recovery of V_2O_5 from the coal ash were discussed.The best conditions for roasting are temperature750-800℃for1 h.underthe oxidation-chlorination atmosphere.When the ore:NaCl=100:10 by weight,η_roast reaches85.5％.According to the results,a flowsheet for V_2O_5 extrac-tion from coal ash has been proposed.     

苏州城市规划区Ⅱ承压水开采与地面沉降预防控制研究

在孔隙承压水开采与地面沉降的关系上存在2种观点。水、土应力平衡理论认为：只要开采承压水，就会引发应力失衡并导致地面沉降；而水、土动态平衡理论则认为：除非开采水压力至水、土应力平衡面以下，否则不会引发地面沉降。苏州城市规划区第Ⅱ承压水开采水位与地面沉降动态观测表明，在-33m处存在一个天然动态水、土应力平衡面。第Ⅱ承压含水层形成后，经上覆堆积物自重压力长期压缩作用，其水压力具较高的压强．这种天然状态下产生的弹性释放储存量可开采利用多少，取决于开采状态下水、土应力平衡时可消耗压力水柱高度中的水头值。因而地面沉降的根本原因是开采水位超过了-33m，突破了天然状态水、土应力平衡面水位。Ⅱ承压含水层在天然状态受上覆堆积物重力产生的高压强弹性释放储存量现象，可以帮助我们确立该地区孔隙Ⅱ承压水开采不产生地面沉降的临界水位(水、土应力平衡面)。这一点对承压水开采条件、可开采资源性质具有重大实际意义。同样可以应用于饱受地面沉降困扰的无锡、常州及周边地区，为地下水开发利用政策由单一的封井停采转为目标水位控制开采提供了科学依据。同时也为此政策在承压水动力学机制上找到了内在原因。