大兴安岭地区古利库金(银)矿床成因探讨

古利库金(银)矿床的形成与早白垩世中晚期火山喷发活动及其所形成的火山穹隆构造有关,矿体定位于火山活动波及范围内,平均成矿温度220℃,平均成矿压力135×105Pa,成矿深度约500～600m,属冰长石-绢云母型浅成低温热液矿床,与国内外同类型矿床具有可比性.     

东北地区浅成低温热液矿床的地质特征和构造背景

通过中国东北地区浅戍低温热液矿床的综合特征研究,将矿床的分布划分为德尔布干、呼玛、小兴安岭和吉东4个矿集区,根据其矿床地质、地球化学特征初步确定成矿流体主要来自大气降水,部分混有岩浆水;戍矿物质主要来自赋矿围岩和戍矿岩浆-流体系统;多数矿床形成于中低温、中浅成环境,个别矿床成矿温度高、深度大,显示了斑岩型或造山型与浅成低温溶液型成矿系统之间的连续性;厘定大规模成岩成矿时间为130Ma左右,构造环境是古亚洲洋闭合后陆陆碰撞过程的挤压-伸展转变体制,并以矿集区尺度的CMF模式解释了浅成低温热液矿床岩浆-流体系统的发育机制。     

Application of Chlorite Geothermometry to Hydrothermal Alteration in Toyoha Geothermal System, Southwestern Hokkaido, Japan

In this study, we applied chemical geothermometers to the estimation of formation temperatures of chlorites from various types of hydrothermally altered rocks in the Toyoha geothermal field, using core samples from six drill holes (TH-2 to TH-7) together with wasted ore samples from Toyoha vein-type ore deposit. Based on the preliminary examination of mineral assemblages by X-ray powder diffraction and optical microscopy, hydrothermal alteration observed through the drill holes was classified into four types of alteration zones: propylitic, mixed-layer minerals, kaolin minerals, and ore mineralized zones. The mineral assemblage of the ore mineralized zone observed through TH-2, TH-4, and TH-6 is similar to those of Toyoha ore veins reported previously. The Fe³⁺/ΣFe ratios of chlorites were determined by X-ray photoelectron spectroscopy (XPS), in addition to the usual microprobe analyses. The ratios ranged from 0.20–0.26 for chlorites from the propylitic alteration zone and from 0.13 to 0.17 for those from the ore mineralized zone associated with sulfide minerals. After correcting the Fe³⁺ contents in the octahedral sites of chlorite structures, we obtained acceptable temperatures of the chlorite formation by application of geothermometers, for instance, a similar range of 150–300°C for chlorites from either the propylitic zone or the ore mineralized zone developed through TH-2, TH-4, and TH-6. Chlorites from the ore mineralized zone proximal to the Toyoha deposit are characterized by high Fe and Mn contents compared to the propylitic chlorites, which is similar to the Toyoha vein-filling chlorites; the formation temperatures were close to both the homogenization temperatures of fluid inclusions and the present subsurface temperatures measured through drill holes. Chlorites from the Toyoha ore veins, however, gave slightly higher formation temperatures (180–350°C) than those of chlorites from the ore mineralized zone in the drill cores. This suggests that several types of hydrothermal alteration occurred at different stages in the Toyoha geothermal field and the composition of product chlorite was controlled not only by the temperature but also the composition of fluid related to the formation. Reliable estimation of temperature for the chlorite formation provides basic information on evaluating correctly other physicochemical conditions prevalent at the formation.     

Nature of the Ore-Forming Fluid at the Quaternary Noya Gold Deposit in Kyushu,Japan

We discuss the nature of the ore-forming hydrothermal fluid in the Noya gold-bearing calcite-quartz-adularia veins of central Kyushu, Japan on the basis of oxygen, carbon, and strontium isotope ratios, and aqueous speciation calculations for the present-day geothermal fluid. The isotopic values of the Noya ore-forming fluid were estimated to be −6.5‰ for δ¹³C and −7.5‰ for δ¹⁸O. The oxygen isotopic equilibrium temperatures for vein calcite are more than 180°C at the bottom of the Noya mineralization zone, and decrease with increasing elevation. As the temperature decreased, the dominant carbon species in the fluid changed from H₂CO₃ to HCO₃^- at about 120°C. The equilibrium temperatures for vein quartz are consistent with the calcite calculations. The carbon and oxygen isotope trends of the Noya vein calcite and the isotope ratios of strontium suggest that the fluids that precipitated the Noya veins were controlled by an andesite-dominated geology. Chondrite-normalized REE patterns for the white-colored veins from wells 51-WT-1 and 51-WT-2 displayed a light REE-rich pattern with positive Eu anomalies, suggesting the existence of a reducing environment for the fluid. The pyrite-rich gray-colored veins and a silicified rock from well 51-WT-2 showed higher REE concentrations than did the white veins. Altered host andesitic rocks have similar REE patterns to that of the silicified rock, and have higher REE contents than the others in the drill cores. Aqueous speciation calculations showed that the fluid in the hydrothermal reservoir is currently in muscovite stability. The fluid at the ore-mineralization stage may have contained more potassium or have had a higher pH, so that adularia precipitated with calcite and quartz, as well as gold. Fluid boiling at depth in the system produced the gold-bearing calcite-quartz-adularia veins.     

黑龙江省争光岩金矿床地质特征及成因探讨

争光岩金矿区位于黑河市西部,距我国著名的多宝山铜矿东南约8 km处。该矿床为一低温热液蚀变矿床,主要赋存于燕山晚期闪长岩体与奥陶系中统多宝山组地层内外接触带上,矿体呈脉状产出,受接触构造和断裂构造控制,现控制规模已达中型。笔者对该矿床的地质特征进行了总结,并对其成因进行了分析和探讨。     

Chemistry and Occurrences of Native Tellurium from Epithermal Gold Deposits in Japan

The chemistry and mode of occurrences of native tellurium in the epithermal gold ores from Teine, Kobetsuzawa, Mutsu, Kawazu, Suzaki and Iriki in Japan are examined. Mineral assemblages in contact with native tellurium are: quartz‐sylvanite at Teine, quartz‐hessite‐sylvanite‐tellurantimony at Kobetsuzawa, quartz at Mutsu, quartz‐stutzite‐hessite‐sylvanite‐tetradymite at Kawazu, quartz at Suzaki, and quartz‐goldfieldite at Iriki. The peak patterns of XRD for native tellurium from these six ores are nearly identical to that of JCPDS 4–554. Their chemical compositions of Te range from 98.16 to 100.73 wt.%, showing nearly pure tellurium. Other elements detected are: Se of 0–0.85 and Cu of 0–0.74 at Teine, Sb of 0.45–0.47 and Se of 0.19–0.27 at Kawazu, Se of 0.22–1.11 and Sb of 0–0.49 at Suzaki, and Cu of 0.69–0.98, As of 0.22–0.28 and Bi of 0–0.22 wt.% at Iriki. No other elements are detected in the ores of Kobetsuzawa and Mutsu. The ranges of associated minor compositions are consistent with those of the experimental phase. The differences would be related to associate minerals. The mineral assemblages in these ores agree well with the previously proposed experimental phase relations in Au‐Ag‐Te ternary system for 120–280°C. The Suzaki ore has high Te‐Au assemblage: from calaverite‐sylvanite‐krennerite via native tellurium to petzite, with changing mineralization stage, whereas the Kobetsuzawa and the Kawazu ores have high Te‐Ag assemblage of tellurium‐hessite, and native tellurium‐stutzite‐hessite‐sylvanite, respectively. The Teine ore has intermediate assemblage of native tellurium‐sylvanite. The mineral assemblages in the Au‐Ag‐Te system are related to the hydrothermal environment especially to the pH condition, i.e. Au rich assemblages under acidic and Ag rich assemblages under intermediate pH conditions, being supported by alteration mineral species. The other telluriferous epithermal gold deposits not in association with native tellurium such as Agawa, Date, Takeno, Chugu, Chitose, Sado and Kushikino are estimated to have been formed under higher pH conditions as adularia and calcite occur in these deposits. The pH‐Eh diagram for aqueous tellurium species and tellurium minerals at 250°C indicates that the region of native tellurium occurs between those of aqueous telluride and tellurous species at lower pH, being consistent with their mineral assemblages in ores and alteration envelopes.     

斑岩型和浅成低温热液型矿床成矿流体与找矿预测研究:以华南若干典型矿床为例

斑岩型和浅成低温热液型矿床是全球铜、钼、金、银的主要来源之一,具有重要经济价值。这两类矿床之间通常存在紧密的时空关系,对其成矿流体性质和演化的解剖不仅有利于探究金属沉淀机制,也有助于揭示两者之间的内在成因联系。本文在综述国内外重要研究前沿基础上,以中国华南富家坞斑岩型铜钼(金)矿、桐村斑岩钼矿,以及邱村和安村浅成低温热液金矿为例,系统总结了斑岩型和浅成低温热液型矿床流体特征、演化规律和金属沉淀机制、探讨了从斑岩型到浅成低温热液型流体演化的“气相迁移”模型,并以福建紫金山铜金矿床为例,介绍了应用流体填图进行找矿预测的实例。     

伊宁吐拉苏地区硅化岩型放特征及成因

硅化岩型金矿赋矿地层主要为下石炭统大哈拉军山组酸性火山灰凝灰岩段;含矿岩石主要为硅化凝灰质砾岩和硅化凝灰岩;具有低品位、大矿量、埋藏浅、层控性明显的特点;成矿期分为原生沉积富集、水热交代蚀变、表生氧化淋滤三期;包裹体少而小,以液相成分为主,气液比5％～10％;成矿流体以大气降水为主,含有少量岩浆水,盐度N/w(MaCl)0.39％,pH值5.5,Eh值-0.8～-1.2V;成矿温度88℃～98℃,成矿压力59×105Pa,成矿深度230m左右,属浅成低温水热系统金矿。     

内蒙古巴彦哈尔金矿床地质特征及成因初探

内蒙古巴彦哈尔金矿床位于华北陆块北缘艾力庙-锡林浩特中间地块西北缘.矿床赋存于中元古代温都尔庙群的绢云石英片岩和绿泥石片岩中.矿床的形成与区内韧性剪切带及华力西期岩浆活动关系密切.矿区内共圈定出5个矿体,总体走向为北西向,矿体呈似层状或透镜状产出,矿石类型包括石英脉型和糜棱蚀变岩型.金矿化与硅化和黄铁绢英岩化蚀变关系密切.结合矿床的矿体地质、矿物成分、矿物嵌布及围岩蚀变特征以及前人包裹体测温结果,认为矿床类型为浅成低温热液型金矿.     

Polymetallic Mineralization at the Shin-Ohtoyo Deposit, Harukayama District, Hokkaido, Japan

Abstract: The Shin-Ohtoyo Cu–Au deposit is located in the Harukayama district, 20 km west of Sapporo, Hokkaido, Japan. Both acid-type disseminated and adularia–quartz–type vein Au mineralizations have been recognized within a small distance of less than 500 m in the district. Mineralogical characteristics of sulfide ores from the Shin-Ohtoyo deposit have been proved to be polymetallic. Ore minerals containing Sn, V, Bi and Te are recognized. Nine ore types are recognized in terms of characteristic mineral assemblage; (1) chalcedonic quartz veinlets in silicified zone around the deposit, (2) bismuthinite, emplectite, friedrichite and tetrahedrite, (3) an unnamed Cu–Sn–Fe–Zn sulfide, colusite-series minerals, stannoidite, emplectite and tetrahedrite, (4) bournonite, Se-bearing galena and tetrahedrite, (5) luzonite/famatinite and Ag-bearing tetrahedrite, (6) colusite-series minerals, emplectite, aikinite and tetrahedrite/goldfieldite, (7) luzonite/famatinite, colusite-series minerals, mawsonite and tetra–hedrite/goldfieldite, (8) enargite, luzonite/famatinite and tetrahedrite, and (9) colusite-series minerals and tetrahedrite. The first occurrence of friedrichite and stibiocolusite from Japan are reported. The chemical formula of the unnamed phase corresponds to Cu₆(Cu, Fe, Zn)Sn₃S₁₀. Sulfur isotopic ratios (δ³⁴S) of sulfides from the stockpile range from –0. 5% to +1. 9%, and those from drill cores recovered by Metal Mining Agency of Japan (MMAJ) vary from –2. 7% to +0. 8%. Sulfur isotopic ratio of barite in a cavity in the silicified tuff breccia collected from the stock pile yields +27. 1%, while that of barite collected from MMAJ core is +21. 7%. Sulfur isotopic thermometry applied for a pair of barite (+21. 7%) and associated pyrite (+1. 8%) indicates about 300°C. High–Te tetrahedrite composition from both the chalcedonic quartz vein in the silicified zone around the Shin-Ohtoyo deposit and the polymetallic sulfide ores from the adit of the deposit, suggests that the Au mineralization in the former is attributed to a hydrothermal system marginal to the polymetallic mineralization.